2019年7月10日のコンテンツから

きょうのどうぶつ

お昼寝中の野ネズミ…と言いたいところですが、上半身がありません。食べられたのでしょう。


[読みたい論文] ピロ亜硫酸カリウムを二酸化硫黄源にしてスルホンを合成します。

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4541

ピロリン酸カリウムは使うことがなかったなぁ。


計算終わりました

略語を登録しました

MMPC
micro/mesoporous platelet carbon
DORA
dual orexin receptor antagonist
LRE
luciferin regenerating enzyme
EFG
electrochemically fluorinated graphene
SREF
stimulated Raman excited fluorescence
OCD
orbital current density
QOC
quasi optical cavity
SVI
sequential vapor infiltration
EDS
essential dynamics sampling
PAD
protein-associated domain
FPR
false-positive rate
FNR
false-negative rate
OCT
optimum cutting temperature
EER
exchange-enhanced reactivity
NBP
Ni-binding protein


注目の記事やプレスリリース

シロアリの配偶者探索における動き方の秘策を解明 -状況に応じた歩行パターンの使い分け-
(京都大学)
http://www.kyoto-u.ac.jp/ja/research/research_results/2019/190620_2.html

1939年はこんな年

人名反応など

Creighton法Gould−Jacobs反応 [Doi 1]
Marker反応 [Doi 1]
Meerweinアリール化 [Doi 1]

ノーベル化学賞

性ホルモンの研究 (Adolf Friedrich Johann Butenandt), ポリメチレン類およびテルペン類の研究
(Leopold Ru?i?ka)
できごとNHKがテレビ実験放送を公開
電気庁設置
米穀配給統制令法公布
アインシュタイン=シラードの手紙
ハインケル社(ドイツ)のHe178が世界初のジェット飛行に成功
チリで大地震(M8.3)
男鹿半島で地震(M6.6)
トルコで大地震(M8.0)
日本電気工業と昭和肥料が合併、昭和電工設立
東京芝浦電気(東芝)設立
大和自動車交通設立
大日本音楽著作権協会(日本音楽著作権協会)創立
東京高速鉄道(東京メトロ銀座線)新橋−渋谷間全通
東京地下鉄道と東京高速鉄道の乗り入れ運転開始(東京メトロ銀座線)
阪神梅田駅が地下化
毎日新聞社機ニッポンが世界一周
大日本航空がニューヨーク・横浜間の飛行に成功
日本国民の男子の長髪及び女子のパーマネントを禁止
映画「風と共に去りぬ」


オススメ論文

[ACS Catal. 20199, 6415–6424.] Deactivation Mechanism of Pd/CeO2?ZrO2 Three-Way Catalysts Analyzed by Chassis-Dynamometer Tests and in Situ Diffuse Reflectance Spectroscopy
Machida, Masato; Fujiwara, Ayumi; Yoshida, Hiroshi; Ohyama, Junya; Asakura, Hiroyuki; Hosokawa, Saburo; Tanaka, Tsunehiro; Haneda, Masaaki; Tomita, Atsuko; Miki, Takeshi; Iwashina, Katsuya; Endo, Yoshinori; Nakahara, Yunosuke; Minami, Shigekazu; Kato, Naohiro; Hayashi, Yoshiyuki; Goto, Hideki; Hori, Masao; Tsuda, Toyofumi; Miura, Kazuya; Kimata, Fumikazu; Iwachido, Kinichi
Tag: TRXROEMDRSTWCABSXASXRDe-CTPBGS
https://doi.org/10.1021/acscatal.9b01669

[ACS Catal. 20199, 6118–6123.] Reductive C?C Coupling by Desulfurizing Gold-Catalyzed Photoreactions
Zhang, Lumin; Si, Xiaojia; Yang, Yangyang; Witzel, Sina; Sekine, Kohei; Rudolph, Matthias; Rominger, Frank
Tag: StAuAAHRUVABSEElLEe-LEDBLAlk
https://doi.org/10.1021/acscatal.9b01368

光酸化還元触媒 
[ACS Catal. 20199, 6555–6563.] Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of α-CF2H-Substituted Ketones in Flow
Nakayama, Yoshiki; Ando, Gaku; Abe, Manabu; Koike, Takashi; Akita, Munetaka
Tag: FPCECRLFPPCDFTSES
https://doi.org/10.1021/acscatal.9b01312

CO2還元 
[ACS Catal. 20199, 6305–6319.] Role of a Hydroxide Layer on Cu Electrodes in Electrochemical CO2 Reduction
Iijima, Go; Inomata, Tomohiko; Yamaguchi, Hitoshi; Ito, Miho; Masuda, Hideki
Tag: ATRSEIRASGBCuECHCOCH3CH2OHECRSEIRAABSCPECO2RC2H4CCH4IRCatEtOH
https://doi.org/10.1021/acscatal.9b00896

[ACS Catal. 20199, 6425–6434.] Pt/TiH2 Catalyst for Ionic Hydrogenation via Stored Hydrides in the Presence of Gaseous H2
Wu, Qifan; Zhang, Chao; Arai, Masahiko; Zhang, Bin; Shi, Ruhui; Wu, Peixuan; Wang, Zhuangqing; Liu, Qiang; Liu, Ke; Lin, Weiwei; Cheng, Haiyang; Zhao, Fengyu
Tag: ETHTiCAL104-55-2e-CCat
https://doi.org/10.1021/acscatal.9b00917

[J. Org. Chem. 201984, 8602–8614.] Iron-Promoted Intramolecular Cascade Cyclization for the Synthesis of Selenophene-Fused, Quinoline-Based Heteroacenes
Sonawane, Amol D.; Kubota, Yasuhiro; Koketsu, Mamoru
Tag: AEFeSeNu91-22-5DCMCH2Cl2
https://doi.org/10.1021/acs.joc.9b01061

[J. Org. Chem. 201984, 8596–8601.] Topologically Controlled Synthesis of Reversible Macrocyclic Compounds in Microemulsions
Alqarni, Yanallah; Tabor, Rico F.; Saito, Kei
Tag: CMPDM
https://doi.org/10.1021/acs.joc.9b00913

ヒドロシリル化 
[J. Org. Chem. 201984, 8552–8561.] Theoretical Study on the Rhodium-Catalyzed Hydrosilylation of C?C and C?O Double Bonds with Tertiary Silane
Zhao, Liming; Nakatani, Naoki; Sunada, Yusuke; Nagashima, Hideo; Hasegawa, Jun-ya
Tag: NROSRETSrdsDMKDBACERhCCatSiH4
https://doi.org/10.1021/acs.joc.9b00959

[J. Org. Chem. 201984, 8380–8391.] Substitution of the Dimethylamino Group in Gramines and One-Pot Cyclization to Tetrahydro-Î?-carbolines Using a Triazine-Based Activating Agent
Fujita, Hikaru; Nishikawa, Riho; Sasamoto, Ozora; Kitamura, Masanori; Kunishima, Munetaka
Tag: Li244-63-3NH2DMANuMe
https://doi.org/10.1021/acs.joc.9b00039

[J. Phys. Chem. A 2019123, 5649–5659.] Time-Dependent Long-Range-Corrected Density-Functional Tight-Binding Method Combined with the Polarizable Continuum Model
Nishimoto, Yoshio
Tag: PCMTDLRCDFTBemABSTBDFT
https://doi.org/10.1021/acs.jpca.9b03713

[J. Phys. Chem. A 2019123, 5633–5639.] First-Principles Study of the Reaction Mechanism of CHO + H on Graphene Surface
Kayanuma, Megumi; Shoji, Mitsuo; Furuya, Kenji; Kamiya, Katsumasa; Aikawa, Yuri; Umemura, Masayuki; Shigeta, Yasuteru
Tag: ISMRAIMDMDSMDABMDOTSGS
https://doi.org/10.1021/acs.jpca.9b02345

[J. Phys. Chem. C 2019123, 16281–16287.] Quinone-Facilitated Coordinated Bipyrene and Polypyrene on Au(111) by Capture of Gold Adatoms
Liu, Xinbang; Du, Yongping; Timmer, Alexander; MÃ?nig, Harry; Wan, Xinling; Huang, Xinyan; Ji, Qingmin; Kan, Erjun; Ariga, Katsuhiko; Hill, Jonathan P.; Fuchs, Harald; Kong, Huihui
Tag: NSPEAuXPSBrPSSTMPyrPyDFT
https://doi.org/10.1021/acs.jpcc.9b04060

自己組織化単分子膜 
[J. Phys. Chem. C 2019123, 16127–16136.] Deviation from Point Dipole Analysis for Exciton Quenching in Quaterthiophene-Terminated Self-Assembled Monolayers on Au(111)
Osumi, Yuji; Yamada, Takashi; Ie, Yutaka; Kato, Hiroyuki S.
Tag: XRXRREETMLETSAMe-
https://doi.org/10.1021/acs.jpcc.9b01801

[J. Phys. Chem. C 2019123, 16034–16045.] Evaluation of the Electronic and Local Structure of Mn in Proton-Conducting Oxide, Ca(Zr,Mn)O3???Î?, To Elucidate a Direct Hydrogen Dissolution Reaction
Oishi, Masatsugu; Nakamura, Takashi; Watanabe, Iwao; Yamamoto, Takashi; Doi, Takuya; Ina, Toshiaki; Nitta, Kiyofumi; Amezawa, Koji; Okuyama, Yuji
Tag: HOOOVOvacABSXASe-P
https://doi.org/10.1021/acs.jpcc.9b03897

カーボンナノチューブ 
[J. Phys. Chem. Lett. 201910, 3744–3749.] Water Confined in Hydrophobic Cup-Stacked Carbon Nanotubes beyond Surface-Tension Dominance
Li, Qin-Yi; Matsushita, Ryo; Tomo, Yoko; Ikuta, Tatsuya; Takahashi, Koji
Tag: CANTCSCNTCHEMCNTHVTEMe-
https://doi.org/10.1021/acs.jpclett.9b00718

[J. Phys. Chem. Lett. 201910, 3710–3714.] Î?-Carotene Probes the Energy Transfer Pathway in the Photosystem II Core Complex
Yoneda, Yusuke; Nagasawa, Yutaka; Umena, Yasufumi; Miyasaka, Hiroshi
Tag: PSCSETRCCARABSCHlPSIIPheo
https://doi.org/10.1021/acs.jpclett.9b01072

膜タンパク質 
[J. Phys. Chem. Lett. 201910, 3615–3620.] pH-Responsive Binding Properties of Light-Harvesting Complexes in a Photosystem II Supercomplex Investigated by Thermodynamic Dissociation Kinetics Analysis
Kim, Eunchul; Watanabe, Akimasa; Sato, Ryoichi; Okajima, Keisuke; Minagawa, Jun
Tag: PSLHCPSIIMP
https://doi.org/10.1021/acs.jpclett.9b01208

[J. Phys. Chem. Lett. 201910, 3531–3535.] pH-Sensing Machinery of Excitation Energy Transfer in Diatom PSI?FCPI Complexes
Nagao, Ryo; Yokono, Makio; Ueno, Yoshifumi; Shen, Jian-Ren; Akimoto, Seiji
Tag: PSEETFLLHCETPSICHlSSF
https://doi.org/10.1021/acs.jpclett.9b01314

[Org. Lett. 201921, 5269–5272.] Multicomponent Ugi Reaction of Indole-N-carboxylic Acids: Expeditious Access to Indole Carboxamide Amino Amides
Zeng, Linwei; Sajiki, Hironao; Cui, Sunliang
Tag: INDCOOHNH2Ugi
https://doi.org/10.1021/acs.orglett.9b01871

[Org. Lett. 201921, 5252–5258.] 3-Thioaryne Intermediates for the Synthesis of Diverse Thioarenes
Nakamura, Yu; Miyata, Yoshihiro; Uchida, Keisuke; Yoshida, Suguru; Hosoya, Takamitsu
Tag: HetSAr
https://doi.org/10.1021/acs.orglett.9b01862

[Org. Lett. 201921, 5238–5242.] Cobalt-Catalyzed Tandem Radical Cyclization/C?C Coupling Initiated by Directed C?H Activation
Sun, Qiao; Yoshikai, Naohiko
Tag: RHetCoCAr
https://doi.org/10.1021/acs.orglett.9b01846

トリフルオロメチル化合物 
[Org. Lett. 201921, 5183–5186.] Asymmetric Michael Reaction of α-CF3 Thioester and α,Î?-Unsaturated Aldehyde Catalyzed by Diphenylprolinol Silyl Ether
Hayashi, Yujiro; Yamada, Tomoaki; Sato, Misaki; Watanabe, Shoya; Kwon, Eunsang; Iwasaki, Kotaro; Umemiya, Shigenobu
Tag: asMRpipPIPDTFM
https://doi.org/10.1021/acs.orglett.9b01774

[Org. Lett. 201921, 5162–5166.] Site-Selectivity of Prato Additions to C70: Experimental and Theoretical Studies of a New Thermodynamic Product at the dd-[5,6]-Junction
Liosi, Korinne; Romero-Rivera, Adrian; Semivrazhskaya, Olesya; Caniglia, Caravaggio D.; Garcia-Borràs, Marc; Trapp, Nils; Osuna, S�lvia; Yamakoshi, Yoko
Tag: XRSCXRDKPXRDSC
https://doi.org/10.1021/acs.orglett.9b01756

銅触媒 
[Org. Lett. 201921, 5152–5156.] Cu-Catalyzed Cross-Dehydrogenative Coupling of Heteroaryl C(sp2)?H and Tertiary C(sp3)?H Bonds for the Construction of All-Carbon Triaryl Quaternary Centers
Tang, Zhi; Liu, Zhili; Tong, Zhou; Xu, Zhihui; Au, Chak-Tong; Qiu, Renhua; Kambe, Nobuaki
Tag: CDCTPCRTPHINDcbz91-22-5Ar
https://doi.org/10.1021/acs.orglett.9b01755

[Org. Lett. 201921, 5006–5009.] Synthesis of 4-Deoxy Pyranosides via Catalyst-Controlled Site-Selective Toluoylation of Abundant Sugars
Yanagi, Masanori; Ueda, Yoshihiro; Ninomiya, Ryo; Imayoshi, Ayumi; Furuta, Takumi; Mishiro, Kenji; Kawabata, Takeo
Tag: C
https://doi.org/10.1021/acs.orglett.9b01549

[Org. Lett. 201921, 4991–4995.] BrÃ?nsted Acid-Initiated Formal [1,3]-Rearrangement Dictated by Î?-Substituted Ene-Aldimines
Jongwohan, Chanantida; Honda, Yasushi; Suzuki, Toshiyasu; Fujinami, Takeshi; Adachi, Kiyohiro; Momiyama, Norie
Tag: NH2
https://doi.org/10.1021/acs.orglett.9b01533

[Org. Lett. 201921, 4933–4938.] Synthesis of (2,2-Diborylvinyl)arenes by Rhodium-Catalyzed Desulfanylative gem-Diborylation of 2-Arylvinyl Sulfides
Uetake, Yuta; Isoda, Motoyuki; Niwa, Takashi; Hosoya, Takamitsu
Tag: BPDRhCB2Pin
https://doi.org/10.1021/acs.orglett.9b01253

[Nature Chemistry 201911, 644–652.] De novo macrocyclic peptides that specifically modulate Lys48-linked ubiquitin chains
Nawatha, Mickal; Rogers, Joseph M.; Bonn, Steven M.; Livneh, Ido; Lemma, Betsegaw; Mali, Sachitanand M.; Vamisetti, Ganga B.; Sun, Hao; Bercovich, Beatrice; Huang, Yichao; Ciechanover, Aaron; Fushman, David; Suga, Hiroaki; Brik, Ashraf
Tag: UbPCD
https://doi.org/10.1038/s41557-019-0278-x

[Nature Chemistry 201911, 669–675.] A catalytically active [Mn]-hydrogenase incorporating a non-native metal cofactor
Pan, Hui-Jie; Huang, Gangfeng; Wodrich, Matthew D.; Tirani, Farzaneh Fadaei; Ataka, Kenichi; Shima, Seigo; Hu, Xile
Tag: HTMMnCat
https://doi.org/10.1038/s41557-019-0266-1

[Bull. Chem. Soc. Jpn 201992, 1218–1225.] Development of a Flow-Injection ESR System for Evaluating the Lipophilic Alkoxyl Radical Eliminating Capacities (L-AREC) of Tocopherol Analogues and Unsaturated Fatty Acids
Sakurai, Yasuhiro; Yamaguchi, Tomoko; Ando, Kai; Kuwabara, Keiko; Nakajima, Hiroki; Morimoto, Chie; Yoshikawa, Shinichi; Niwa, Masumi; Miyake, Yusuke; Kanaori, Kenji; Nakajima, Akira; Tajima, Kunihiko
Tag: HAAOAcAEtESHRFAESRAlInUFAFIPhOHAcOEte-EA
https://doi.org/10.1246/bcsj.20190059

[Bull. Chem. Soc. Jpn 201992, 1211–1217.] Two-Way Chromic Systems Based on Tetraarylanthraquinodimethanes: Electrochromism in Solution and Mechanofluorochromism in a Solid State
Ishigaki, Yusuke; Sugawara, Kazuma; Yoshida, Masaki; Kato, Masako; Suzuki, Takanori
Tag: PXRDECETFLemSSXRXRDe-
https://doi.org/10.1246/bcsj.20190094

液晶 
[Bull. Chem. Soc. Jpn 201992, 1226–1233.] Self-Assembled Liquid-Crystalline Ion Conductors: Odd-Even Effects of Flexible Spacers Binding a Carbonate Moiety and an Aliphatic Rod-Like Core on Phase Transition Properties and Ion Conductivities
Mizumura, Yurika; HÃ?gberg, Daniel; Arai, Kenichiro; Sakuda, Junji; Soberats, Bartolome; Yoshio, Masafumi; Kato, Takashi
Tag: NSLCCLiLC
https://doi.org/10.1246/bcsj.20190076

[Bull. Chem. Soc. Jpn 201992, 1234–1236.] Sterilization Properties of Ozonated Water and Sodium Hypochlorite Assisted by Ultraviolet Irradiation
Maeno, Yuki; Kitaori, Noriyuki
Tag: UVNa
https://doi.org/10.1246/bcsj.20190023

配位高分子 有機半導体 
[Chem. Lett. 201948, 756–759.] Formation of Pores and Ï?-Stacked Columns in Benzothienobenzothiophene-based Linear Coordination Polymers
Koyama, Shohei; Iguchi, Hiroaki; Takaishi, Shinya; Cosquer, Goulven; Kumagai, Shohei; Takeya, Jun; Okamoto, Toshihiro; Yamashita, Masahiro
Tag: PCPOMOPyrMOSCOSCCPOSHOMO
https://doi.org/10.1246/cl.190276

[Chem. Lett. 201948, 764–767.] Fibronectin Coating on Implant Material Surface Attracted Both Osteoblasts and Bacteria
Cui, Xinnan; Hoshino, Yu; Miura, Yoshiko
Tag: FN
https://doi.org/10.1246/cl.190293

パラジウム触媒 
[Chem. Lett. 201948, 760–763.] Palladium-catalyzed One-step Synthesis of Symmetrical Diaryl Sulfones from Aryl Halides and a Sulfur Dioxide Surrogate
Tanaka, Hiromichi; Konishi, Hideyuki; Manabe, Kei
Tag: PdSCArSO2
https://doi.org/10.1246/cl.190300

全合成 ルテニウム触媒 
[Chem. Lett. 201948, 768–770.] Facile Construction of an α-(1-Cyclopentenyl)ketone Core by Ruthenium-catalyzed Hydrative Cyclization of 1,6-Allenyne: Total Synthesis of (+)-Myomontanone
Katagiri, Koichi; Kodera, Haruka; Tayu, Masanori; Saito, Nozomi
Tag: RuNuRu-catalyzed
https://doi.org/10.1246/cl.190202

[Chem. Lett. 201948, 771–774.] Synthesis of Seven-membered Ring Containing Difluoromethylene Unit by Sc(OTf)3-catalyzed Activation of Single C?F Bond in CF3 Group
Hisano, Naoya; Kimura, Daiki; Mori, Keiji
Tag: LA
https://doi.org/10.1246/cl.190280

ナノ粒子 
[Chem. Lett. 201948, 775–778.] Selective Hydrogen Production from Formate Using Nanoparticle with Homogeneously Polymer-dispersed Platinum Clusters
Minami, Yusuke; Muroga, Yumiko; Yoshida, Tomoko; Amao, Yutaka
Tag: ArPVPPVPONHfaPtPAANP64-18-6HCOOH
https://doi.org/10.1246/cl.190311

[Chem. Lett. 201948, 783–786.] Enantioselective Aza-Michael/Protonation Reactions in Water
Kitanosono, Taku; Sakai, Masaru; Zhu, Lei; Kobayashi, ShÅ?
Tag: NuMe
https://doi.org/10.1246/cl.190317

[Chem. Lett. 201948, 787–790.] A P?C Chelate, Protic 1,2-Dihydropyridin-2-ylidene Ruthenium Complex: Synthesis, Structure, and Reversible Deprotonation
Tashima, Naoto; Sawazaki, Taka; Kayaki, Yoshihito; Kuwata, Shigeki
Tag: bpACNANANTRuMeCNOAcANaNpH
https://doi.org/10.1246/cl.190253

カーボンナノチューブ 
[Chem. Lett. 201948, 791–794.] Meta-linkage Design of Bis-aryldiazonium Modifiers for Wavelength Tuning of Near Infrared Photoluminescence from Locally Functionalized Single-walled Carbon Nanotubes
Shiraki, Tomohiro; Yu, Boda; Shiraishi, Tomonari; Shiga, Tamehito; Fujigaya, Tsuyohiko
Tag: NTSWCNTCPLCNTNIRIR
https://doi.org/10.1246/cl.190203

カーボンナノチューブ ナノ粒子 
[Chem. Lett. 201948, 795–798.] Facile Preparation of Holey Carbon Nanotubes Assisted by Ag Nanoparticle Catalysts for High-performance Micro-supercapacitors
Gan, Lu; Xu, Cigang; Yang, Jiangrong; Ma, Yunfeng; Cai, Jinguang; Watanabe, Akira
Tag: NTSSACOCspFGCNTNPCCat
https://doi.org/10.1246/cl.190094

[Chem. Lett. 201948, 799–801.] Sodium-ion Intercalation Behavior of Graphitized Carbon Nanospheres Covered with Basal Plane
Kondo, Yasuyuki; Fukutsuka, Tomokazu; Miyazaki, Kohei; Miyahara, Yuto; Abe, Takeshi
Tag: GCCNaCNS
https://doi.org/10.1246/cl.190111

[ChemPhysChem 201920, 1698–1705.] Influence of Perfluorohexane-Enriched Atmosphere on Viscoelasticity and Structural Order of Self-Assembled Semifluorinated Alkanes at the Air-Water Interface
Mielke, SalomÃ?; Abuillan, Wasim; Veschgini, Mariam; Liu, Xianhe; Konovalov, Oleg; Krafft, Marie Pierre; Tanaka, Motomu
Tag: PFHMLGIGISAXGISAXSVEAWI
https://doi.org/10.1002/cphc.201900316

[ChemNanoMat 20195, 957–963.] COF-Derived N,P Co-Doped Carbon as a Metal-Free Catalyst for Highly Efficient Oxygen Reduction Reaction
Yang, Chao; Maenosono, Shinya; Duan, Jingui; Zhang, Xiaobin
Tag: COFCOCH3OHCORR
https://doi.org/10.1002/cnma.201900159

CO2還元 
[ChemElectroChem 20196, 3101–3107.] Electrochemical CO2 Reduction on Bimetallic Surface Alloys: Enhanced Selectivity to CO for Co/Au(110) and to H2 for Sn/Au(110)
Todoroki, Naoto; Tei, Hiroki; Miyakawa, Taku; Tsurumaki, Hiroto; Wadayama, Toshimasa
Tag: ARRHEHECMLSTMSTMCO2RECRPCD
https://doi.org/10.1002/celc.201900725

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