2019年7月11日のコンテンツから

きょうのどうぶつ

雨の朝のスズメ。雨の日には猫は庭を通り過ぎませんが、スズメは台風だろうがやってきます。


[読みたい論文] 光学活性アミンの絶対配置と光学純度をシッフ塩基にして決めます

https://nanoniele.jp/cgi-bin/archive/nanoniele_archive.pl?c=4542

不斉中心を持つ光学活性アミンの絶対配置と光学純度の新規な決定法について報告している論文のようです。


計算終わりました


略語を登録しました

TEM
transmittance electron microscopy
DAC
donor-acceptor cyclopropane
GLIP
gel-liquid interfacial polymerization
PSD
post source decay
DNIC
double nanocluster ion compound
SNIC
single nanocluster ion compound
LDP
London dispersion potential


注目の記事やプレスリリース

ヒトが『しっとり感』を感じるメカニズムを解明~化粧品・自動車・繊維・バーチャルリアリティに応用展開~
(山形大学)
https://www.yamagata-u.ac.jp/jp/information/press/2190710_01/
単独で普通の細胞を直に幹細胞に変えるステミン遺伝子の発見
(名古屋大学)
http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20190710_itbm1.pdf
定説覆す発見 10nmサイズの高品質マグネタイト作製で明らかに ~ナノエレクトロニクスへの展開とマグネタイトの性質の起源解明に期待~
(JST)
https://www.jst.go.jp/pr/announce/20190710-2/index.html
引っ張りに強いカーボンナノチューブの構造を特定 ~軽量で高強度な究極の構造材料の実現に一歩近づく~
(JST)
https://www.jst.go.jp/pr/announce/20190710/index.html


1940年はこんな年

人名反応など

Baudisch反応 [Doi 1]
Carroll転位 [Doi 1]
Cope転位 [Doi 1]
Kroll法Ramberg−Bäcklund反応

ノーベル化学賞

(該当者なし)

できごと

炭素14をMartin KamenとSam Rubenが発見
米国・科学者動員令1940
日本ニュース映画社(日本映画社)設立
武田化成株式会社(吉富製薬)設立
大阪朝日新聞と東京朝日新聞の題号を朝日新聞に統一
大日本航空が横浜-サイパン-パラオ間定期航空路を開始
勝鬨橋開通
艦上戦闘機にゼロ戦採用
勤労所得の源泉徴収開始
ハティ・マクダニエルがアカデミー賞助演女優賞を受賞


オススメ論文

[Organometallics 201938, 2597–2601.] 9-Aza-10-boraanthracene Stabilized by Coordination of an N-Heterocyclic Carbene and Its Methylated Cation: Synthesis, Structure, and Electronic Properties
Ishikawa, Yutaro; Suzuki, Katsunori; Yamashita, Makoto
Tag: lpESNHetABSNuNHCe-
https://doi.org/10.1021/acs.organomet.9b00310

[Chem. Lett. 201948, 802–810.] Enhanced Conformational Fluctuations during Protein Reactions
Terazima, Masahide
Tag: TR
https://doi.org/10.1246/cl.190195

[Chem. Lett. 201948, 820–823.] Determination of Molecular Orientation in Bi-analyte Mono-molecule Layer through Electrochemical Surface-enhanced Raman Scattering Measurements
Oyamada, Nobuaki; Minamimoto, Hiro; Wakisaka, Yumi; Murakoshi, Kei
Tag: MIECSERS
https://doi.org/10.1246/cl.190282

[Chem. Lett. 201948, 828–831.] Phase-selective Hydrothermal Synthesis of Metallic MoS2 at High Temperature
He, Daoping; Ooka, Hideshi; Li, Yamei; Jin, Fangming; Nakamura, Ryuhei
Tag: HTSCysCH
https://doi.org/10.1246/cl.190254

[Chem. Lett. 201948, 832–835.] Rice-husk-based Silicon-carbide-derived Carbon as an Electrode Material for Electric Double-layer Capacitors
Saito, Takahiro; Ishikawa, Shinji
Tag: CDCSSAEDLCEDLCSi
https://doi.org/10.1246/cl.190142

[Chem. Lett. 201948, 836–839.] Pb-free Sn Perovskite Solar Cells Doped with Samarium Iodide
Hamada, Kengo; Hirotani, Daisuke; Kamarudin, Muhammad Akmal; Nishimura, Kohei; Shen, Qing; Iikubo, Satoshi; Minemoto, Takashi; Yoshino, Kenji; Toyoda, Taro; Hayase, Shuzi
Tag: SmPSCP
https://doi.org/10.1246/cl.190163

[Chem. Lett. 201948, 840–843.] Disruption of Liquid Marbles Induced by Host-Guest Interaction
Kozuka, Shohei; Banno, Taisuke; Fujii, Syuji; Nakamura, Yoshinobu; Yusa, Shin-ichi
Tag: CDAdHAdaOTSMe
https://doi.org/10.1246/cl.190232

[Chem. Lett. 201948, 847–850.] Coupling of Two Microbeads Exhibiting Different Features of Oscillations in the Belousov-Zhabotinsky Reaction
Kuze, Masakazu; Hiranishi, Yuri; Okamoto, Yasunao; Shioi, Akihisa; Nakata, Satoshi
Tag: BZCERC
https://doi.org/10.1246/cl.190292

[Chem. Lett. 201948, 855–858.] Formation of Hydroxyapatite Crystals from Octacalcium Phosphate with Incorporated Succinate Ion under Hydrothermal Conditions
Yokoi, Taishi; Goto, Tomoyo; Kitaoka, Satoshi
Tag: XRHAPHAOCPsucXRD
https://doi.org/10.1246/cl.190258

[New J. Chem. 201943, 10894–10898.] Dicationic ditelluride salts stabilized by N-heterocyclic carbene
Nakata, Norio; Kawauchi, Fumihiko; Takahashi, Shintaro; Ishii, Akihiko
Tag: HetXRNHCXRD
https://doi.org/10.1039/C9NJ02138H

全合成 
[Angew. Chem. Int. Ed. 201958, 9851–9855.] Total Syntheses of (+)-Aquatolide and Related Humulanolides
Takao, Ken-ichi; Kai, Hirotaka; Yamada, Ai; Fukushima, Yuuki; Komatsu, Daisuke; Ogura, Akihiro; Yoshida, Keisuke
https://doi.org/10.1002/anie.201904404

[Angew. Chem. Int. Ed. 201958, 9856–9860.] Iridium-Catalyzed Direct C4- and C7-Selective Alkynylation of Indoles Using Sulfur-Directing Groups
Kona, Chandrababu Naidu; Nishii, Yuji; Miura, Masahiro
Tag: DGIrHetSINDFGPY
https://doi.org/10.1002/anie.201904709

[Angew. Chem. Int. Ed. 201958, 9984–9988.] Unexpected Macrocyclic Multinuclear Zinc and Nickel Complexes that Function as Multitasking Catalysts for CO2 Fixations
Takaishi, Kazuto; Nath, Bikash Dev; Yamada, Yuya; Kosugi, Hiroyasu; Ema, Tadashi
Tag: NiZnNH2CCat
https://doi.org/10.1002/anie.201904224

[Angew. Chem. Int. Ed. 201958, 9998–10002.] Stabilized Gallylene in a Pincer-Type Ligand: Synthesis, Structure, and Reactivity of PGaIP-Ir Complexes
Saito, Narumasa; Takaya, Jun; Iwasawa, Nobuharu
Tag: Ir
https://doi.org/10.1002/anie.201904968

[ChemSusChem 201912, 2936–2954.] Catalytic Performance of Nanoporous Metal Skeleton Catalysts for Molecular Transformations
Jin, Tienan; Terada, Masahiro; Bao, Ming; Yamamoto, Yoshinori
Tag: ECCCat
https://doi.org/10.1002/cssc.201900318

C-Hアリール化 
[ChemSusChem 201912, 3049–3053.] Iron-Catalyzed ortho C-H Arylation and Methylation of Pivalophenone N-H Imines
Xu, Wengang; Yoshikai, Naohiko
Tag: FeDGPivDCBCNCCat
https://doi.org/10.1002/cssc.201900164

[ChemSusChem 201912, 3115–3125.] Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis
Jamil, Md. A. R.; Siddiki, S. M. A. Hakim; Touchy, Abeda Sultana; Rashed, Md. Nurnobi; Poly, Sharmin Sultana; Jing, Yuan; Ting, Kah Wei; Toyao, Takashi; Maeno, Zen; Shimizu, Ken-ichi
Tag: RAZLNH2TGCat
https://doi.org/10.1002/cssc.201900365

[J. Polym. Sci. Part A: Polym. Chem. 201957, 1500–1507.] Interpolymer association of amphiphilic diblock copolymers bearing pendant siloxane and phosphorylcholine groups
Kozuka, Shohei; Kuroda, Keita; Ishihara, Kazuhiko; Yusa, Shin-ichi
Tag: LSCRPFLRCH3CH2OHDBCPRPPMPCBCPEtOH
https://doi.org/10.1002/pola.29407

[J. Polym. Sci. Part A: Polym. Chem. 201957, 1569–1579.] Control of thermal, mechanical, and optical properties of three-component maleimide copolymers by steric bulkiness and hydrogen bonding
Nagase, Soichiro; Miyama, Koki; Matsumoto, Akikazu
Tag: TgStHRInBuMIAABAnBATGHEATGAHEMHB
https://doi.org/10.1002/pola.29421

[J. Polym. Sci. Part A: Polym. Chem. 201957, 1564–1568.] Effect of oligo(spiroorthocarbonate)s on the volume shrinkage of epoxides during crosslinking by sulfonium salt-initiated cationic polymerization of epoxides
Mori, Yasuyuki; Sudo, Atsushi; Endo, Takeshi
Tag: CPCLPENT
https://doi.org/10.1002/pola.29420

[J. Polym. Sci. Part A: Polym. Chem. 201957, 1601–1605.] Toward one-pot olefin/thiophene block copolymers using an in situ ligand exchange
Leone, Amanda K.; Dewyer, Amanda L.; Kubo, Tomohiro; Zimmerman, Paul M.; McNeil, Anne J.
Tag: TPTPH109-67-1CBCP
https://doi.org/10.1002/pola.29426

[J. Polym. Sci. Part B: Polym. Phys. 201957, 952–960.] Preparation and Morphologies of AB6? Block-Graft Copolymers
Watanabe, Momoka; Asai, Yusuke; Takano, Atsushi; Matsushita, Yushu
Tag: LamPIPIPasPStPSLAP
https://doi.org/10.1002/polb.24850

[Eur. J. Inorg. Chem. 20192019, 3045–3052.] Heptacoordinate Structures of Organotin Halides with Three Phosphine Donors: Halogen-Substituent Effect on Geometry
Kameo, Hajime; Kawamoto, Tatsuya; Sakaki, Shigeyoshi; Bourissou, Didier; Nakazawa, Hiroshi
Tag: D-AHalpbpDFT
https://doi.org/10.1002/ejic.201900524

[Chem. Eur. J. 201925, 8987–8991.] Asymmetric Aza-Diels?Alder Reaction with Ion-Paired?Iron Lewis Acid?BrÃ?nsted Acid Catalyst
Tomifuji, Rei; Kurahashi, Takuya; Matsubara, Seijiro
Tag: CPCasLAABSDACPAe-CTOF
https://doi.org/10.1002/chem.201901563

[Chem. Eur. J. 201925, 8996–9000.] Total Syntheses of (???)-Secologanin, (???)-5-Carboxystrictosidine, and (???)-Rubenine
Rakumitsu, Kenta; Sakamoto, Jukiya; Ishikawa, Hayato
Tag: PSPictet-SpenglerINDMR
https://doi.org/10.1002/chem.201902073

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