2019年5月17日のコンテンツから

きょうのどうぶつ

ちょっとかっこよくなったキジトラ。前々からちょっと不恰好なネコだなあと思っていましたが、理由がわかりました。足が短く、顔が小さい。動きが軽いようで、庭をぴょんぴょん跳ねながら走り回っていました。

[読みたい論文] 交換反応でボロン酸エステルをフリーのボロン酸にします

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4504

この手法にどれだけの意義があるのか正直わかりませんが、やり方としてはちょっと面白いと思います。


計算終わりました


略語を登録しました

SOR
steam oil ratio
PDSC
pressure differential scanning calorimeter
CWM
coal water mixture
WBR
water bleeding ratio
PAPE
polyhydric alcohol phosphate ester
SGG
simulated gasification gas
CTH
catalytic transfer hydrogenolysis
ECA
expanded clay aggregate
ASB
aluminum silicate ball
PCT
particle center temperature
WCOME
waste cooking oil methyl ester
PPBB
partial premixed bluff body
LYT
leaf yellow tea
GRBD
grapevine red blotch disease
TSS
total soluble solids
ALI
acute liver injury
CACS
cellulose assisted combustion synthesis
PSZB
pure silica zeolite beta
DBN
dynamic Bayesian network
EFA
extended finite automata
TSNMF
transfer semi nonnegative matrix factorization
VRHP
vapor recompression heat pump
BSC
breakthrough sulfur capacity
HMO
hydrogen manganese oxide
PSDF
particle size distribution function
WBE
wastewater-based epidemiology
ICC
intraclass correlation coefficient
YCWP
yeast cell wall particle
CRS
combination-responsive strategy
RMT
receptor-mediated targeting
TMR
tumor-microenvironment responsiveness
AJP
aerosol jet printing
CGFR
carrier gas flow rate


注目の記事やプレスリリース

超高精度平面回路計測技術により300 GHz帯で印刷配線の性能を評価 -未開拓周波数領域を利用した通信やセンサーの利用を加速-
(産業技術総合研究所)
https://www.aist.go.jp/aist_j/press_release/pr2019/pr20190517/pr20190517.html
X線照射で始まる超高速反応の観測に成功 レントゲンによるX線の発見から120年で初
(東北大学)
https://www.tohoku.ac.jp/japanese/2019/05/press20190517-01-X.html
新規マンガンモリブデン窒化物を自己燃焼反応で合成~複合窒化物を用いた新規材料の創出や触媒の開発に期待~
(北海道大学・山梨大学)
https://www.hokudai.ac.jp/news/2019/05/post-530.html
本学の提案課題が 2019 年度の地球規模課題対応国際科学 技術協力プログラム(SATREPS)に採択
(広島大学)
https://www.hiroshima-u.ac.jp/system/files/119255/本学の提案課題が2019年度の地球規模課題対応国際科学技術協力プログラム(SATREPS)に採択.pdf
多発性骨髄腫における遺伝子変異蓄積の分子メカニズムの一端を解明 -新たな治療標的としてのDNAシトシン脱アミノ化酵素の可能性-
(京都大学)
http://www.kyoto-u.ac.jp/ja/research/research_results/2019/190509_3.html
生物発光で複数マウスの脳活動を同時にライブ観察 -社会性行動を司る脳機能や精神疾患研究分野での新たな展開に期待-
(理化学研究所)
http://www.riken.jp/pr/press/2019/20190517_2/
我が家の我流インドカレーレシピ
(六本木で働くデータサイエンティストのブログ)
https://tjo.hatenablog.com/entry/2019/05/17/080000
有機合成反応で食品の品質管理 -乳製品に含まれるアクロレイン付加物を迅速・簡便に検出-
(理化学研究所)
http://www.riken.jp/pr/press/2019/20190517_1/

1981年はこんな年

人名反応など

Bogerピリジン合成 [Doi 1]
Corey−Itsuno還元 [Doi 1]
Danheiser環化 [Doi 1]
Hiraoカップリング [Doi 1]
Schöllkopf法 [Doi 1]

ノーベル化学賞

化学反応過程の理論的研究
(Kenichi Fukui, Roald Hoffmann)

できごと

スペースシャトル・コロンビアが初のスペースシャトルミッションで打ち上げ
パラオが自治領となる
最初のAIDS患者発見例
マハティール・ビン・モハマドがマレーシア首相となる
ダイアナ妃、チャールズ・ウィンザー(イギリス王子)と結婚
IBMがマイクロソフトのDOS搭載の「IBM PC」を発表
中国残留孤児が初来日
「力うどん」発売(エースコック)
日本初の新交通システムが神戸市で営業開始
ピンク・レディーが解散
「Dr.スランプ アラレちゃん」放送開始(フジテレビ)
「名犬ジョリィ放映開始」(NHK)
「オレたちひょうきん族」放送開始(フジテレビ)
「ドライペット」発売(エステー化学=エステー)
「常用漢字表」告示
「まんが水戸黄門」放映開始(東京12チャンネル=テレビ東京)
東京12チャンネルがテレビ東京に社名変更
「リアルゴールド」発売(日本コカ・コーラ)
「雪見だいふく」発売(ロッテ)
「なるほど!ザ・ワールド」放送開始(フジテレビ)
「じゃりン子チエ」放映開始(毎日放送)
「うる星やつら」放映開始(フジテレビ)
「FOCUS」創刊(新潮社)
ロス疑惑
「セーラー服と機関銃」上映
「北の国から」放送(フジテレビ)


オススメ論文

[Lab Chip 201919, 1828–1837.] A numbering-up strategy of hydrodynamic microfluidic filters for continuous-flow high-throughput cell sorting
Ozawa, Ryoken; Iwadate, Hideki; Toyoda, Hajime; Yamada, Masumi; Seki, Minoru
Tag: HTHDF
http://dx.doi.org/10.1039/C9LC00053D

[CrystEngComm 201921, 2985–2993.] Single crystal growth of bulk InGaZnO4 and analysis of its intrinsic transport properties
Tanaka, Yusuke; Wada, Kazuhiro; Kobayashi, Yuki; Fujii, Takenori; Denholme, Saleem J.; Sekine, Ryotaro; Kase, Naoki; Kimizuka, Noboru; Miyakawa, Nobuaki
Tag: HEXHxOSGSC
http://dx.doi.org/10.1039/C9CE00007K

[Chem. Commun. 201955, 5681–5684.] Efficient “turn-off??? fluorescence photoswitching in a highly fluorescent diarylethene single crystal
Ishida, Sanae; Kitagawa, Daichi; Kobatake, Seiya; Kim, Sunnam; Kurihara, Seiji; Fukaminato, Tuyoshi
Tag: FLDAEETSC
http://dx.doi.org/10.1039/C9CC02441G

[Chem. Commun. 201955, 5740–5742.] Rh(i)-Catalyzed [3+2] annulation reactions of cyclopropenones with amides
Haito, Akira; Chatani, Naoto
Tag: Alk
http://dx.doi.org/10.1039/C9CC02397F

[New J. Chem. 201943, 7233–7242.] New molecular design for blue BODIPYs
Wu, Zhiyuan; Fujita, Hikaru; Magdaong, Nikki Cecil M.; Diers, James R.; Hood, Don; Allu, Srinivasarao; Niedzwiedzki, Dariusz M.; Kirmaier, Christine; Bocian, David F.; Holten, Dewey; Lindsey, Jonathan S.
Tag: PSpTolACNANANTTolMeCNFLQYStPhMeTEtATriEAABSTEALSSPYDCMTolHCH2Cl2
http://dx.doi.org/10.1039/C9NJ01114E

ポルフィリン 
[New J. Chem. 201943, 7209–7232.] Annulated bacteriochlorins for near-infrared photophysical studies
Fujita, Hikaru; Jing, Haoyu; Krayer, Michael; Allu, Srinivasarao; Veeraraghavaiah, Gorre; Wu, Zhiyuan; Jiang, Jianbing; Diers, James R.; Magdaong, Nikki Cecil M.; Mandal, Amit K.; Roy, Arpita; Niedzwiedzki, Dariusz M.; Kirmaier, Christine; Bocian, David F.; Holten, Dewey; Lindsey, Jonathan S.
Tag: BChlFLTRQYABSNIRPorIR
http://dx.doi.org/10.1039/C9NJ01113G

[New J. Chem. 201943, 7269–7274.] The rational synthesis of aerosol-assisted alumina powders having uniform mesopores and highly accessible surfaces
Maruoka, Hirokazu; Kimura, Tatsuo
Tag: CCat
http://dx.doi.org/10.1039/C9NJ01319A

[New J. Chem. 201943, 7350–7354.] Optical and magnetic properties of trans-indigoË???? radical anions. Magnetic coupling between trans-indigoË???? (S = 1/2) mediated by intermolecular hydrogen N?H?Oî??C bonds
Konarev, Dmitri V.; Zorina, Leokadiya V.; Batov, Mikhail S.; Khasanov, Salavat S.; Otsuka, Akihiro; Yamochi, Hideki; Kitagawa, Hiroshi; Lyubovskaya, Rimma N.
Tag: HRRA
http://dx.doi.org/10.1039/C9NJ00802K

[New J. Chem. 201943, 7491–7501.] Thermo- and photo-stable symmetrical benzo[cd]indolenyl-substituted heptamethine cyanine dye carrying a tetrakis(pentafluorophenyl)borate that absorbs only near-infrared light over 1000 nm
Funabiki, Kazumasa; Yanagawa, Ryuta; Kubota, Yasuhiro; Inuzuka, Toshiyasu
Tag: MIClO4142-29-0ABSVLNIRDCMCH2Cl2IR
http://dx.doi.org/10.1039/C9NJ00867E

[Org. Chem. Front. 20196, 1372–1377.] Highly soluble C2v-symmetrical fullerene derivatives: efficient synthesis, characterization, and electrochemical study
Ma, Yue; Uchiyama, Kouya; Ueno, Hiroshi; Okada, Hiroshi; Moriyama, Hiroshi; Matsuo, Yutaka
Tag: DLSAgLSLDSECSMC60retDSLPhMeDLAAnHDCMTolHCH2Cl2
http://dx.doi.org/10.1039/C9QO00056A

有機発光ダイオード 
[Synth. Met. 2019252, 62–68.] TADF activation by solvent freezing: The role of nonradiative triplet decay and spin-orbit coupling in carbazole benzonitrile derivatives
Hosokai, T.; Nakanotani, H.; Santou, S.; Noda, H.; Nakayama, Y.; Adachi, C.
Tag: PrSOFLNPLemBNPhMeDFSOCcbzOLEDLETADFTolHLED
http://www.sciencedirect.com/science/article/pii/S0379677919301237

[Tetrahedron 201975, 2993–3000.] Neomacrophorin and premacrophorin congeners from Trichoderma sp. 1212-03
Nishiyama, Mami; Maeda, Hayato; Tonouchi, Akio; Hashimoto, Masaru
Tag: 110-83-8ECDCSCDe-MSDFT
http://www.sciencedirect.com/science/article/pii/S0040402019304089

[Tetrahedron Lett. 201960, 1493–1497.] Novel synthesis of 1,4-thiazin-2-one O-(tert-butyl) oximes and benzo[b][1,4]thiazin-2-one O-(tert-butyl) oximes in the presence of K2CO3/SiO2
Aoyama, Tadashi; Tashiro, Kenshiro; Hayakawa, Mamiko; Shimada, Shigeru; Ouchi, Akihiko
Tag: BrtBut-BuBuDBSB
http://www.sciencedirect.com/science/article/pii/S0040403919304149

三成分カップリング 
[Tetrahedron Lett. 201960, 1467–1470.] Organozinc-aided, HMPA-free, stoichiometric three-component coupling for the general synthesis of prostaglandins and stable prostacyclin analogs with biological significance
Koyama, Hiroko; Izumiseki, Atsuto; Suzuki, Masaaki
Tag: PGCATCCSC
http://www.sciencedirect.com/science/article/pii/S0040403919303867

[ACS Comb. Sci. 201921, 400–407.] Development of a High-Throughput Screening Method for Oxide-Ion Conductors and Its Application to Bismuth-Based Oxide Library Thin Films
Matsubara, Masato; Suzumura, Akitoshi; Tajima, Shin; Asahi, Ryoji
Tag: HTSCSDBiXRHTXRDTF
https://doi.org/10.1021/acscombsci.8b00193

[ACS Comb. Sci. 201921, 350–361.] An Inter-Laboratory Study of Zn?Sn?Ti?O Thin Films using High-Throughput Experimental Methods
Hattrick-Simpers, Jason; Zakutayev, Andriy; Barron, Sara C.; Trautt, Zachary T.; Nguyen, Nam; Choudhary, Kamal; DeCost, Brian; Phillips, Caleb; Kusne, A. Gilad; Yi, Feng; Mehta, Apurva; Takeuchi, Ichiro; Perkins, John D.; Green, Martin L.
Tag: PLDPVDFPVDHTNFELTF
https://doi.org/10.1021/acscombsci.8b00158

[ACS Sustainable Chem. Eng. 20197, 8868–8875.] Trimethyl Glycine as an Environmentally Benign and Biocompatible Organocatalyst for Ring-Opening Polymerization of Cyclic Carbonate
Saito, Tatsuya; Takojima, Kaoru; Oyama, Takafumi; Hatanaka, Shintaro; Konno, Takashi; Yamamoto, Takuya; Tajima, Kenji; Isono, Takuya; Satoh, Toshifumi
Tag: APCTOFPCQAamInFTMatGTMCGlyMALDIPTMCMALDI-TOFROPCIR
https://doi.org/10.1021/acssuschemeng.9b00884

[ACS Sustainable Chem. Eng. 20197, 8670–8677.] Utilization of Dealkaline Lignin as a Source of Sodium-Promoted MoS2/Mo2C Hybrid Catalysts for Hydrogen Production from Formic Acid
Kurnia, Irwan; Yoshida, Akihiro; Situmorang, Yohanes Andre; Kasai, Yutaka; Abudula, Abuliti; Guan, Guoqing
Tag: CHSNaCBFADNPM64-18-6HCOOHCCat
https://doi.org/10.1021/acssuschemeng.9b00488

[ACS Sustainable Chem. Eng. 20197, 8512–8521.] Macroporous Niobium Phosphate-Supported Magnesia Catalysts for Isomerization of Glucose-to-Fructose
Gao, Da-Ming; Shen, Yong-Bing; Zhao, Bohan; Liu, Qian; Nakanishi, Kazuki; Chen, Jie; Kanamori, Kazuyoshi; Wu, Huaping; He, Zhiyong; Zeng, Maomao; Liu, Haichao
Tag: GluMgNbGlc
https://doi.org/10.1021/acssuschemeng.9b00292

自己集合 ナノ粒子 
[ACS Sustainable Chem. Eng. 20197, 8331–8339.] One-Pot Hydrothermal Synthesis of Nitrogen Functionalized Carbonaceous Material Catalysts with Embedded Iron Nanoparticles for CO2 Hydrogenation
Guo, Lisheng; Zhang, Peipei; Cui, Yu; Liu, Guangbo; Wu, Jinhu; Yang, Guohui; Yoneyama, Yoshiharu; Tsubaki, Noritatsu
Tag: HTSFeSSACNpyrEDAEDNPSAPy123-75-1CCat
https://doi.org/10.1021/acssuschemeng.8b06795

[J. Chem. Educ. 201996, 998–1001.] Aqueous Dearomatization/Diels?Alder Cascade to a Grandifloracin Precursor
Shimizu, Emily; Cory, Brett; Hoang, Johnson; Castro, Giovanni G.; Jung, Michael E.; Vosburg, David A.
Tag: CAMS
https://doi.org/10.1021/acs.jchemed.8b00857

イオン液体 
[J. Chem. Theory Comput. 201915, 3008–3020.] The Fragment Molecular Orbital Method Based on Long-Range Corrected Density-Functional Tight-Binding
Vuong, Van Quan; Nishimoto, Yoshio; Fedorov, Dmitri G.; Sumpter, Bobby G.; Niehaus, Thomas A.; Irle, Stephan
Tag: PCMLRCDFTBEMIMFMOEMIEtCTMOTrpWMDSMDTBILPIESIEGSDFT
https://doi.org/10.1021/acs.jctc.9b00108

[J. Chem. Theory Comput. 201915, 2896–2912.] Spatially-Decomposed Free Energy of Solvation Based on the Endpoint Density-Functional Method
Ishii, Yoshiki; Yamamoto, Naoki; Matubayasi, Nobuyuki; Zhang, Bin W.; Cui, Di; Levy, Ronald M.
Tag: AlaAHSFESoltNH2MeEDHB
https://doi.org/10.1021/acs.jctc.8b01309

[J. Med. Chem. 201962, 4780–4781.] Correction to Synthesis of 11C-Labeled RXR Partial Agonist 1-[(3,5,5,8,8-Pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)amino]benzotriazole-5-carboxylic Acid (CBt-PMN) by Direct [11C]Carbon Dioxide Fixation via Organolithiation of Trialkyltin Precursor and PET Imaging Thereof
Shibahara, Osamu; Watanabe, Masaki; Takamura, Yuta; Yamada, Shoya; Akehi, Masaru; Sasaki, Takanori; Akahoshi, Akiya; Hanada, Takahisa; Hirano, Hiroyuki; Nakatani, Shunsuke; Nishioka, Hiromi; Takeuchi, Yasuo; Kakuta, Hiroki
Tag: COOH
https://doi.org/10.1021/acs.jmedchem.9b00617

[J. Med. Chem. 201962, 4669–4682.] Novel Deazaflavin Analogues Potently Inhibited Tyrosyl DNA Phosphodiesterase 2 (TDP2) and Strongly Sensitized Cancer Cells toward Treatment with Topoisomerase II (TOP2) Poison Etoposide
Kankanala, Jayakanth; Ribeiro, Carlos J. A.; Kiselev, Evgeny; Ravji, Azhar; Williams, Jessica; Xie, Jiashu; Aihara, Hideki; Pommier, Yves; Wang, Zhengqiang
Tag: PDEPh
https://doi.org/10.1021/acs.jmedchem.9b00274

[J. Med. Chem. 201962, 4656–4668.] Design, Synthesis, and Preclinical Characterization of Selective Factor D Inhibitors Targeting the Alternative Complement Pathway
Karki, Rajeshri G.; Powers, James; Mainolfi, Nello; Anderson, Karen; Belanger, David B.; Liu, Donglei; Ji, Nan; Jendza, Keith; Gelin, Christine F.; Mac Sweeney, Aengus; Solovay, Catherine; Delgado, Omar; Crowley, Maura; Liao, Sha-Mei; Argikar, Upendra A.; Flohr, Stefanie; La Bonte, Laura R.; Lorthiois, Edwige L.; Vulpetti, Anna; Brown, Ann; Long, Debby; Prentiss, Melissa; Gradoux, Nathalie; de Erkenez, Andrea; Cumin, Frederic; Adams, Christopher; Jaffee, Bruce; Mogi, Muneto
Tag: LPSBZABnNH2PRSerSAMGAMDIISPNH
https://doi.org/10.1021/acs.jmedchem.9b00271

[J. Med. Chem. 201962, 4483–4499.] Structure-Guided Drug Design of 6-Substituted Adenosine Analogues as Potent Inhibitors of Mycobacterium tuberculosis Adenosine Kinase
Crespo, Roberto; Dang, Qun; Zhou, Nian E.; Guthrie, Liam M.; Snavely, Thomas C.; Dong, Wen; Loesch, Kimberly A.; Suzuki, Takao; You, Lanying; Wang, Wei; O’Malley, Theresa; Parish, Tanya; Olsen, David B.; Sacchettini, James C.
Tag: MtbTBADO
https://doi.org/10.1021/acs.jmedchem.9b00020

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