2019年3月12日のコンテンツから

[読みたい論文] ラジカル反応らしくないC(sp3)−H結合活性化反応


https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4461

反応場をうまく制御した銅触媒による反応です。

C–H結合活性化ですが、Nanonieleの分野分析では、有機化学の分野で最も活発に研究が行われています。その次が配位化学。均一系触媒による反応が数多く報告されているためかと思われます。金属はPd, Cu, Feの順。遷移金属というキーワードもよく使われます。詳細と関連論文のリストは下記リンクより。

https://nanoniele.jp/cgi-bin/nanoniele.cgi?inputsite=detail&inputid=20151119144022&keyword=CHBA&detailkey=CHBA

オススメ論文

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http://dx.doi.org/10.1039/C9RA00255C

[RSC Adv. 20199, 7107–7114.] Donor?acceptor polymers containing thiazole-fused benzothiadiazole acceptor units for organic solar cells
Nakamura, Tomoya; Ishikura, Yasuhisa; Arakawa, Noriko; Hori, Megumi; Satou, Motoi; Endo, Masaru; Masui, Hisashi; Fuse, Shinichiro; Takahashi, Takashi; Murata, Yasujiro; Murdey, Richard; Wakamiya, Atsushi
Tag: VOCOMOUMOLUMOBDTHJBHJBTBTDAMOOCVC3H3NSPCEOBGOSCHOMOe-OFC
http://dx.doi.org/10.1039/C9RA00229D

[RSC Adv. 20199, 7321–7323.] Concise total syntheses of phelligridins A, C, and D
Ohyoshi, Takayuki; Mitsugi, Keisuke; Higuma, Tatsuya; Ichimura, Fumitaka; Yoshida, Masahito; Kigoshi, Hideo
http://dx.doi.org/10.1039/C8RA10346A

[RSC Adv. 20199, 7543–7550.] Blue-emitting acridine-tagged silver(i)-bis-N-heterocyclic carbene
Prabusankar, Ganesan; Muthukumaran, Nirmala; Vaddamanu, Moulali; Raju, Gembali; Velappan, Kavitha; Sathyanarayana, Arruri; Masaya, Yamane; Sugiyama, Shohei; Hisano, Kyohei; Tsutsumi, Osamu
Tag: TCSPCAgSPCSPCFLTFLHetQYemEAXRSCXRDimHFPNmeTSCPCTCPSCNHCMeXRDSC
http://dx.doi.org/10.1039/C9RA00281B

ナノ粒子 
[Analyst 2019144, 2158–2165.] Rapid detection of hypnotics using surface-enhanced Raman scattering based on gold nanoparticle co-aggregation in a wet system
Segawa, Hiroki; Fukuoka, Takao; Itoh, Tamitake; Imai, Yuichi; Iwata, Yuko T.; Yamamuro, Tadashi; Kuwayama, Kenji; Tsujikawa, Kenji; Kanamori, Tatsuyuki; Inoue, Hiroyuki
Tag: LODGNPAuNPAuMatFNZSERSNPVS
http://dx.doi.org/10.1039/C8AN01829D

[Anal. Biochem. 2019570, 13–20.] Development of a novel l-histidine assay method using histamine dehydrogenase and a stable mutant of histidine decarboxylase
Yamaguchi, Hiroki; Nakata, Kunio; Tatsumi, Moemi; Sugiki, Masayuki; Miyano, Hiroshi; Mizukoshi, Toshimi
Tag: WTHisHHDC51-45-6
http://www.sciencedirect.com/science/article/pii/S0003269718309977

[Anal. Biochem. 2019570, 27–31.] Pyruvate kinase from Geobacillus stearothermophilus displays an unusual preference for Mn2+ in a cycling reaction
Ueda, Shigeru; Sakasegawa, Shin-ichi
Tag: G6PDHGluAbsGlcG6PDGluG6PGlu
http://www.sciencedirect.com/science/article/pii/S0003269718306146

[ChemCatChem 201911, 1412–1424.] Beyond Cars: Fischer-Tropsch Synthesis for Non-Automotive Applications
Sun, Jian; Yang, Guohui; Peng, Xiaobo; Kang, Jincan; Wu, Jinhu; Liu, Guangbo; Tsubaki, Noritatsu
Tag: FTSFTC
https://doi.org/10.1002/cctc.201802051

固体酸化物形燃料電池 
[ChemCatChem 201911, 1472–1479.] Rh/Ce0.25Zr0.75O2 Catalyst for Steam Reforming of Propane at Low Temperature
Yu, Lin; Sato, Katsutoshi; Nagaoka, Katsutoshi
Tag: HCFCSRLPGSOFCHEC3H8C
https://doi.org/10.1002/cctc.201801824

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