2019年7月5日のコンテンツから

きょうのどうぶつ

足摺岬の灯台の近くで見かけたネコ。千太郎かもしれませんが、近寄っても猫パンチは喰らいませんでした。足摺岬のあたりはイノシシが出没するようで、罠が仕掛けてありました。蝉の声が独特というかすごかった。


[読みたい論文] 添加剤不要!パラジウム触媒下でのビアリール合成

基質のチョイスがようわかららんので、読みたい論文に追加しました。

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4538


計算終わりました


略語を登録しました

CRACR
chemoselectively rapid azo-coupling reaction
CAP
chilled ammonia process
TMF
transfer matrix formalism


注目の記事やプレスリリース

「メッセンジャーRNA医薬を用いた脊髄損傷の新たな治療法を開発」 ― 神経機能修復・再生療法への応用に光! ―
(東京医科歯科大学)
http://www.tmd.ac.jp/archive-tmdu/kouhou/20190704_1.pdf
核医学治療中に放出されるα線放出核種の検出に成功 ~ 新しい放射線検出器開発によりα線放出核種の検出を実現 ~
(名古屋大学)
http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20190704_med1.pdf
学外の方も利用できる機器利用制度がスタート
(東京工業大学)
https://www.titech.ac.jp/news/2019/044629.html
絶滅危惧植物にのみ見られるゲノムの脆弱性を発見
(京都大学)
http://www.kyoto-u.ac.jp/ja/research/research_results/2019/190627_2.html
植物の酸化還元状態をリアルタイムで検知 チオレドキシンの酸化還元状態変化のセンサーを開発
(東京工業大学)
https://www.titech.ac.jp/news/2019/044644.html
亜鉛空気電池の二次電池化に資する電解質 -ポストリチウム大容量電池の実現へ一歩-
(産業技術総合研究所)
https://www.aist.go.jp/aist_j/new_research/2019/nr20190704/nr20190704.html
スーパーエルニーニョに対する強い台風の数の変動 ―台風の季節予測に向けた大気の内部変動の予測の重要性―
(東京大学)
https://www.aori.u-tokyo.ac.jp/research/news/2019/20190703.html
学ぶの論文紹介2019年6月号(その他の論文編
(有機化学を学ぶ人のブログ)
https://yuukiwomanabu.com/2019/07/04/学ぶの論文紹介2019年6月号(その他の論文編)/
学ぶの論文紹介2019年6月号(合成・医薬系編)
(有機化学を学ぶ人のブログ)
https://yuukiwomanabu.com/2019/07/04/学ぶの論文紹介2019年6月号(合成・医薬系編)/
学ぶの論文紹介2019年6月号(反応編)
(有機化学を学ぶ人のブログ)
https://yuukiwomanabu.com/2019/07/04/学ぶの論文紹介2019年6月号(反応編)/


2015年はこんな年

ノーベル化学賞

DNA修復の仕組みの研究
(Tomas Lindahl, Paul L. Modrich, Aziz Sancar)

できごと

スイス・フランの対ユーロの上限、1ユーロ=1.20フランを廃止
鳥取空港の愛称が「鳥取砂丘コナン空港」に
戦艦武蔵をシブヤン海海底で発見
姫路城天守閣の一般公開を再開
広島空港に着陸しようとしたアシアナ航空機が滑走路から外れ停止
日本の超電導リニア車両が有人走行実験で時速603キロを記録
ネパールで地震(M7.8)
2015年アムトラック脱線事故
「トリセツ」(西野カナ)
SIMロックの解除が義務化
箱根山に火口周辺警報を発表
口永良部島・新岳で爆発的噴火
小笠原諸島西方沖で地震(震源の深さは682km)、震度1以上の揺れを47都道府県全てで観測
中国株の大暴落
「バケモノの子」公開
「新宝島」(サカナクション)
IPv4アドレスの在庫が枯渇
スポーツ庁設置
防衛装備庁設置
「おそ松さん」放送
「365日の紙飛行機」(AKB48)


オススメ論文

[J. Membr. Sci. 2019587, 117184.] New insights into the relationship between draw solution chemistry and trace organic rejection by forward osmosis
Zheng, Lei; Price, William E.; McDonald, James; Khan, Stuart J.; Fujioka, Takahiro; Nghiem, Long D.
Tag: FOLMWSoltISRSF
http://www.sciencedirect.com/science/article/pii/S0376738819309585

[Chem. Eur. J. 201925, 8691–8695.] Cyclic Naphthalene Diimide Dimer with a Strengthened Ability to Stabilize Dimeric G-Quadruplex
Takeuchi, Ryusuke; Zou, Tingting; Wakahara, Daiki; Nakano, Yoshifumi; Sato, Shinobu; Takenaka, Shigeori
Tag: NpHM
https://doi.org/10.1002/chem.201901468

[Chem. Eur. J. 201925, 8701–8704.] Concise Construction of the ACDE Ring System of Calyciphylline???A Type Alkaloids by a [5+2] Cycloaddition
Nakamura, Hugh; Kawakami, Manami; Tsukano, Chihiro; Takemoto, Yoshiji
Tag: CvicCA
https://doi.org/10.1002/chem.201901690

[Chem. Eur. J. 201925, 8719–8724.] Triple Helical Ir(ppy)3 Phenylene Cage Prepared by Diol-Mediated Benzannulation: Synthesis, Resolution, Absolute Stereochemistry and Photophysical Properties
Sato, Hiroki; Blemker, Michelle A.; Hellinghausen, Garrett; Armstrong, Daniel W.; Nafie, Jordan W.; Roberts, Sean T.; Krische, Michael J.
Tag: IrO
https://doi.org/10.1002/chem.201902122

[Chem. Eur. J. 201925, 8797–8804.] Pyrrole-Based Ï?-System?PtII Complexes: Chiroptical Properties and Excited-State Dynamics with Microsecond Triplet Lifetimes
Hirata, Goki; Kobayashi, Yoichi; Sato, Ryuma; Shigeta, Yasuteru; Yasuda, Nobuhiro; Maeda, Hiromitsu
Tag: ISCTAABSPYSC
https://doi.org/10.1002/chem.201900848

[Chem. Eur. J. 201925, 8820–8828.] Pulsed EPR Dipolar Spectroscopy under the Breakdown of the High-Field Approximation: The High-Spin Iron(III) Case
Abdullin, Dinar; Matsuoka, Hideto; Yulikov, Maxim; Fleck, Nico; Klein, Christoph; Spicher, Sebastian; Hagelueken, Gregor; Grimme, Stefan; LÃ?tzen, Arne; Schiemann, Olav
Tag: HSESRIDMEe-
https://doi.org/10.1002/chem.201900977

プロトン伝導膜 
[J. Mater. Chem. A 20197, 15585–15592.] Acidic liquid-swollen polymer membranes exhibiting anhydrous proton conductivity higher than 100 mS cm???1 at around 100 °C
Kajita, Takato; Tanaka, Haruka; Noro, Atsushi; Matsushita, Yushu; Nakamura, Naoki
Tag: ahPCM
https://doi.org/10.1039/C9TA01890E

[CrystEngComm 201921, 3948–3953.] Surfactant-assisted synthesis of large Cu-BTC MOF single crystals and their potential utilization as photodetectors
Sun, Yu; Amsler, Maximilian; Goedecker, Stefan; Caravella, Alessio; Yoshida, Masaki; Kato, Masako
Tag: PDSC
https://doi.org/10.1039/C9CE00440H

[CrystEngComm 201921, 3910–3914.] Polarized fluorescence of a crystal having uniaxially oriented molecules by a carbazole-diyl-bridged macrocage
Hashimoto, Hikaru; Inagaki, Yusuke; Momma, Hiroyuki; Kwon, Eunsang; Yamaguchi, Kentaro; Setaka, Wataru
Tag: FLcbze-SC
https://doi.org/10.1039/C9CE00706G

[Chem. Commun. 201955, 7792–7795.] Development of 2-aminoisobutyric acid (Aib)-rich cell-penetrating foldamers for efficient siRNA delivery
Misawa, Takashi; Ohoka, Nobumichi; Oba, Makoto; Yamashita, Hiroko; Tanaka, Masakazu; Naito, Mikihiko; Demizu, Yosuke
Tag: AibAA
https://doi.org/10.1039/C9CC02203A

[Chem. Commun. 201955, 7760–7763.] 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(V) oxidant
Yusubov, Mekhman S.; Soldatova, Natalia S.; Postnikov, Pavel S.; Valiev, Rashid R.; Yoshimura, Akira; Wirth, Thomas; Nemykin, Victor N.; Zhdankin, Viktor V.
Tag: TfOHTFSATFMSAHOTfSC
https://doi.org/10.1039/C9CC04203B

イオン液体 
[Chem. Commun. 201955, 7737–7740.] Development of a novel ionic liquid–curcumin complex to enhance its solubility, stability, and activity
Chowdhury, Md. Raihan; Moshikur, Rahman Md; Wakabayashi, Rie; Tahara, Yoshiro; Kamiya, Noriho; Moniruzzaman, Muhammad; Goto, Masahiro
Tag: IL
https://doi.org/10.1039/C9CC02812A

クロスカップリング 
[Synth. Met. 2019254, 180–183.] Synthesis of conjugated polymer consisting of three-component aromatic units via two-step cross-dehydrogenative-coupling reactions
Tanaka, Chie; Kuwabara, Junpei; Yasuda, Takeshi; Kanbara, Takaki
Tag: CDCD-ACP327-54-8CCLECCR
http://www.sciencedirect.com/science/article/pii/S0379677919303716

[Tetrahedron 201975, 3977–3981.] Ring-size controlled dimerization of synthetic zinc chlorophyll derivatives possessing a 1-azacycloalkyl group through mutual coordination of amino moiety to central zinc atom
Watanabe, Hiroaki; Nakamura, Soichi; Tamiaki, Hitoshi
Tag: ZnNHxABSCHlMeDCMCDHexMCH2Cl2
http://www.sciencedirect.com/science/article/pii/S0040402019306672

[Tetrahedron 201975, 4042–4052.] Characterization and cytotoxicity of ellagitannins from Stachyurus praecox fruit
Orejola, Joanna; Luz, Mark Anthony; Matsuo, Yosuke; Saito, Yoshinori; Morita, Kouichi; Tanaka, Takashi
Tag: DMKACEDFT
http://www.sciencedirect.com/science/article/pii/S0040402019307094

[Tetrahedron Lett. 201960, 1929–1933.] Synthesis and conformational analysis of N-aryl-N-(6-azulenyl)acetamides
Ito, Ai; Ishii, Ayako; Amaki, Takamasa; Fukuda, Kazuo; Yamasaki, Ryu; Okamoto, Iwao
Tag: e-Ar
http://www.sciencedirect.com/science/article/pii/S0040403919305805

トリフルオロメチル化合物 
[Tetrahedron Lett. 201960, 1924–1928.] Silica gel-mediated self-aldol reactions of highly volatile aldehydes under organic solvent-free conditions without reflux condenser
Tanemura, Kiyoshi
Tag: SFCDMKrfxpipPIPDTFMACE
http://www.sciencedirect.com/science/article/pii/S0040403919305817

クロスカップリング 
[Chem. Asian J. 201914, 2230–2234.] Acetylene and trans-Ethylene Bridged BIII-Subporphyrin Dimers
Bekki, Yosuke; Kang, Seongsoo; Kim, Dongho; Osuka, Atsuhiro
Tag: FLTRQYStTAC2H2ABSCCLSSC2H4CCR
https://doi.org/10.1002/asia.201900547

[ChemBioChem 201920, 1684–1687.] Hemoglobin(Î?C93A)?Albumin Cluster: Mutation of Cysteine-Î?93 to Alanine Allows Moderate Reduction of O2 Affinity by Inositol Hexaphosphate
Morita, Yoshitsugu; Igarashi, Keisuke; Funaki, Ryosuke; Komatsu, Teruyuki
Tag: HbAlaCysACMIHSARBCSA
https://doi.org/10.1002/cbic.201900079

[Eur. J. Inorg. Chem. 20192019, 2977–2981.] Isolation of a Relatively Air-Stable, Bulky Silyl-Substituted, Neutral Silicon-Centered Radical
Holzner, Richard; Kaushansky, Alexander; Tumanskii, Boris; Frisch, Philipp; Linsenmann, Fabian; Inoue, Shigeyoshi
Tag: CVCVRSiSSORBSC
https://doi.org/10.1002/ejic.201900522

[Angew. Chem. Int. Ed. 201958, 9394–9398.] Directional Charge Transport in Layered Two-Dimensional Triazine-Based Graphitic Carbon Nitride
Noda, Yu; Merschjann, Christoph; TarÃ?bek, JÃ?n; Amsalem, Patrick; Koch, Norbert; Bojdys, Michael J.
Tag: CNECCTRGCNLBGFETSCe-
https://doi.org/10.1002/anie.201902314

[Angew. Chem. Int. Ed. 201958, 9389–9393.] A Purified, Solvent-Intercalated Precursor Complex for Wide-Process-Window Fabrication of Efficient Perovskite Solar Cells and Modules
Ozaki, Masashi; Shimazaki, Ai; Jung, Mina; Nakaike, Yumi; Maruyama, Naoki; Yakumaru, Shinya; Rafieh, Alwani Imanah; Sasamori, Takahiro; Tokitoh, Norihiro; Ekanayake, Piyasiri; Murata, Yasujiro; Murdey, Richard; Wakamiya, Atsushi
Tag: Me2SOPSCDMSOMAPIPCEP
https://doi.org/10.1002/anie.201902235

[Angew. Chem. Int. Ed. 201958, 9425–9428.] An Isolable Silicon Analogue of a Ketone that Contains an Unperturbed Si=O Double Bond
Kobayashi, Ryo; Ishida, Shintaro; Iwamoto, Takeaki
Tag: EDGSiXRSCXRDLBDBXRDe-SC
https://doi.org/10.1002/anie.201905198

クロスカップリング 
[Angew. Chem. Int. Ed. 201958, 9439–9442.] Synthesis of a Strained Spherical Carbon Nanocage by Regioselective Alkyne Cyclotrimerization
Hayase, Norihiko; Nogami, Juntaro; Shibata, Yu; Tanaka, Ken
Tag: CNCCemSCCCC
https://doi.org/10.1002/anie.201903422

[Angew. Chem. Int. Ed. 201958, 9522–9526.] Cell-Penetrating Dynamic-Covalent Benzopolysulfane Networks
Cheng, Yangyang; Zong, Lili; LÃ?pez-Andarias, Javier; Bartolami, Eline; Okamoto, Yasunori; Ward, Thomas R.; Sakai, Naomi; Matile, Stefan
Tag: SretDCN
https://doi.org/10.1002/anie.201905003

クロスカップリング 
[Angew. Chem. Int. Ed. 201958, 9547–9550.] Unprecedented Regioregular Poly(1,4-arylene)s Prepared by Nickel(II)-Catalyzed Cross-Coupling Polymerization of 2,5-Disubstituted Bromo(chloro)arylene
Shibuya, Yushin; Nakagawa, Naoki; Miyagawa, Naoki; Suzuki, Toyoko; Okano, Kentaro; Mori, Atsunori
Tag: NiHalHTCCCDC
https://doi.org/10.1002/anie.201903791

[Angew. Chem. Int. Ed. 201958, 9581–9585.] Viscoelastic Conjugated Polymer Fluids
Shinohara, Akira; Pan, Chengjun; Guo, Zhenfeng; Zhou, Liyang; Liu, Zhonghua; Du, Lei; Yan, Zhichao; Stadler, Florian J.; Wang, Lei; Nakanishi, Takashi
Tag: FLCPVESCAlk
https://doi.org/10.1002/anie.201903148

金属有機構造体 (MOF) ポルフィリン 
[Angew. Chem. Int. Ed. 201958, 9590–9595.] Photoconductivity in Metal?Organic Framework (MOF) Thin Films
Liu, Xiaojing; Kozlowska, Mariana; Okkali, Timur; Wagner, Danny; Higashino, Tomohiro; Brenner-WeiÃ?, Gerald; Marschner, Stefan M.; Fu, Zhihua; Zhang, Qiang; Imahori, Hiroshi; BrÃ?se, Stefan; Wenzel, Wolfgang; WÃ?ll, Christof; Heinke, Lars
Tag: photocondLBLD-AC60CSMOFDAPELPore-TF
https://doi.org/10.1002/anie.201904475

[Angew. Chem. Int. Ed. 201958, 9611–9618.] On-Surface Evolution of meso-Isomerism in Two-Dimensional Supramolecular Assemblies
Park, Juyeon; Kim, Ju-Hyung; Bak, Sunmi; Tahara, Kazukuni; Jung, Jaehoon; Kawai, Maki; Tobe, Yoshito; Kim, Yousoo
Tag: SM
https://doi.org/10.1002/anie.201904290

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