2019年5月15日のコンテンツから

きょうのどうぶつ

ハの字眉のクロ3号。画像ではわかりませんが、尻尾が中くらいの長さなのが特徴です。我が家の庭を通り過ぎる頻度が他の黒猫よりも少ないですね。

[読みたい論文] 欲求不満がさらに強まったルイスペア

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4502

ホウ素-水素結合があるため、従来のルイスペアとは反応性が異なるようです。なぜ「水素原子」を持たせたのかも気になるところ。

計算終わりました

略語を登録しました

MOTF
mesoporous oxide thin film
SCPPC
self-charged photo-power cell
CEMC
cluster expansion Monte Carlo
OIC
organogel ionic conductor
EICA
evaporation-induced confinement assembly
TICS
twisted intramolecular charge shuttle
LBR
luminescent back reflector
CBCT
cone beam computed tomography
CICS
collision-induced charge stripping
OCE
out-coupling efficiency
TFNM
thin-film nanocomposite membrane
TSPE
thermoresponsive solid-polymer electrolyte
NTS
neural tactile sensor
HBM
homogeneous bulk-mixed
IGF1R
insulin growth factor-1 receptor

注目の記事やプレスリリース

白昼夢が幸福につながる条件が明らかに -マインドフルネスとオタク消費の効果を実証-
(広島大学)
https://www.hiroshima-u.ac.jp/system/files/119125/白昼夢が幸福につながる条件が明らかに.pdf
ナノスケールの光の制御技術を開発 ~空間極限の分解能を持つ顕微分光に期待~
(科学技術振興機構)
https://www.jst.go.jp/pr/info/info1376/index.html
AI技術の早期社会実装に向けた研究開発プロジェクトで新たに7件を採択
(NEDO)
https://www.nedo.go.jp/news/press/AA5_101115.html
金属電極/固体電解質界面に形成される イオンの空間電荷層の観察に世界で初めて成功!
(名古屋大学)
http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20190514_imass001.pdf
ヒドロキシイソオキソフロリンの合成に関する論文がOrg. Lettに掲載されました。
(名古屋大学忍久保研究室)
http://www.chembio.nagoya-u.ac.jp/labhp/organic1/index.html
植物は幹細胞の頑強な増殖を止めるために多段階スイッチを使っていた 開花、種づくりに向けての巧妙な仕組み解明 ~園芸植物の花の改良や食糧増産に期待~
(奈良先端科学技術大学院大学)
http://www.naist.jp/pressrelease/2019/05/005749.html

1979年はこんな年

人名反応など

Danishefsky-Kitaharaジエン [Doi 1]
Piancatelli転位 [Doi 1]
Sakurai-Hosomiアリル化反応 [Doi 1]
Stetter反応 [Doi 1]

ノーベル化学賞

ボランの構造研究
(William Nunn Lipscomb, Jr.)

できごと

「チップスター」発売(ヤマザキナビスコ=ヤマザキビスケット)
「クイズダービー」放送開始(TBS)
軽自動車の規格改正(550cc)
個別宅配サービス「宅急便」発売(大和運輸=ヤマトホールディングス)
国内初の5つ子誕生
「徹子の部屋」放送開始
後楽園球場に日本初の人工芝が登場
アップルコンピュータ(アップル)設立
「日清焼そばU.F.O.」発売(日清食品)
アントニオ猪木対モハメド・アリの異種格闘技戦
株式会社ヴァル研究所設立
「どん兵衛きつねうどん」発売(日清食品)
ピンク・レディーがレコードデビュー
東急ハンズ設立
エボラ出血熱の世界初の患者がコンゴ民主共和国で発生
こちら葛飾区亀有公園前派出所」連載開始(山止たつひこ=秋本治)
日本初のF1日本グランプリが開催
東急ハンズが1号店オープン
「白い恋人」発売(石屋製菓)
日本初のドライブスルー登場(新潟県長岡市)

オススメ論文

カーボンナノチューブ 
[RSC Adv. 20199, 13998–14003.] Influence of local strain caused by cycloaddition on the band gap control of functionalized single-walled carbon nanotubes
Maeda, Yutaka; Kuroda, Kiyonori; Tambo, Haruto; Murakoshi, Hiyori; Konno, Yui; Yamada, Michio; Zhao, Pei; Zhao, Xiang; Nagase, Shigeru; Ehara, Masahiro
Tag: TDNTSWCNT109-64-8111-24-0CPLCNTCADFT
http://dx.doi.org/10.1039/C9RA02183C

[RSC Adv. 20199, 14465–14471.] Quantitative analysis of crystallinity in an argyrodite sulfide-based solid electrolyte synthesized via solution processing
Yubuchi, So; Tsukasaki, Hirofumi; Sakuda, Atsushi; Mori, Shigeo; Hayashi, Akitoshi; Tatsumisago, Masahiro
Tag: SEXRCH3CH2OHEtOHTEMXRDe-THF
http://dx.doi.org/10.1039/C9RA00949C

[J. Phys. Chem. A 2019123, 4000–4013.] Importance of the Parallel Component of the Transition Moments to the 1Π1 (5A′) and 3Π1 (3A′) Excited States of ICN in the Ã?-Band Photodissociation
Kashimura, Tatsuhiko; Yabushita, Satoshi
Tag: TDMGSABSe-
https://doi.org/10.1021/acs.jpca.9b01127

[J. Phys. Chem. A 2019123, 3985–3991.] Raman Optical Activity on a Solid Sample: Identification of Atropisomers of Perfluoroalkyl Chains Having a Helical Conformation and No Chiral Center
Shimoaka, Takafumi; Sonoyama, Masashi; Amii, Hideki; Takagi, Toshiyuki; Kanamori, Toshiyuki; Hasegawa, Takeshi
Tag: ROASSPFASDAHEL
https://doi.org/10.1021/acs.jpca.8b11613

[J. Phys. Chem. B 2019123, 4157–4157.] Correction to “Anomalous Water Molecules and Mechanistic Effects of Water Nanotube Clusters Confined to Molecular Porous Crystals???
Tadokoro, Makoto; Ohhara, Takashi; Ohata, Yuki; Suda, Takahiro; Miyasato, Yuji; Yamada, Takeshi; Kikuchi, Tatsuya; Tanaka, Ichiro; Kurihara, Kazuo; Oguni, Masaharu; Nakasuji, Kazuhiro; Yamamuro, Osamu; Kuroki, Ryota
Tag: NT
https://doi.org/10.1021/acs.jpcb.9b03433

イオン液体 
[J. Phys. Chem. B 2019123, 4098–4107.] Solvation Structure of Poly(benzyl methacrylate) in a Solvate Ionic Liquid: Preferential Solvation of Li?Glyme Complex Cation
Hashimoto, Kei; Kobayashi, Yumi; Kokubo, Hisashi; Ueki, Takeshi; Ohara, Koji; Fujii, Kenta; Watanabe, Masayoshi
Tag: PBzMAMDSLCSTMDCNILHECSTSILSCAAMDM
https://doi.org/10.1021/acs.jpcb.9b02458

ポルフィリン 
[J. Phys. Chem. C 2019123, 11529–11538.] A Diprotonated Porphyrin as an Electron Mediator in Photoinduced Electron Transfer in Hydrogen-Bonded Supramolecular Assemblies
Suzuki, Wataru; Kotani, Hiroaki; Ishizuka, Tomoya; Kawano, Masaki; Sakai, Hayato; Hasobe, Taku; Ohkubo, Kei; Fukuzumi, Shunichi; Kojima, Takahiko
Tag: PSTASETHTRPETBnTAPDDMKABSPIETPore-ACE
https://doi.org/10.1021/acs.jpcc.9b02449

[J. Phys. Chem. C 2019123, 11351–11361.] Calculation of Charge-Transfer Electronic Coupling with Nonempirically Tuned Range-Separated Density Functional
Kitoh-Nishioka, Hirotaka; Ando, Koji
Tag: RCTF2FDBFTFe-M
https://doi.org/10.1021/acs.jpcc.8b11343

[ACS Biomater. Sci. Eng. 20195, 2482–2490.] In Vivo Human Cartilage Formation in Three-Dimensional Bioprinted Constructs with a Novel Bacterial Nanocellulose Bioink
Apelgren, Peter; Karabulut, Erdem; Amoroso, Matteo; Mantas, Athanasios; MartÃ?nez Ã?vila, HÃ?ctor; KÃ?lby, Lars; Kondo, Tetsuo; Toriz, Guillermo; Gatenholm, Paul
Tag: BNCACC
https://doi.org/10.1021/acsbiomaterials.9b00157

[ACS Biomater. Sci. Eng. 20195, 2297–2306.] Transcutaneous Codelivery of Tumor Antigen and Resiquimod in Solid-in-Oil Nanodispersions Promotes Antitumor Immunity
Wakabayashi, Rie; Kono, Hidetoshi; Kozaka, Shuto; Tahara, Yoshiro; Kamiya, Noriho; Goto, Masahiro
Tag: LCOVAIFNTLRTAATLR7
https://doi.org/10.1021/acsbiomaterials.9b00260

エアロゲル 
[Biomacromolecules 201920, 2051–2057.] Formation of Nanofibrous Structure in Biopolymer Aerogel during Supercritical CO2 Processing: The Case of Chitosan Aerogel
Takeshita, Satoru; Sadeghpour, Amin; Malfait, Wim J.; Konishi, Arata; Otake, Katsuto; Yoda, Satoshi
Tag: NSAuCHITCHICTSCSAGCH3OH
https://doi.org/10.1021/acs.biomac.9b00246

[Biomacromolecules 201920, 1956–1964.] Recyclable Fully Biobased Chitosan Adsorbents Spray-Dried in One Pot to Microscopic Size and Enhanced Adsorption Capacity
Feng, Zhaoxuan; Danjo, Takahiro; Odelius, Karin; Hakkarainen, Minna; Iwata, Tadahisa; Albertsson, Ann-Christine
Tag: NaCLCHITCHICTSDCFCSZPMeMO
https://doi.org/10.1021/acs.biomac.9b00186

[Biomacromolecules 201920, 1849–1859.] Oligoarginine-Bearing Tandem Repeat Penetration-Accelerating Sequence Delivers Protein to Cytosol via Caveolae-Mediated Endocytosis
Okuda, Akiko; Tahara, Shinya; Hirose, Hisaaki; Takeuchi, Toshihide; Nakase, Ikuhiko; Ono, Atsushi; Takehashi, Masanori; Tanaka, Seigo; Futaki, Shiroh
Tag: CPPCDsiRNAFPIgGIgRArgGFPeGFPEGFPMe
https://doi.org/10.1021/acs.biomac.8b01299

ポリアクリルアミド 膜タンパク質 
[ACS Omega 20194, 8341–8349.] Entropy-Driven Mechanisms between Disulfide-Bond Formation Protein A (DsbA) and B (DsbB) in Escherichia coli
Yazawa, Kenjiro; Furusawa, Hiroyuki
Tag: ICQCMBPAGEQCMSDS-PAGEC12H25CysETCECNaDSUQnPAAmMPPAe-SDSCat
https://doi.org/10.1021/acsomega.9b00474

ポリアクリルアミド 膜タンパク質 
[ACS Omega 20194, 8341–8349.] Entropy-Driven Mechanisms between Disulfide-Bond Formation Protein A (DsbA) and B (DsbB) in Escherichia coli
Yazawa, Kenjiro; Furusawa, Hiroyuki
Tag: ICQCMBPAGEQCMSDS-PAGEC12H25CysETCECNaDSUQnPAAmMPPAe-SDSCat
https://doi.org/10.1021/acsomega.9b00474

ナノワイヤー 
[ACS Omega 20194, 8299–8304.] Water?Organic Cosolvent Effect on Nucleation of Solution-Synthesized ZnO Nanowires
Akihiro, Yuya; Nagashima, Kazuki; Hosomi, Takuro; Kanai, Masaki; Anzai, Hiroshi; Takahashi, Tsunaki; Zhang, Guozhu; Yasui, Takao; Baba, Yoshinobu; Yanagida, Takeshi
Tag: tBuOHtBut-BuBuTBADMKNWACE
https://doi.org/10.1021/acsomega.9b00945

金属有機構造体 (MOF) 
[Chem. Eur. J. 201925, 6698–6702.] Synthesis of Chiral Labtb and Visualization of Its Enantiomeric Excess by Induced Circular Dichroism Imaging
Yamada, Teppei; Eguchi, Toshiki; Wakiyama, Taro; Narushima, Tetsuya; Okamoto, Hiromi; Kimizuka, Nobuo
Tag: ICDSGLaFPheMPABSeeMOFMeCDCMOFMO
https://doi.org/10.1002/chem.201900329

[Chem. Eur. J. 201925, 6712–6717.] Peripheral Modifications of meso-Hydroxyporphyrins: Formation of Ï?-Electronic Anions and Ion-Pairing Assemblies
Sasano, Yoshifumi; Haketa, Yohei; Tanaka, Hiroki; Yasuda, Nobuhiro; Hisaki, Ichiro; Maeda, Hiromitsu
Tag: Phe-
https://doi.org/10.1002/chem.201901095

[Chem. Eur. J. 201925, 6741–6752.] Influence of Alkoxy Chain Length on the Properties of Two-Dimensionally Expanded Azulene-Core-Based Hole-Transporting Materials for Efficient Perovskite Solar Cells
Truong, Minh Anh; Lee, Jaehyun; Nakamura, Tomoya; Seo, Ji-Youn; Jung, Mina; Ozaki, Masashi; Shimazaki, Ai; Shioya, Nobutaka; Hasegawa, Takeshi; Murata, Yasujiro; Zakeeruddin, Shaik Mohammed; GrÃ?tzel, Michael; Murdey, Richard; Wakamiya, Atsushi
Tag: TAAPSCOBuHTMPCE275-51-4ELMeSCe-PAlk
https://doi.org/10.1002/chem.201806317

[Chem. Eur. J. 201925, 6797–6806.] Reductive Rearrangement of Tetraphenyldiphosphine Disulfide To Trigger the Bisthiophosphinylation of Alkenes and Alkynes
Sato, Yuki; Nishimura, Misaki; Kawaguchi, Shin-ichi; Nomoto, Akihiro; Ogawa, Akiya
Tag: OPCP
https://doi.org/10.1002/chem.201900073

ナノ粒子 
[Chem. Eur. J. 201925, 6807–6813.] Self-Supported ZIF-Derived Co3O4 Nanoparticles-Decorated Porous N-Doped Carbon Fibers as Oxygen Reduction Catalyst
Song, Li; Tang, Jing; Wang, Tao; Wu, Chao; Ide, Yusuke; He, Jianping; Yamauchi, Yusuke
Tag: DMECECNFCOCFGlymeESPNPNDCe-CCat
https://doi.org/10.1002/chem.201900197

[ChemSusChem 201912, 1775–1793.] Recent Advances in the Development of Molecular Catalyst-Based Anodes for Water Oxidation toward Artificial Photosynthesis
Zahran, Zaki N.; Tsubonouchi, Yuta; Mohamed, Eman A.; Yagi, Masayuki
Tag: PVPECWOMCWOCAPSCCat
https://doi.org/10.1002/cssc.201802795

[ChemSusChem 201912, 1807–1824.] Molecular Catalysts Immobilized on Semiconductor Photosensitizers for Proton Reduction toward Visible-Light-Driven Overall Water Splitting
Morikawa, Takeshi; Sato, Shunsuke; Sekizawa, Keita; Arai, Takeo; Suzuki, Tomiko M.
Tag: PSHOPECMCVLSCVLDOWSC
https://doi.org/10.1002/cssc.201900441

[ChemSusChem 201912, 1825–1834.] Sodium Tantalate Photocatalysts Doped with Metal Cations: Why Are They Active for Water Splitting?
Onishi, Hiroshi
Tag: CBQESrHSSONaABSSCOWSe-EHIR
https://doi.org/10.1002/cssc.201802935

[ChemSusChem 201912, 1906–1910.] Visible-Light-Driven Photocatalytic Z-Scheme Overall Water Splitting in La5Ti2AgS5O7-based Powder-Suspension System
Song, Zhimin; Hisatomi, Takashi; Chen, Shanshan; Wang, Qian; Ma, Guijun; Li, Shikuo; Zhu, Xiaodi; Sun, Song; Domen, Kazunari
Tag: AQYHQYOVLVLDOEPOWSe-
https://doi.org/10.1002/cssc.201802306

ポルフィリン 
[ChemSusChem 201912, 1939–1948.] Promotive Effect of Bicarbonate Ion on Two-Electron Water Oxidation to Form H2O2 Catalyzed by Aluminum Porphyrins
Kuttassery, Fazalurahman; Sebastian, Abin; Mathew, Siby; Tachibana, Hiroshi; Inoue, Haruo
Tag: ECNaWOCPENa2CO3Pore-Cat
https://doi.org/10.1002/cssc.201900560

ナノ粒子 
[ChemSusChem 201912, 1958–1965.] Platinum Cocatalyst Loaded on Calcium Titanate Photocatalyst for Water Splitting in a Flow of Water Vapor
Yoshida, Hisao; Yamada, Ryoko; Yoshida, Tomoko
Tag: CaHPtOPtNPNPCat
https://doi.org/10.1002/cssc.201802799

[ChemSusChem 201912, 1977–1983.] Cu3MS4 (M=V, Nb, Ta) and its Solid Solutions with Sulvanite Structure for Photocatalytic and Photoelectrochemical H2 Evolution under Visible-Light Irradiation
Ikeda, Satoru; Aono, Naruhiko; Iwase, Akihide; Kobayashi, Hisayoshi; Kudo, Akihiko
Tag: SSPECSSRABSVLSC
https://doi.org/10.1002/cssc.201802702

ナノファイバー ナノ粒子 
[Chem. Rec. 201919, 843–858.] Peptide Nanomaterials Designed from Natural Supramolecular Systems
Inaba, Hiroshi; Matsuura, Kazunori
Tag: NAMNPNPNFBB
https://doi.org/10.1002/tcr.201800149

[Chem. Rec. 201919, 947–959.] Gold-Palladium Nanocluster Catalysts for Homocoupling: Electronic Structure and Interface Dynamics
Ehara, Masahiro; Priyakumar, U. Deva
Tag: ALGMNCAuPdESrdsMatHalMDe-CDFTAr
https://doi.org/10.1002/tcr.201800177

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