2019年3月15日のコンテンツから

今日のどうぶつ

松の木を突っつくコゲラです。散歩中に”ビー、カタカタ”と音がしたので見上げるといました。

[読みたい論文] 光学活性亜鉛触媒によるエナンチオ選択的分子内Conia-ene型反応

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4464

J. Am. Chem. Soc.から。純粋なConia-ene反応とは少し違うようで、論文に掲載の反応様式とConia-ene反応の違いというか共通点というか、そういうものがどこにあるのか気になったので、読みたい論文に追加です。

[読みたい論文] 副反応を気にしなくて良いピナコールカップリング

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4454

(この記事ではなく)読みたいと思っていたこの論文の内容が、ケムステさんで紹介されていましたので読まずに済みそうです(でもまだ読みたい)。

触媒的不斉交差ピナコールカップリングの開発(https://www.chem-station.com/blog/2019/03/redcoupling.html)

掛け算の順序のことでブツクサ言ってるツイートを見かけたのでツイートしたら、クソリプいただきました。

私のアカウントからはなぜか見えないけど(笑)

算数には算数の、数学には数学のプロトコルがある。それだけのことだと思うんですよね。算数と数学を同じものだとするからいかんのでは、と。中学1年の最初の数学の授業で先生から「算数と数学は違う」と言われたの、いまでも憶えていますよ。

たゆたえども沈まず-有機化学あれこれ- の記事、読みました。

学位論文審査に投稿論文の掲載が本当に必要かという話。確かに理解できるところはあります。博士の学位をどう担保するか、ですね。

博士号出すのに投稿論文って必須なんですかね

人名反応を年別にまとめました。

今日も明日も加筆です。

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4455

1942年はこんな年

人名反応など

Wittig転位

ノーベル化学賞

(該当者なし)

できごと

興亜工業大学(現千葉工業大学)開校

帝国石油設立

鉄道技術研究所設立

西日本鉄道(西鉄)設立

広島電鉄設立。

三井船舶(商船三井)設立

関門鉄道トンネル開業

大日本映画(大映)設立

産業経済新聞(産経新聞)創刊

西日本新聞発刊

静岡新聞創刊

東京新聞創刊

東京に初の空襲警報発令

井の頭自然文化園開園

共栄火災海上保険設立

オススメの論文

[Org. Biomol. Chem. 201917, 2887–2891.] A parallel permeability assay of peptides across artificial membranes and cell monolayers using a fluorogenic reaction
Morimoto, Jumpei; Amano, Rei; Ono, Takahiro; Sando, Shinsuke
Tag: ML
http://dx.doi.org/10.1039/C9OB00133F

全合成 
[Org. Biomol. Chem. 201917, 2896–2905.] Improved synthesis of 2,4,6-trialkylpyridines from 1,5-diketoalkanes: the total synthesis of Anibamine
Miyakoshi, Takeru; Konno, Hiroyuki
Tag: PyrpyrPy
http://dx.doi.org/10.1039/C8OB02723D

クロスカップリング 
[Org. Biomol. Chem. 201917, 2972–2984.] Zinc-catalyzed regioselective C?P coupling of p-quinol ethers with secondary phosphine oxides to afford 2-phosphinylphenols
Zhang, Ming; Jia, Xiaoyu; Zhu, Haowei; Fang, Xutong; Ji, Chenyi; Zhao, Sizhuo; Han, Li-Biao; Shen, Ruwei
Tag: ZnCLASPONuCCCCR
http://dx.doi.org/10.1039/C9OB00129H

[Chem. Sci. 201910, 3196–3201.] An Al-doped SrTiO3 photocatalyst maintaining sunlight-driven overall water splitting activity for over 1000? h of constant illumination
Lyu, Hao; Hisatomi, Takashi; Goto, Yosuke; Yoshida, Masaaki; Higashi, Tomohiro; Katayama, Masao; Takata, Tsuyoshi; Minegishi, Tsutomu; Nishiyama, Hiroshi; Yamada, Taro; Sakata, Yoshihisa; Asakura, Kiyotaka; Domen, Kazunari
Tag: OWS
http://dx.doi.org/10.1039/C8SC05757E

ニッケル触媒 
[Chem. Sci. 201910, 3242–3248.] Nickel-catalyzed oxidative C?H/N?H annulation of N-heteroaromatic compounds with alkynes
Obata, Atsushi; Sasagawa, Akane; Yamazaki, Ken; Ano, Yusuke; Chatani, Naoto
Tag: NiCatIMDimHHimimidINDFGbimPYHPzpzHpzAr
http://dx.doi.org/10.1039/C8SC05063E

ナノ粒子 
[Chem. Sci. 201910, 3289–3294.] Charge transfer dependence on CO2 hydrogenation activity to methanol in Cu nanoparticles covered with metal?organic framework systems
Kobayashi, Hirokazu; Taylor, Jared M.; Mitsuka, Yuko; Ogiwara, Naoki; Yamamoto, Tomokazu; Toriyama, Takaaki; Matsumura, Syo; Kitagawa, Hiroshi
Tag: HfZrCatCTNPCH3OH
http://dx.doi.org/10.1039/C8SC05441J

[Chem. Sci. 201910, 3330–3339.] Downsizing feature of microphase-separated structures via intramolecular crosslinking of block copolymers
Watanabe, Kodai; Katsuhara, Satoshi; Mamiya, Hiroaki; Yamamoto, Takuya; Tajima, Kenji; Isono, Takuya; Satoh, Toshifumi
Tag: AFLamNGLStEMCLLAPStICPSAFMTEMe-TFBCP
http://dx.doi.org/10.1039/C8SC05016C

[Chem. Sci. 201910, 3385–3400.] A new route for the efficient metalation of unfunctionalized aromatics
Peel, Andrew J.; Tezuka, Noriyuki; D{‘}Rozario, James M.; Uchiyama, Masanobu; Wheatley, Andrew E. H.
Tag: SSHCPhHBZ
http://dx.doi.org/10.1039/C8SC04325F

[Phys. Chem. Chem. Phys. 201921, 5882–5889.] Electrochemical hydrogenation of non-aromatic carboxylic acid derivatives as a sustainable synthesis process: from catalyst design to device construction
Sadakiyo, Masaaki; Hata, Shinichi; Fukushima, Takashi; JuhÃ?sz, Gergely; Yamauchi, Miho
Tag: ECCOOHC
http://dx.doi.org/10.1039/C8CP07445C

[Phys. Chem. Chem. Phys. 201921, 5966–5973.] Band alignment in quantum wells from automatically tuned DFT+U
Kolesov, Grigory; Lin, Chungwei; Knyazev, Andrew; Kojima, Keisuke; Katz, Joseph; Akiyama, Koichi; Nakai, Eiji; Kawahara, Hiroyuki
Tag: CBGGALDAESCBODFTQWe-
http://dx.doi.org/10.1039/C9CP00122K

[Phys. Chem. Chem. Phys. 201921, 6238–6246.] The energy level of the Fe2+/3+-transition in BaTiO3 and SrTiO3 single crystals
Suzuki, Issei; Gura, Leonard; Klein, Andreas
Tag: CBCBMOEaOVOvacELSC
http://dx.doi.org/10.1039/C8CP07872F

ナノファイバー 
[Angew. Chem. Int. Ed. 201958, 3764–3768.] Photoresponsive Circular Supramolecular Polymers: A Topological Trap and Photoinduced Ring-Opening Elongation
Adhikari, Bimalendu; Aratsu, Keisuke; Davis, Joyal; Yagai, Shiki
Tag: AZBABAZONF
https://doi.org/10.1002/anie.201811237

[Angew. Chem. Int. Ed. 201958, 3814–3818.] Stereospecific α-Sialylation by Site-Selective Fluorination
Hayashi, Taiki; Kehr, Gerald; Bergander, Klaus; Gilmour, Ryan
Tag: mFBBM
https://doi.org/10.1002/anie.201812963

[Angew. Chem. Int. Ed. 201958, 3952–3956.] One-Step Synthesis of Dendritic Highly Branched Polystyrenes by Organotellurium-Mediated Copolymerization of Styrene and a Dienyl Telluride Monomer
Lu, Yangtian; Yamago, Shigeru
Tag: CTALPSStPStFGPyrPyPSBCPM
https://doi.org/10.1002/anie.201814566

光酸化還元触媒 
[Angew. Chem. Int. Ed. 201958, 4002–4006.] Photoredox-Catalyzed Site-Selective α-C(sp3)-H Alkylation of Primary Amine Derivatives
Ashley, Melissa A.; Yamauchi, Chiaki; Chu, John C. K.; Otsuka, Shinya; Yorimitsu, Hideki; Rovis, Tomislav
Tag: HATHRPGVLPCNH2VLPCe-
https://doi.org/10.1002/anie.201812227

[Angew. Chem. Int. Ed. 201958, 4007–4011.] Enantioselective N-Heterocyclic Carbene Catalysis that Exploits Imine Umpolung
Fernando, Jared E. M.; Nakano, Yuji; Zhang, Changhe; Lupton, David W.
Tag: StetterCatHetNHC
https://doi.org/10.1002/anie.201812585

[Angew. Chem. Int. Ed. 201958, 4027–4030.] Alkyllithium Compounds Bearing Electrophilic Functional Groups: A Flash Chemistry Approach
Nagaki, Aiichiro; Yamashita, Hiroki; Hirose, Katsuyuki; Tsuchihashi, Yuta; Yoshida, Jun-ichi
Tag: EFGEl
https://doi.org/10.1002/anie.201814088

[ACS Omega 20194, 5147–5154.] Temperature-Controlled Locally Excited and Twisted Intramolecular Charge-Transfer State-Dependent Fluorescence Switching in Triphenylamine?Benzothiazole Derivatives
Kundu, Anu; Karthikeyan, Subramanian; Sagara, Yoshimitsu; Moon, Dohyun; Anthony, Savarimuthu Philip
Tag: TICTLEFLTFLNCTQYSSIMDimHHimimidABSFELEHECTSICT
https://doi.org/10.1021/acsomega.8b03099

[ACS Pharmacol. Transl. Sci. 20192, 52–65.] Novel and Potent Dopamine D2 Receptor Go-Protein Biased Agonists
Bonifazi, Alessandro; Yano, Hideaki; Guerrero, Adrian M.; Kumar, Vivek; Hoffman, Alexander F.; Lupica, Carl R.; Shi, Lei; Newman, Amy Hauck
Tag: PCRFADAGPCRGPGR
https://doi.org/10.1021/acsptsci.8b00060

[J. Phys. Chem. A 2019123, 2125–2141.] Development of the ReaxFF Methodology for Electrolyte?Water Systems
Fedkin, Mark V.; Shin, Yun Kyung; Dasgupta, Nabankur; Yeon, Jejoon; Zhang, Weiwei; van Duin, Diana; van Duin, Adri C. T.; Mori, Kento; Fujiwara, Atsushi; Machida, Masahiko; Nakamura, Hiroki; Okumura, Masahiko
Tag: BEPTrdfHQMOBDEMDReaxFFFF
https://doi.org/10.1021/acs.jpca.8b10453

[J. Phys. Chem. A 2019123, 1945–1952.] Photo- and Electro-Driven Molecular Switching System of Aryl-Bridged Photochromic Radical Complexes
Yamamoto, Katsuya; Mutoh, Katsuya; Abe, Jiro
Tag: ECDPABIECECRECRRAAre-
https://doi.org/10.1021/acs.jpca.8b12384

ナノ粒子 
[J. Phys. Chem. C 2019123, 6080–6089.] High Turnover Frequency CO?NO Reactions over Rh Overlayer Catalysts: A Comparative Study Using Rh Nanoparticles
Yoshida, Hiroshi; Koizumi, Kenichi; Boero, Mauro; Ehara, Masahiro; Misumi, Satoshi; Matsumoto, Akinori; Kuzuhara, Yusuke; Sato, Tetsuya; Ohyama, Junya; Machida, Masato
Tag: APDTOFIRMDDFTDFT-MDNPOTSRLSTFC
https://doi.org/10.1021/acs.jpcc.9b00383

[J. Phys. Chem. C 2019123, 6062–6069.] Charging of the Ice/Solution Interface by Deprotonation of Dangling Bonds, Ion Adsorption, and Ion Uptake in an Ice Crystal As Revealed by Zeta Potential Determination
Inagawa, Arinori; Harada, Makoto; Okada, Tetsuo
Tag: DBZPOTS
https://doi.org/10.1021/acs.jpcc.8b12435

[J. Phys. Chem. C 2019123, 6030–6036.] Structure and Electronic Properties of [Ca24Al28O64]4+?·4e??? Surfaces: Opportunities for Termination-Controlled Electron Transfer
Ong, Phuong-Vu; Hosono, Hideo; Sushko, Peter V.
Tag: BEETOBDEDFTe-
https://doi.org/10.1021/acs.jpcc.8b11866

[J. Phys. Chem. C 2019123, 5964–5971.] Structures of Rhodium Oxide Cluster Cations Rh7Om+ (m = 4???7, 12, 14) Revealed by Infrared Multiple Photon Dissociation Spectroscopy
MafunÃ?, Fumitaka; Koyama, Kohei; Nagata, Toshiaki; Kudoh, Satoshi; Yasuike, Tomokazu; Miyajima, Ken; Huitema, Douwe M. M.; Chernyy, Valeriy; Bakker, Joost M.
Tag: cOIROODFTe-Rh
https://doi.org/10.1021/acs.jpcc.8b11068

CO2還元 
[J. Phys. Chem. C 2019123, 5951–5963.] An In Situ Surface-Enhanced Infrared Absorption Spectroscopy Study of Electrochemical CO2 Reduction: Selectivity Dependence on Surface C-Bound and O-Bound Reaction Intermediates
Katayama, Yu; Nattino, Francesco; Giordano, Livia; Hwang, Jonathan; Rao, Reshma R.; Andreussi, Oliviero; Marzari, Nicola; Shao-Horn, Yang
Tag: APXPSSEIRASPEpcIRESECXPSHCGHGSEIRAABSPSDFTCO2Re-ECRC
https://doi.org/10.1021/acs.jpcc.8b09598

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