2019年3月13日のコンテンツから

[読みたい論文] マグネシウム/クロロシラン還元剤を使う不飽和エステルのトリフルオロアセチル化

長岡技科大のグループによる、Mg/TMSCl還元剤に関する研究です。

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4462

この論文のキーワードでもあるマグネシウムですが、Nanonieleの分析によると、分析化学の分野での研究が活発に行われているようです。関連のキーワードにはカーボンナノチューブに関するものがいくつか挙がっています。

https://nanoniele.jp/cgi-bin/nanoniele.cgi?inputsite=detail&inputid=1120142501123240&keyword=Mg&detailkey=MG


それから反応に使われているNMPですが、ピロリジンをベースにたどってくと分かりやすいかと。ピロリジン、2-ピロリドン、N-メチル-2-ピロリドン、と。C=O結合があるからとか、窒素原子にメチル基が結合しているとか。


人名反応を年別にまとめました。

今日も加筆しました。明日も加筆すると思います。

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4455

1940年はこんな年

人名反応など

Carroll転位 [Doi 1]
Cope転位Ramberg−Bäcklund反応Cope転位 [Doi 1]
Kroll法Baudisch反応 [Doi 1]


ノーベル化学賞は該当者なし。

できごと

炭素14をMartin KamenとSam Rubenが発見
米国・科学者動員令
日本ニュース映画社(日本映画社)設立
武田化成株式会社(吉富製薬)設立
大阪朝日新聞と東京朝日新聞の題号を朝日新聞に統一
大日本航空が横浜-サイパン-パラオ間定期航空路を開始
勝鬨橋開通
艦上戦闘機にゼロ戦採用
勤労所得の源泉徴収開始
ハティ・マクダニエルがアカデミー賞助演女優賞を受賞

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