2019年6月14日のコンテンツから

きょうのどうぶつ

この時季になってもまだやってくる、夏毛のたぬき。


[読みたい論文] 炭酸メチルナトリウムをC1源として使って非対称ケトンを合成します

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4523

二酸化炭素でなく炭酸メチルナトリウムなのがなぜなのか知りたいので、読みたい論文に追加しました。synthonだよsynthon。

計算終わりました

略語を登録しました

MSAE
metamaterial selective absorber emitter
TRMPS
time resolved multiple-probe spectroscopy
PDG
pressure densified glass
WLED
white light emitting device
DCN
dual-crosslink network

注目の記事やプレスリリース

電力使用の削減未達量を検出する技術を世界で初めて開発 ~スパース再構成を利用し、少ないデータで高速かつ正確に~
(名古屋大学)
http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20190614_engg1.pdf
ワイル粒子がつなぐ量子化された伝導を観測
(東京大学)
https://www.t.u-tokyo.ac.jp/foe/press/setnws_201906141357157406869563.html
大阪平野が持つ地中熱ポテンシャルを「見える化」 -地下水資源を活かした新たな都市づくりに向けて-
(産業技術総合研究所)
https://www.aist.go.jp/aist_j/press_release/pr2019/pr20190614/pr20190614.html
構造多型検出アルゴリズムの包括的評価 -既存の検出手法より最適手法の提示が可能に-
(理化学研究所)
http://www.riken.jp/pr/press/2019/20190614_2/
電力使用の削減未達量を検出する技術を世界で初めて開発 ~スパース再構成を利用し、少ないデータで高速かつ正確に~
(科学技術振興機)
https://www.jst.go.jp/pr/announce/20190614-2/index.html
「酸素」が手足の形作りの進化に重要な役割を果たしていることを発見 四肢動物の陸上進出に伴う環境変化によって、手足を形作るメカニズム「指間細胞死」が誕生
(東京工業大学)
https://www.titech.ac.jp/news/2019/044484.html
体温レベルの温度でDNAの高速増幅に成功 分子ロボットから核酸検査まで、どこでも使える増幅法
(東京工業大学)
https://www.titech.ac.jp/news/2019/044389.html
電力使用の削減未達量を検出する技術を世界で初めて開発 ~スパース再構成を利用し、少ないデータで高速かつ正確に~
(北海道大学)
https://www.hokudai.ac.jp/news/190614_pr.pdf
スピン流が機械的な動力を運ぶことを実証 ~ミクロな量子力学からマクロな機械運動を生み出す新手法~
(科学技術振興機)
https://www.jst.go.jp/pr/announce/20190613/index.html
スピン流が機械的な動力を運ぶことを実証 -ミクロな量子力学からマクロな機械運動を生み出す新手法-
(理化学研究所)
http://www.riken.jp/pr/press/2019/20190614_1/
スピン流が機械的な動力を運ぶことを実証 ~ミクロな量子力学からマクロな機械運動を生み出す新手法~
(東北大学)
https://www.tohoku.ac.jp/japanese/2019/06/press20190614-01-micro.html

2000年はこんな年

人名反応など

Liebeskind−Sroglカップリング [Doi 1]
MacMillan触媒 [Doi 1]

ノーベル化学賞

導電性高分子の発見と開発
(Alan Jay Heeger, Alan Graham MacDiarmid, Hideki Shirakawa)

できごと

2000年問題の発生が注目されたが大きな問題は起きず
「プロジェクトX~挑戦者たち~」放送開始(NHK)
閏日問題で不具合
「PlayStation 2」発売
有珠山が23年ぶりに噴火
西鉄バスジャック事件
土曜ワイド劇場「相棒 警視庁ふたりだけの特命係」放送(テレビ朝日)
「TRICK」放送開始(テレビ朝日)
ヒトゲノム、ドラフト配列の終了を宣言
金融庁が発足
三宅島雄山噴火
「地上の星/ヘッドライト・テールライト」(中島みゆき)
「月光」(鬼束ちひろ)
「慎吾ママのおはロック」(慎吾ママ)
鳥取県西部地震(M7.3)
SHOP99設立
「犬夜叉」放送開始(日本テレビ)
「はじめの一歩」放送開始(日本テレビ)
ストーカー規制法施行
BSデジタル放送開始
カルフール幕張が開店
インターネット博覧会が開幕


オススメ論文

自己組織化単分子膜 
[ACS Appl. Mater. Interfaces 201911, 21177–21183.] Rapid and Selective Deposition of Patterned Thin Films on Heterogeneous Substrates via Spin Coating
Zhang, Yuanyi; D’Ambra, Colton A.; Katsumata, Reika; Burns, Ryan L.; Somervell, Mark H.; , Rachel; Segalman, A.; Hawker, Craig J.; Bates, Christopher M.
Tag: MLSnSAM10025-78-2TFSC
https://doi.org/10.1021/acsami.9b05190

ポルフィリン 
[ACS Appl. Mater. Interfaces 201911, 20812–20819.] Solid-State, Near-Infrared to Visible Photon Upconversion via Triplet?Triplet Annihilation of a Binary System Fabricated by Solution Casting
Abulikemu, Aizitiaili; Sakagami, Yusuke; Heck, Claire; Kamada, Kenji; Sotome, Hikaru; Miyasaka, Hiroshi; Kuzuhara, Daiki; Yamada, Hiroko
Tag: ISCUCPFLTRQYemSSMatETMPRUBTETNIRsensPorIR
https://doi.org/10.1021/acsami.9b04148

[ACS Appl. Mater. Interfaces 201911, 20670–20677.] Fibroin-like Peptides Self-Assembling on Two-Dimensional Materials as a Molecular Scaffold for Potential Biosensing
Li, Peiying; Sakuma, Kouhei; Tsuchiya, Shohei; Sun, Linhao; Hayamizu, Yuhei
Tag: NSAAECSAP
https://doi.org/10.1021/acsami.9b04079

[ACS Sustainable Chem. Eng. 20197, 9881–9887.] Effects of Coapplication of Rh-Doping and Ag-Substitution on the Band Structure of Li2TiO3 and the Photocatalytic Property
Watanabe, Kenta; Iwase, Akihide; Nozawa, Shunsuke; Adachi, Shin-ichi; Kudo, Akihiko
Tag: VBVLWBGMO
https://doi.org/10.1021/acssuschemeng.9b00513

[ACS Sustainable Chem. Eng. 20197, 9857–9864.] Synthesis of C2-Regioselectively Substituted Curdlan Acetate Propionate and the Effect of C2 Substituent on Their Properties
Chien, Chih-Ying; Enomoto, Yukiko; Iwata, Tadahisa
Tag: CURPWAXDOAcAAcXRDSCWAXRDBzHPhCHOXRDDP
https://doi.org/10.1021/acssuschemeng.9b00415

[ACS Sustainable Chem. Eng. 20197, 9750–9753.] Kinetic and Thermodynamic Requirements To Extend Solvent Compatibility in Thermal-Assisted Extraction of Inert Platinum Group Metals
Zheng, Zhiwei; Arai, Tsuyoshi; Takao, Koichiro
Tag: 111-87-5PtPGM
https://doi.org/10.1021/acssuschemeng.9b01622

[Biochemistry 201958, 2695–2702.] Non-Steady State Analysis of Enzyme Kinetics in Real Time Elucidates Substrate Association and Dissociation Rates: Demonstration with Analysis of Firefly Luciferase Mutants
Dale, Renee; Ohmuro-Matsuyama, Yuki; Ueda, Hiroshi; Kato, Naohiro
Tag: AAWTemFlucLucQSSCatRLU
https://doi.org/10.1021/acs.biochem.9b00272

[Ind. Eng. Chem. Res. 201958, 10114–10118.] Theoretical Evaluation of an Organic Phase Change Material (PCM)-Inserted Dual-Functional Adsorbent for the Recovery of Heat of Adsorption
Choi, Jihye; Yoshie, Kenichi; Moteki, Takahiko; Ogura, Masaru
Tag: PCMMSPCHOA
https://doi.org/10.1021/acs.iecr.9b00198

[Ind. Eng. Chem. Res. 201958, 9915–9920.] Effect of Alkanediol Additives on the Properties of Polyphenylene-Based Proton Exchange Membranes
Long, Zhi; Zhang, Yaojian; Miyake, Junpei; Miyatake, Kenji
Tag: PEMC12H25BuOctAlk
https://doi.org/10.1021/acs.iecr.9b01564

有機電界効果トランジスタ 有機半導体 
[J. Am. Chem. Soc. 2019141, 9373–9381.] Excellent Semiconductors Based on Tetracenotetracene and Pentacenopentacene: From Stable Closed-Shell to Singlet Open-Shell
Jousselin-Oba, Tanguy; Mamada, Masashi; Marrot, JÃ?rÃ?me; Maignan, Antoine; Adachi, Chihaya; Yassar, Abderrahim; Frigoli, Michel
Tag: OSVTShSESESRGSLBGABSFETSCOSCOFET92-24-0OSEMe-TF
https://doi.org/10.1021/jacs.9b03488

有機電界効果トランジスタ 有機半導体 
[J. Am. Chem. Soc. 2019141, 9373–9381.] Excellent Semiconductors Based on Tetracenotetracene and Pentacenopentacene: From Stable Closed-Shell to Singlet Open-Shell
Jousselin-Oba, Tanguy; Mamada, Masashi; Marrot, JÃ?rÃ?me; Maignan, Antoine; Adachi, Chihaya; Yassar, Abderrahim; Frigoli, Michel
Tag: OSVTShSESESRGSLBGABSFETSCOSCOFET92-24-0OSEMe-TF
https://doi.org/10.1021/jacs.9b03488

[J. Am. Chem. Soc. 2019141, 9349–9357.] Plastic/Ferroelectric Crystals with Easily Switchable Polarization: Low-Voltage Operation, Unprecedentedly High Pyroelectric Performance, and Large Piezoelectric Effect in Polycrystalline Forms
Harada, Jun; Kawamura, Yuto; Takahashi, Yukihiro; Uemura, Yohei; Hasegawa, Tatsuo; Taniguchi, Hiroki; Maruyama, Koji
Tag: PCEFpc
https://doi.org/10.1021/jacs.9b03369

[J. Am. Chem. Soc. 2019141, 9225–9238.] An Ultimate Stereocontrol in Supramolecular Photochirogenesis: Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Sulfur-Linked Î?-Cyclodextrin Dimers
Ji, Jiecheng; Wu, Wanhua; Liang, Wenting; Cheng, Guo; Matsushita, Ryohei; Yan, Zhiqiang; Wei, Xueqin; Rao, Ming; Yuan, De-Qi; Fukuhara, Gaku; Mori, Tadashi; Inoue, Yoshihisa; Yang, Cheng
Tag: CDSHT
https://doi.org/10.1021/jacs.9b01993

ポルフィリン 
[J. Am. Chem. Soc. 2019141, 9155–9159.] Photocatalytic Oxygenation Reactions with a Cobalt Porphyrin Complex Using Water as an Oxygen Source and Dioxygen as an Oxidant
, Young; Hong, Hyun; Han, Ji Won; Jung, Jieun; Nakagawa, Tatsuo; Lee, Yong-Min; Nam, Wonwoo; Fukuzumi, Shunichi
Tag: ACNANANTMeCNTRFFLHTREPRESRTAOCoABShmbVLH2TPPHPPorH2O2e-TON
https://doi.org/10.1021/jacs.9b02864

[Polym. Chem. 201910, 2960–2974.] Layer-by-layer assembly of nanofilms to control cell functions
Zeng, Jinfeng; Matsusaki, Michiya
Tag: LBLTEHT
http://dx.doi.org/10.1039/C9PY00305C

[Polym. Chem. 201910, 3116–3126.] Ferulic acid-based reactive core?shell latex by seeded emulsion polymerization
Li, Wing Sze Jennifer; Ladmiral, Vincent; Takeshima, Hisaaki; Satoh, Kotaro; Kamigaito, Masami; Semsarilar, Mona; Negrell, Claire; Lacroix-Desmazes, Patrick; Caillol, Sylvain
Tag: StC12H25RAcamInNaCLDSPhR107-22-2PhOHSEPSDSMDP
http://dx.doi.org/10.1039/C9PY00079H

[Inorg. Chem. Front. 20196, 1587–1597.] High-valence-state manganate(v) Ba3Mn2O8 as an efficient anode of a proton-conducting solid oxide steam electrolyzer
Toriumi, Hajime; Kobayashi, Taisei; Hinokuma, Satoshi; Ina, Toshiaki; Nakamura, Takashi; Amezawa, Koji; Zhu, Chunyu; Habazaki, Hiroki; Aoki, Yoshitaka
Tag: EXAFSECCTBaOABSOERECMe-
http://dx.doi.org/10.1039/C9QI00253G

[Chem. Commun. 201955, 6831–6834.] Mechanochromic dendrimers: the relationship between primary structure and mechanochromic properties in the bulk
Watabe, Takuma; Ishizuki, Kuniaki; Aoki, Daisuke; Otsuka, Hideyuki
http://dx.doi.org/10.1039/C9CC03011E

[Chem. Commun. 201955, 6850–6853.] Enhancement of exon skipping activity by reduction in the secondary structure content of LNA-based splice-switching oligonucleotides
Shimo, Takenori; Tachibana, Keisuke; Kawawaki, Yuki; Watahiki, Yuuka; Ishigaki, Taku; Nakatsuji, Yusuke; Hara, Takashi; Kawakami, Junji; Obika, Satoshi
Tag: SSO
http://dx.doi.org/10.1039/C8CC09648A

カーボンナノチューブ 
[Chem. Commun. 201955, 6854–6857.] Brighter near-IR emission of single-walled carbon nanotubes modified with a cross-linked polymer coating
Nagai, Yukiko; Yudasaka, Masako; Kataura, Hiromichi; Fujigaya, Tsuyohiko
Tag: NTSWCNTCPLemCNTNIRIR
http://dx.doi.org/10.1039/C9CC02712B

[CrystEngComm 201921, 3552–3556.] Two-step epitaxial growth of NbON (100) thin films on rutile-type TiO2 (101) substrates and reduction of residual carrier concentration by RF reactive sputtering
Kikuchi, Ryosuke; Nakamura, Toru; Kaneko, Yasushi; Hato, Kazuhito
Tag: TF
http://dx.doi.org/10.1039/C9CE00478E

[CrystEngComm 201921, 3557–3567.] Mineralization of magnetic nano-tape in self-organized nanospace composed of nucleopeptides and peptides
Murai, Kazuki; Inagaki, Kaede; Hiraoka, Chisato; Minoshima, Sayaka; Kinoshita, Takatoshi; Nagata, Kenji; Higuchi, Masahiro
Tag: NSHMAGHB
http://dx.doi.org/10.1039/C9CE00146H

固体酸化物形燃料電池 
[J. Mater. Chem. A 20197, 13910–13916.] Direct evidence for two-dimensional oxide-ion diffusion in the hexagonal perovskite-related oxide Ba3MoNbO8.5???Î?
Yashima, Masatomo; Tsujiguchi, Takafumi; Fujii, Kotaro; Niwa, Eiki; Nishioka, Shunta; Hester, James R.; Maeda, Kazuhiko
Tag: EEMEMOHEXHxFCONDOVOvacSOFCP
http://dx.doi.org/10.1039/C9TA03588E

[Dalton Trans. 201948, 8053–8056.] Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand
Dale, Sarah; Bonanno, Nico M.; Pelaccia, Mark; Lough, Alan J.; Miyawaki, Atsuhiro; Takahashi, Kazuyuki; Lemaire, Martin T.
Tag: MVOSICVTECRCTSSIVCTLESC
http://dx.doi.org/10.1039/C9DT01788G

[Dalton Trans. 201948, 8068–8075.] A water-soluble cyclometalated iridium(iii) complex for pH sensing based on aggregation-induced enhanced phosphorescence
Ohno, Keiji; Sakata, Tetuya; Shiiba, Machi; Nagasawa, Akira; Fujihara, Takashi
Tag: HCTemSSSBAIEP
http://dx.doi.org/10.1039/C8DT04861D

[Molecular Catalysis 2019472, 1–9.] Rh-catalyzed 1,4-addition reactions of arylboronic acids accelerated by co-immobilized tertiary amine in silica mesopores
Motokura, Ken; Hashiguchi, Kohei; Maeda, Kyogo; Nambo, Masayuki; Manaka, Yuichi; Chun, Wang-Jae
Tag: MSTMPBANH2CEATONCatSiH4
http://www.sciencedirect.com/science/article/pii/S2468823119301981

[J. Organomet. Chem. 2019894, 39–42.] Hydridoaluminates and hydridoborates of lithium stabilized by a Cyclen-derived NNNN-Type macrocyclic ligand
Lemmerz, Lara E.; Mukherjee, Debabrata; Spaniol, Thomas P.; Okuda, Jun
Tag: cyclenLiXRSCXRDXRDSCM
http://www.sciencedirect.com/science/article/pii/S0022328X19301809

[Tetrahedron 201975, 3553–3569.] Reductive coupling of aliphatic cyclic imides and Ï?-amidoesters with benzophenones by low-valent titanium: Synthesis of 5-diarylmethylene-1,5-dihydropyrrol-2-ones, 6-diarylmethyl-2-pyridones, and Ï?-(diarylmethylene)lactams
Kise, Naoki; Kinameri, Syn; Sakurai, Toshihiko
Tag: AsnBLGAEAsxGluTiNGlnQBZPBP
http://www.sciencedirect.com/science/article/pii/S0040402019305320

[Tetrahedron 201975, 3657–3665.] Selective synthesis and optical properties of diimidazo[1,2-a:5′,1′-c]quinoxaline derivatives
Matsumoto, Shoji; Abe, Shunsuke; Akazome, Motohiro
Tag: Be-Ar
http://www.sciencedirect.com/science/article/pii/S0040402019305939

[Tetrahedron 201975, 3650–3656.] Gold-catalyzed chemoselective formal (3+2)-Annulation reaction between Î?-naphthols and methyl aryldiazoacetate
Harada, Shingo; Sakai, Chigaya; Tanikawa, Koki; Nemoto, Tetsuhiro
Tag: AuCuCMeRhC
http://www.sciencedirect.com/science/article/pii/S0040402019305927

[Tetrahedron 201975, 3650–3656.] Gold-catalyzed chemoselective formal (3+2)-Annulation reaction between Î?-naphthols and methyl aryldiazoacetate
Harada, Shingo; Sakai, Chigaya; Tanikawa, Koki; Nemoto, Tetsuhiro
Tag: AuCuCMeRhC
http://www.sciencedirect.com/science/article/pii/S0040402019305927

超原子価ヨウ素 
[Tetrahedron 201975, 3617–3627.] Recyclable synthesis of mesityl iodonium(III) salts
Dohi, Toshifumi; Hayashi, Takumi; Ueda, Shohei; Shoji, Toshitaka; Komiyama, Keina; Takeuchi, Hitoshi; Kita, Yasuyuki
Tag: TFEIFGNuHVI
http://www.sciencedirect.com/science/article/pii/S0040402019305733

[Tetrahedron Lett. 201960, 1653–1657.] Pd(OAc)2-catalyzed orthogonal synthesis of 2-hydroxybenzoates and substituted cyclohexanones from acyclic unsaturated 1,3-carbonyl compounds
Miyagi, Toshinori; Okada, Sho; Tada, Naoya; Sugihara, Masahiro; Kagawa, Natsuko; Takabatake, Tetsuhiko; Toyota, Masahiro
Tag: H108-94-1Cat
http://www.sciencedirect.com/science/article/pii/S0040403919304848

凝集誘起発光 
[Tetrahedron Lett. 201960, 1663–1666.] Effect of water of crystallization on aggregation-induced emission in structurally similar crystals
Hayashi, Naoto; Okamoto, Naoki; Onoue, Masaya; Yamamoto, Kensuke; Yoshino, Junro
Tag: emAIE
http://www.sciencedirect.com/science/article/pii/S004040391930485X

[Tetrahedron Lett. 201960, 1682–1685.] Synthesis of poly condensed oxygen-containing helical heterocycles via rearrangement of benzofused-2,2′-diphenoquinone derivatives
Hossain, Md. Sharif; Inoue, Shota; Shahabuddin, Mohammad; Kimura, Takao; Karikomi, Michinori
Tag: CPDBLHetO110-00-9
http://www.sciencedirect.com/science/article/pii/S0040403919305052

[Tetrahedron Lett. 201960, 1732–1735.] Indium(III)-catalyzed intramolecular addition of silyl enolates to alkynes
Kinoshita, Hidenori; Negishi, Kenta; Fushimi, Saya; Miura, Katsukiyo
Tag: EElCat
http://www.sciencedirect.com/science/article/pii/S004040391930509X

[Tetrahedron Lett. 201960, 1702–1705.] Halogen-substituent effect on the spectroscopic properties of 2-phenyl-6-dimethylaminobenzothiazoles
Misawa, Rena; Matsuhashi, Chihiro; Yamaji, Minoru; Mutai, Toshiki; Yoshikawa, Isao; Houjou, Hirohiko; Noguchi, Keiichi; Maki, Shojiro; Hirano, Takashi
Tag: ISCFLAcQYemHalABSDMA95-16-9PhHAEe-C13H9NS
http://www.sciencedirect.com/science/article/pii/S0040403919305076

[Tetrahedron Lett. 201960, 1736–1740.] Microwave-assisted, rapid synthesis of 2-vinylquinolines and evaluation of their antimalarial activity
Huang, Guang; Solano, Claribel Murillo; Su, Yuxin; Ezzat, Nameer; Matsui, Shino; Huang, Liuyu; Chakrabarti, Debopam; Yuan, Yu
Tag: MIMWITfNH2
http://www.sciencedirect.com/science/article/pii/S0040403919305088

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