[読みたい論文] ビニルエーテルのSuzuki−Miyaura型アリール化

Viewed: 12:09:35 in December 10, 2019

Posted: May 8, 2019

Highly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki−Miyaura Cross-Coupling of Alkenyl Ethers (Ho, Guo-Ming; Sommer, Heiko; Marek, Ilan)
Org. Lett. 2019, 21 (8), 2913−2917.

Keywords: Ni; Suzuki−Miyaura coupling; acac; DIBAL; PCy3

ニッケル触媒下でのビニルエーテルとアリールボロン酸の反応。炭素−炭素結合形成を経てスチレン類が生成します。Suzuki−Miyaura型反応ですね。


アルコキシル基が脱離基として使えることが知られるようになってからだいぶ時が経ちました。当時は驚いたものです。

反応機構を中心に知りたいことがたくさんありますので、読みたい論文に追加しました。

DIBAL。DIBALHとも表記しますが、有機アルミニウム化合物の一種ですね。下のような構造。触媒サイクルの中でどのような役割を果たすのか、おそらく還元剤としてなのでしょうが。


そしてタイトルとGraphical Abstractにもありますが、出発のアルケンと生成物の幾何異性。出発のビニルエーテルの幾何異性(E/Z)体の比が生成物のそれらとはどうも異なるようで、その違いがどこから来るのか、触媒サイクルの中でなのか、それとも単純に熱異性化によるものなのか、気になるところです。兎にも角にも反応機構。

この記事を書いた人
「牧岡ふうふ堂」オーナー。博士(工学)。
酒都圏在住。
某地方の国立系工業大学でアシスタントをしていました。 専門は有機反応・金属錯体(主に希土類)・π共役系。
twitterアカウントは@makiokafufudo(お仕事用)、@ymakioka(個人用)です。

 

1974年はこんな年

人名反応など
Overman転位 [Doi 1]
Rubottom酸化 [Doi 1] [Doi 2] [Doi 3]
ノーベル化学賞
高分子化学の理論、実験両面にわたる基礎研究
(Paul John Flory)
できごと
端島(軍艦島)が炭鉱閉鎖、無人島に
「モンチッチ人形」発売(セキグチ)
「あさげ」発売(永谷園)
ルバング島で小野田寛郎元少尉を発見
「ニュースセンター9時」放送開始(NHK総合)
ガッツ石松が王座獲得(WBC世界ライト級)
「花とゆめ」創刊(白泉社)
伊豆半島沖地震
セブン-イレブン第1号店
国土庁設置
七夕豪雨
ウォーターゲート事件
日本広告審査機構(JARO)設立
「ベルサイユのばら」初演(宝塚大劇場)
原子力船むつが放射線もれ事故
「暗記ペン」発売(トンボ鉛筆)
「宇宙戦艦ヤマト」放映
田中金脈問題
アメダスが運用開始

 

きょうのどうぶつ

ここの画像を使用しています。

カメラ目線のチャシロさん。

 

計算終わりました

 

あわせてどうぞ

SOHOのすすめ記事一覧 2019年
お仕事関係の記事のリストです(2019年)。

読みたい論文シリーズ − 2019年2Q
読みたいけと読んでいない論文を、構造式を描きながら紹介します(2019年4〜6月)。

 

[読みたい論文] フッ化アンモニウム塩とシリルアミンでベンジルC−H結合を切断
どっちがどっちなのだろう。
Org. Lett. 2019, 21 (8), 2588−2592.

[読みたい論文] アザボラフェナントレンの合成と光物性
今回は隅っこの方がアザボラ。
Org. Lett. 2019, 21 (8), 2550−2554.

[読みたい論文] アリールメチルスルフィドからのアリールカルボン酸エステル合成
ジメチルスルフィドが脱離します。
Org. Lett. 2019, 21 (8), 2518−2522.

[読みたい論文] 分子触媒でアルデヒドの端っこをメチレン化
ホルムアルデヒドを使います。
Org. Lett. 2019, 21 (8), 2509−2513.

[読みたい論文] 金属を使わないテトラアリールホスホニウム塩の合成
金属使うと厄介だったんですよね。
ACS Omega 2019, 4 (4), 6690−6696.

各元素がどの分野で活発に研究されているかをまとめました
毎日更新できるように頑張ります。

[読みたい論文] フラストレイテットルイスペアで金錯体
ヒドロアミノ化の触媒にもなります。
Chem. Commun. 2019, 55 (30), 4367−4370.

[読みたい論文] アミドの反応性をNMRで予測します
じれねじれてケミカルシフト
Chem. Commun. 2019, 55 (30), 4423−4426.

[読みたい論文] マグネシウム錯体によるフルオロ炭素−アミノ化反応
実験操作に気になるところありです。
Chem. Commun. 2019, 55 (30), 4339−4342.

[読みたい論文] 脱水素を経るカルボニルα炭素−アルケニル炭素結合形成反応
第4周期の遷移金属触媒で初。
J. Am. Chem. Soc. 2019, 141 (14), 2298−2301.

 

注目のWebコンテンツ

企業の組織と各部署の役割
(Chem-Station)
https://www.chem-station.com/blog/2019/05/busho.html

フラストレート磁性体の量子相転移の圧力・磁場制御を実現 三角格子反強磁性体の新しい量子相の発見
(東北大学)
https://www.tohoku.ac.jp/japanese/2019/04/press20190424-01-kinken.html#.XNIcfr-TRM4.twitter

つる草はハダニがいる植物には巻き付かないことを発見
(京都大学)
http://www.kyoto-u.ac.jp/ja/research/research_results/2019/190429_1.html

10連休 終わる
(ある女性研究者の日記)
https://sunnily.exblog.jp/30583887/

絶対零度付近で起こる超流動ヘリウム中の微粒子の不可解な動きは目には見えない量子渦が操っていたと明らかに
(理化学研究所)
http://www.riken.jp/pr/press/2019/20190508_1/

低エネルギー陽電子ビームの寿命測定をデジタル化して実用レベルを達成
(産業技術総合研究所)
https://www.aist.go.jp/aist_j/press_release/pr2019/pr20190508/pr20190508.html

世界初!DNAオリガミを融合した分子人工筋肉を開発
(東京工業大学)
https://www.titech.ac.jp/news/2019/044236.html

ヒ素化合物の毒性と治療薬への適応
(高純度化学研究所 公式ブログ)
https://www.kojundo.blog/legalmedicine/1737/

国立大学法人広島大学と株式会社 NTT ドコモとの 次世代通信方式5G 等を活用した研究協力に関する 協定書の締結について
(広島大学)
https://www.hiroshima-u.ac.jp/system/files/118727/プレスリリース(NTTドコモとの協定締結).pdf

 

注目の論文

[ChemPhysChem 20190507071112, 2019, 9−1126]
The Driving Force for the Acylation of Î-Lactam Antibiotics by L,D-Transpeptidase 2: Quantum Mechanics/Molecular Mechanics (QM/MM) Study
(Ibeji, Collins U.; Lawal, Monsurat M.; Tolufashe, Gideon F.; Govender, Thavendran; Naicker, Tricia; Maguire, Glenn E. M.; Lamichhane, Gyanu; Kruger, Hendrik G.; Honarparvar, Bahareh)
Tag: SE, MM, Cys, C, TS, RSE, QM, e-

[ChemPhysChem 20190507071113, 2019, 9−1110]
Light-Harvesting Antenna and Proton-Activated Photodynamic Effect of a Novel BODIPY−Fullerene C60 Dyad as Potential Antimicrobial Agent
(Agazzi, Maximiliano L.; Durantini, Javier E.; Gsponer, Natalia S.; Durantini, AndrÃs M.; Bertolotti, Sonia G.; Durantini, Edgardo N.)
Tag: PS, EC, ET, FL, C60, em, PD, O, ABS, SA, VL, LHA, e-

[ChemElectroChem 20190507071141, 2019, 9−2474]
Bismuth Oxysulfide Photoelectrodes with Giant Incident Photon-to-Current Conversion Efficiency: Chemical Stability in Aqueous Solutions
(Bondarenko, Evgeny A.; Streltsov, Eugene A.; Mazanik, Alexander V.; Kulak, Anatoly I.)
Tag: IX, Bi, S, PEC, SC

リチウムイオン二次電池  
[ChemElectroChem 2019050707122, 2019, 9−2456]
Electrochemical Characteristics of Cobaltosic Oxide in Organic Electrolyte According to Bode Plots: Double-Layer Capacitance and Pseudocapacitance
(Xu, Yinsheng; Wang, Shengping; Peng, Huiling; Yang, Zhigao; Martin, Darren J.; Bund, Andreas; Nanjundan, Ashok Kumar; Yamauchi, Yusuke)
Tag: EC, Li, TM, LIB, TMO, DLC, MO

[ChemElectroChem 20190507071216, 2019, 9−2448]
Modular Microfluidic Paper-Based Devices for Multi-Modal Cascade Catalysis
(Andersen, Nalin I.; Artyushkova, Kateryna; MatanoviÄ?, Ivana; Seow?Chavez, Madelaine; Hickey, David P.; Abdelloui, Sofiene; Minteer, Shelley D.; Atanassov, Plamen)
Tag: C, EC, CO2, GLY, SERS, C, Cat

[ChemElectroChem 20190507071234, 2019, 9−2430]
Improvement of the Electrochemical Behavior of (Sb, Sn, Cu)O Ceramic Electrodes as Electrochemical Advanced Oxidation Anodes
(Giner-Sanz, Juan J.; SÃnchez-Rivera, MarÃa J.; GarcÃa-GabaldÃn, Montserrat; Ortega, Emma M.; Mestre, Sergio; PÃrez-Herranz, ValentÃn)
Tag: EAOP, EC, R, AOP

[ChemElectroChem 20190507071322, 2019, 9−2350]
Electroanalysis of Pharmaceuticals on Boron-Doped Diamond Electrodes: A Review
(Sousa, Camila P.; Ribeiro, Francisco W. P.; Oliveira, Thiago M. B. F.; Salazar-Banda, Giancarlo R.; de?Lima-Neto, Pedro; Morais, Simone; Correia, Adriana N.)
Tag: BDD, B, BDDE, WB, e-

[Chem. Asian J. 2019050707141, 2019, 9−1577]
Time-Dependent Emission Enhancement of the Ethynylpyrene-o-Carborane Dyad and Its Application as a Luminescent Color Sensor for Evaluating Water Contents in Organic Solvents
(Nishino, Kenta; Yamamoto, Hideki; Ochi, Junki; Tanaka, Kazuo; Chujo, Yoshiki)
Tag: TD, em, DMK, DCM, ACE, CH2Cl2, THF, TDEE

[Chem. Asian J. 20190507071447, 2019, 9−1523]
Supramolecularly Bonded Layered Heterostructures Exhibiting HER Activity
(Kaur, Manjodh; Singh, Navin Kumar; Gupta, Uttam; Sarkar, Aritra; George, Subi J.; Rao, C. N. R.)
Tag: VdW, NS, H, VL, VLD, HER

[Chem. Asian J. 2019050707162, 2019, 9−1452]
Difluoroboron Chelation to Quinacridonequinone: A Synthetic Method for Air-Sensitive 6,13-Dihydroxyquinacridone via Boron Complexes
(Moriya, Koichiro; Shimada, Ryohei; Ono, Katsuhiko)
Tag: Ar, B, e-

[Chem. Asian J. 20190507071623, 2019, 9−1436]
Photocatalyst-free Synthesis of Indazolones under CO2 Atmosphere
(Yang, Tianbao; Lu, Huiai; Qiu, Renhua; Hong, Ling; Yin, Shuang-Feng; Kambe, Nobuaki)
Tag: NH2

[Chem. Asian J. 2019050707170, 2019, 9−1409]
2-Phenylquinoline–Sugar Hybrids as Photoswitchable α-Glucosidase Inhibitors
(Kitamura, Takashi; Okuyama, Mai; Takahashi, Daisuke; Toshima, Kazunobu)
Tag: Man

クロスカップリング  
[Chem. Asian J. 20190507071711, 2019, 9−1356]
Synthetic Approaches to Star-Shaped Molecules with 1,3,5-Trisubstituted Aromatic Cores
(Kotha, Sambasivarao; Meshram, Milind; Panguluri, Nageswara Rao; Shah, Vrajesh R.; Todeti, Saidulu; Shirbhate, Mukesh E.)
Tag: St, FL, PhH, BZ, CC, Ph, CCR, BB

ナノ粒子  
[Chem. Asian J. 20190507071712, 2019, 9−1344]
Multivalent Sialosides: A Tool to Explore the Role of Sialic Acids in Biological Processes
(Chaudhary, Preeti Madhukar; Toraskar, Suraj; Yadav, Rohan; Hande, Akshay; Yellin, Rina-Arad; Kikkeri, Raghavendra)
Tag: GP, C, NH2, NP

金属有機構造体 (MOF)  
[Chem. Asian J. 20190507071712, 2019, 9−1331]
Metal–Organic Framework (MOF)-Derived Nanoporous Carbon Materials
(Marpaung, Freddy; Kim, Minjun; Khan, Junayet Hossain; Konstantinov, Konstantin; Yamauchi, Yusuke; Hossain, Md. Shahriar A.; Na, Jongbeom; Kim, Jeonghun)
Tag: EC, C, MOF, ESS, C, Cat

[Chem. Asian J. 20190507071714, 2019, 9−1323]
Enantioselective Reaction of 2H-Azirines
(Nakamura, Shuichi)
Tag: DB, NH2, Nu, DA, Cat

CO2還元  
[ChemBioChem 20190507071748, 2019, 9−1196]
Enhanced Bio-Electrochemical Reduction of Carbon Dioxide by Using Neutral Red as a Redox Mediator
(Seelajaroen, Hathaichanok; Haberbauer, Marianne; Hemmelmair, Christine; Aljabour, Abdalaziz; Dumitru, Liviu Mihai; Hassel, Achim Walter; Sariciftci, Niyazi Serdar)
Tag: EIS, IS, C, EC, fa, CO2, WE, ECR, FE, CO2R, e-

[ChemBioChem 20190507071752, 2019, 9−1190]
Probing Colocalization of N-Ras and K-Ras4B Lipoproteins in Model Biomembranes
(Li, Lei; Dwivedi, Mridula; Patra, Satyajit; Erwin, Nelli; MÃbitz, Simone; Winter, Roland)
Tag: Pr, NC

[ChemBioChem 20190507071813, 2019, 9−1174]
Acetyl Coenzyme?A Analogues as Rationally Designed Inhibitors of Citrate Synthase
(Bello, Davide; Rubanu, Maria Grazia; Bandaranayaka, Nouchali; GÃtze, Jan P.; BÃhl, Michael; O'Hagan, David)
Tag: CoA, Asp, D, H, QM, Ac, O, F, CS, Me, HB, HB

[ChemBioChem 20190507071828, 2019, 9−1161]
Rational Structure-Based Design of Fluorescent Probes for Amyloid Folds
(Orts, Julien; Aulikki?WÃlti, Marielle; Ghosh, Dhiman; Campioni, Silvia; Saupe, Sven J.; Riek, Roland)
Tag: ALS, M

[ChemBioChem 20190507071835, 2019, 9−1150]
Hidden Specificities in Enzyme Catalysis: Structural Basis of Substrate Structure-Selectivity Relationship of a Ketoreductase
(HÃckh, Matthias; Lucas, Xavier; Marolt, Marija; Leadlay, Peter F.; MÃller, Michael; GÃnther, Stefan; LÃdeke, Steffen)
Tag: MM, KR, PK, O, KRED

[ChemBioChem 20190507071853, 2019, 9−1145]
Identifying the Biosynthetic Gene Cluster for Triacsins with an N-Hydroxytriazene Moiety
(Twigg, Frederick F.; Cai, Wenlong; Huang, Wei; Liu, Joyce; Sato, Michio; Perez, Tynan J.; Geng, Jiaxin; Dror, Moriel J.; Montanez, Ismael; Tong, Tate L.; Lee, Hyunsu; Zhang, Wenjun)
Tag: BGC

[ChemBioChem 20190507071913, 2019, 9−1129]
Hemoprotein-Catalyzed Cyclopropanation En Route to the Chiral Cyclopropanol Fragment of Grazoprevir
(Kim, Taejin; Kassim, Amude M.; Botejue, Ajit; Zhang, Chen; Forte, Jared; Rozzell, David; Huffman, Mark A.; Devine, Paul N.; McIntosh, John A.)
Tag: C, C3H6O

[Eur. J. Org. Chem. 2019050707214, 2019, 17−2832]
Thermolytic Reagents to Synthesize 5′- or 3′-Mono(thio)phosphate Oligodeoxynucleotides or 3′-modified oligodeoxynucleotides
(Madaoui, Mimouna; Meyer, Albert; Vasseur, Jean-Jacques; Morvan, FranÃois)
Tag: CE, ODN, NH3, MS

ルテニウム  
[Eur. J. Org. Chem. 20190507072123, 2019, 17−2807]
Ruthenium-Catalyzed Synthesis of Isoindolinones via Amide-Directed Addition of Aromatic C-H Bonds to Aldimines
(Miura, Hiroki; Kimura, Yuriko; Terajima, Sachie; Shishido, Tetsuya)
Tag: Ts, Tos, tosyl, CHB, Ru, Ru-catalyzed, C, Ar, Cat

[Eur. J. Org. Chem. 20190507072136, 2019, 17−2769]
Recent Developments in Radical-Mediated Transformations of Organohalides
(Lekkala, Ravindar; Lekkala, Revathi; Moku, Balakrishna; Rakesh, K. P.; Qin, Hua-Li)
Tag: OS, R, C

[Eur. J. Inorg. Chem. 20190507072139, 2019, 17−2312]
Characterization of an AX Compound Derived from Ti2SC MAX Phase
(Hasegawa, George; Kawahara, Kei; Shima, Kazunari; Inada, Miki; Enomoto, Naoya; Hayashi, Katsuro)
Tag: SPS, EC, Ti, S, DMK, ACE

[Eur. J. Inorg. Chem. 20190507072143, 2019, 17−2304]
Ammonothermal Synthesis of the Mixed-Valence Nitrogen-Rich Europium Tantalum Ruddlesden-Popper Phase EuIIEuIII2Ta2N4O3
(Cordes, Niklas; Nentwig, Markus; Eisenburger, Lucien; Oeckler, Oliver; Schnick, Wolfgang)
Tag: MV, N, Ta, SG, RP, SCD, SC, Eu

配位高分子  
[Eur. J. Inorg. Chem. 20190507072153, 2019, 17−2291]
TIMPZ: An Exquisite Building Block for Metal/Hydrogen Coordination Polymers
(LigiÃro, Carolina B. P.; Oliveira, Thiago V.; Fontes, ChÃrbel C. F.; Barragan, Josà T. C.; So, Fernanda W. Y.; Kubota, Lauro T.; Nome, Renà A.; Miranda, Paulo C. M. L.)
Tag: PT, FL, H, ABS, IPT, ESIPT, CP, BB, HB, HB

[Eur. J. Inorg. Chem. 20190507072156, 2019, 17−2284]
Synthesis and Characterization of Cyclometalated NHC Platinum Complexes with Chelating Carboxylate Ligands
(ZÃbranskÃ, Martin; Soellner, Johannes; HorkÃ, Filip; CÃsaÅovÃ, Ivana; Å tÄpniÄka, Petr; Strassner, Thomas)
Tag: AA, Pt, PL, PLQY, QY, em, acacH, C5H12, AmH, Me, Ph, AcOH

有機発光ダイオード  
[Eur. J. Inorg. Chem. 20190507072217, 2019, 17−2247]
New Boron(III) Blue Emitters for All-Solution Processed OLEDs: Molecular Design Assisted by Theoretical Modeling
(Salla, Cristian A. M.; Teixeira dos Santos, JÃssica; Farias, Giliandro; Bortoluzi, Adailton J.; Curcio, Sergio F.; Cazati, Thiago; IzsÃk, RÃbert; Neese, Frank; de Souza, Bernardo; Bechtold, Ivan H.)
Tag: B, FL, ES, em, ABS, EML, OLED, LE, EL, e-, LED, DFT

[Chem. Eur. J. 20190507072245, 2019, 25−6425]
Pluripotent Features of Doubly Thiophene-Fused Benzodiphospholes as Organic Functional Materials
(Higashino, Tomohiro; Ishida, Keiichi; Sakurai, Tsuneaki; Seki, Shu; Konishi, Tatsuki; Kamada, Kenji; Kamada, Kenji; Imahori, Hiroshi)
Tag: NLO, TP, TP, FL, ES, EC, TPH, NIRF, TPA, ABS, NIR, 2PA, e-, MGE, IR, P

[Chem. Eur. J. 20190507072249, 2019, 25−6402]
A Revised Structure Model for the UCl6 Structure Type, Novel Modifications of UCl6 and UBr5, and a Comment on the Modifications of Protactinium Pentabromides
(Deubner, H. Lars; Rudel, Stefan S.; Sachs, Malte; Pietzonka, Clemens; Karttunen, Antti J.; Ivlev, Sergei I.; MÃller, Matthias; Conrad, Matthias; MÃller, Ulrich; Kraus, Florian)
Tag: U, PC, O, Pa, QC, SG, SC

[Chem. Eur. J. 2019050707235, 2019, 25−6392]
Chemical and Electrochemical Lithiation of van der Waals Tetrel-Arsenides
(Mark, Justin; Hanrahan, Michael P.; Woo, Katherine E.; Lee, Shannon; Rossini, Aaron J.; Kovnir, Kirill)
Tag: PXRD, VdW, EC, SS, XR, SG, XRD

金属有機構造体 (MOF)  
[Chem. Eur. J. 20190507072333, 2019, 25−6349]
A Chemiluminescent Metal–Organic Framework
(RÃhle, Bastian; Virmani, Erika; Engelke, Hanna; Hinterholzinger, Florian M.; von?Zons, Tobias; Brosent, Birte; Bein, Thomas; Godt, Adelheid; Wuttke, Stefan)
Tag: TD, pht, FL, H, anth, ANT, AN, ox, Na, CL, TDF, MOF, HP, DBP, H2O2, TF

環化付加反応  
[Chem. Eur. J. 20190507072338, 2019, 25−6342]
Structural Distortion of Cycloalkynes Influences Cycloaddition Rates both by Strain and Interaction Energies
(Hamlin, Trevor A.; Levandowski, Brian J.; Narsaria, Ayush K.; Houk, Kendall N.; Bickelhaupt, F. Matthias)
Tag: DC, GS, 1,3-DC, C4H6, Me, HLG, CA

希土類  
[Chem. Eur. J. 20190507072353, 2019, 25−6326]
Efficient Separation of Light Lanthanides(III) by Using Bis-Lactam Phenanthroline Ligands
(Healy, Mary R.; Ivanov, Alexander S.; Karslyan, Yana; Bryantsev, Vyacheslav S.; Moyer, Bruce A.; Jansone-Popova, Santa)
Tag: REEs, REE, TM, RE, o-phen, phen

トリフルオロメチル化合物  
[Chem. Eur. J. 2019050707241, 2019, 25−6317]
Rhodium(III) Complexes Featuring Coordinated CF3 Appendages
(Emerson-King, Jack; Prokes, Ivan; Chaplin, Adrian B.)
Tag: SS, XR, lemonene, TFM, XRD, Rh

ルテニウム  
[Chem. Eur. J. 20190507072427, 2019, 25−6300]
Metal-Assisted Opening of Intact P4 Tetrahedra
(Modl, Moritz; Heinl, Sebastian; BalÃzs, Gabor; Delgado?Calvo, Fuencisla; Caporali, Maria; Manca, Gabriele; Keilwerth, Martin; Meyer, Karsten; Peruzzini, Maurizio; Scheer, Manfred)
Tag: Ru, ES, XR, SCXRD, Co, TM, XRD, e-, SC, Mn, P

[Chem. Eur. J. 20190507072446, 2019, 25−6295]
Efficient 1,3-Oxazolidin-2-one Synthesis through Heterogeneous PdII-Catalyzed Intramolecular Hydroamination of Propargylic Carbamates
(Oschmann, Michael; Placais, Clotilde; Nagendiran, Anuja; BÃckvall, Jan-E.; Verho, Oscar)
Tag: MCF, C

[Chem. Eur. J. 20190507072451, 2019, 25−6284]
A Mixed-Anion System Consisting of a Germyl Anion and Anions Delocalized on Conjugated Carbon Ring Skeletons
(Fujimori, Shiori; Mizuhata, Yoshiyuki; Tokitoh, Norihiro)
Tag: Ge, C, R, RA

ナノ粒子  
[ACS Omega 20190507072532, 2019, 4−7829]
Robust Superhydrophobic Cotton Fibers Prepared by Simple Dip-Coating Approach Using Chemical and Plasma-Etching Pretreatments
(Nguyen-Tri, Phuong; Altiparmak, Funda; Nguyen, Nam; Tuduri, Ludovic; Ouellet-Plamondon, Claudiane M.; Prud’homme, Robert E.)
Tag: CA, PE, F, NP, SNP, TEOS

[ACS Omega 20190507072540, 2019, 4−7838]
Simplified in Vitro and in Vivo Bioaccess to Prenylated Compounds
(Couillaud, Julie; Rico, Juan; Rubini, Alyssa; Hamrouni, Tarek; Courvoisier-Dezord, Elise; Petit, Jean-Louis; Mariage, Aline; Darii, Ekaterina; Duquesne, Katia; de Berardinis, VÃronique; Iacazio, Gilles)
Tag: GDP, THA, GG, ACP, Glu, Glc, terpene, DMA, Glu, Glu, DMADP, IPK, Tmp

[ACS Omega 20190507072614, 2019, 4−7815]
Preparation of Nanostructured Ta3N5 Electrodes by Alkaline Hydrothermal Treatment Followed by NH3 Annealing and Their Improved Water Oxidation Performance
(Abdel Haleem, Ashraf; Perumandla, Nagaraju; Naruta, Yoshinori)
Tag: RHE, H, O, Ta, WO, VL, SC, WOC, HF, SWS, C, P

自己集合  
[ACS Omega 20190507072640, 2019, 4−7807]
Diasteroselective Colloidal Self-Assembly Affects the Immunological Response of the Molecular Adjuvant Sulfavant
(Manzo, Emiliano; Gallo, Carmela; Fioretto, Laura; Nuzzo, Genoveffa; Barra, Giusi; Pagano, Dario; Krauss, Irene Russo; Paduano, Luigi; Ziaco, Marcello; DellaGreca, Marina; De Palma, Raffaele; Fontana, Angelo)
Tag: DLS, DCC, LS, LDS, DC, DAG, DSL, DLA, SA, M

[ACS Omega 20190507072655, 2019, 5−7911]
Natural Thermoresponsive Rice Granules as Biocompatible Drug Carriers
(Liu, Xue; Oungeun, Pongpat; Banlunara, Wijit; Leelahavanichkul, Asada; Wanichwecharungruang, Supason)
Tag: XR, EM, VAN, TG, XRD, e-, SEM, SEM, IR

[ACS Omega 20190507072743, 2019, 5−7963]
Profiling of Multiphosphorylated Peptides in Kefir and Their Release During Simulated Gastrointestinal Digestion
(Savastano, Maria; Liu, Yufang; Mels, Jennifer; Dittrich, Daniel; Haus, Sabrina; Gensberger-Reigl, Sabrina; Pischetsrieder, Monika)
Tag: GI, TOFMS, TOF, LC, ESI, Mat, HAP, HA, ABS, MS2, MS/MS, SGD, MS

[ACS Omega 20190507072746, 2019, 5−7953]
Dopamine Released from TiO2 Semicrystalline Lattice Implants Attenuates Motor Symptoms in Rats Treated with 6-Hydroxydopamine
(GÃmez-ChavarÃn, Margarita; Prado-Prone, Gina; Padilla, Patricia; RamÃrez Santos, JesÃs; GutiÃrrez-Ospina, Gabriel; GarcÃa-Macedo, Jorge A.)
Tag: 6-OHDA, OHDA, DA, LPO

ナノ粒子  
[J. Phys. Chem. C 20190507072755, 2019, 17−10720]
Effect of Nanoparticle Shape on the Electrical and Thermal Properties of Solid Polymer Electrolytes
(Vasudevan, Sandhya; Fullerton-Shirey, Susan K.)
Tag: AR, PEO, O, NP, SPE, MO, PE

イオン液体  
[J. Phys. Chem. C 2019050707287, 2019, 17−10727]
Effect of Ionic Liquid Structure on the Oxygen Reduction Reaction Under Humidified Conditions
(Doblinger, Simon; Lee, Junqiao; Silvester, Debbie S.)
Tag: AF, RTIL, CV, CV, EDL, py, Pt, am, O, ph, im, IL, RH, AFM, ORR

[J. Phys. Chem. C 20190507072938, 2019, 17−10857]
Selectivity of Photoelectrochemical Water Splitting on TiO2 Anatase Single Crystals
(Nebel, Roman; MacounovÃ, KateÅina; TarÃbkovÃ, Hana; Kavan, Ladislav; Krtil, Petr)
Tag: PZC, Fbp, RHE, H, O, PEC, WO, VFB, O3, SC

ナノ粒子  
[J. Phys. Chem. C 2019050707301, 2019, 17−10881]
High-Energy Electron-Beam-Induced Evolution of Secondary Phase and Enhanced Photocatalytic Activity in Monoclinic BiEuWO6 Nanoparticles
(Shanbogh, Pradeep; Petwal, V. C.; Dwivedi, J.; Rao, Ashok; Sundaram, Nalini G.)
Tag: FESEM, Ra, FL, em, XR, EM, CR, EB, FE, VL, SC, DRS, NP, HE, SSFE, XRD, SSF, FES, IBI, EBI, e-, SEM

ナノ粒子  
[J. Phys. Chem. C 20190507073136, 2019, 17−11032]
Dicopper Dioxygenase Model Immobilized in Mesoporous Silica Nanoparticles for Toluene Oxidation: A Mechanism to Harness Both O Atoms of O2 for Catalysis
(Liu, Chih-Cheng; Tsai, Yi-Fang; Mou, Chung-Yuan; Yu, Steve S.-F.; Chan, Sunney I.)
Tag: MS, MSN, HC, O, PhMe, M-vK, MSNP, NP, SNP, BzH, PhCHO, TolH, C, MO, Cat

熱活性化型遅延蛍光 有機発光ダイオード  
[J. Phys. Chem. C 20190507073234, 2019, 17−11109]
Persistent Dimer Emission in Thermally Activated Delayed Fluorescence Materials
(Etherington, Marc K.; Kukhta, Nadzeya A.; Higginbotham, Heather F.; Danos, Andrew; Bismillah, Aisha N.; Graves, David R.; McGonigal, Paul R.; Haase, Nils; Morherr, Antonia; Batsanov, Andrei S.; Pflumm, Christof; Bhalla, Vandana; Bryce, Martin R.; Monkman, Andrew P.)
Tag: EL, FL, PL, em, DF, cbz, OLED, LE, TADF, TF, LED, 4CzIPN

[J. Phys. Chem. C 20190507073240, 2019, 17−11134]
Extraction of One-Handed Helical Frontier Orbital in Even [n]Cumulenes by Breaking Mirror Images of Right- and Left-Handed Helical Orbitals: Theoretical Study
(Orimoto, Yuuichi; Aoki, Yuriko; Imamura, Akira)
Tag: lp, DB, EL

[J. Phys. Chem. C 20190507073239, 2019, 17−11118]
Synthesis, Optical, Electrochemical, DFT Studies, NLO Properties, and Ultrafast Excited State Dynamics of Carbazole-Induced Phthalocyanine Derivatives
(Bhattacharya, Somdatta; Biswas, Chinmoy; Raavi, Sai Santosh Kumar; Venkata Suman Krishna, Jonnadula; Vamsi Krishna, Narra; Giribabu, Lingamallu; Soma, Venugopal Rao)
Tag: TP, TRF, FL, TR, EC, em, TA, TPA, NLO, FSTA, ABS, cbz, TPACS, FLY, 2PA, Pc, Ph, Pht

有機発光ダイオード  
[J. Phys. Chem. C 20190507073253, 2019, 17−11140]
Predicting Phosphorescence Quantum Yield for Pt(II)-Based OLED Emitters from Correlation Function Approach
(Kim, Inkoo; Son, Won-Joon; Choi, Youn-Suk; Osipov, Alexey; Lee, Dongseon; Lee, Hasup; Jung, Yongsik; Son, Jhunmo; Choi, Hyeonho; Sotoyama, Wataru; Yakubovich, Alexander; Shin, Jaikwang; Lee, Hyo Sug)
Tag: TDM, TD, R, ISC, ECP, PL, PLQY, QY, Mat, OLED, RECP, LE, e-, LED, PQY

[J. Phys. Chem. C 20190507073327, 2019, 17−11189]
Polarized Tip-Enhanced Raman Spectroscopy in Understanding Metal-to-Insulator and Structural Phase Transition in VO2
(Basu, Raktima; Patsha, Avinash; Chandra, Sharat; Amirthapandian, S.; Karkala Gururaj, Raghavendra; Dasgupta, Arup; Dhara, Sandip)
Tag: Ra, TE, DOS, EM, TERS, SPT, HRTEM, TEM, pDOS, HRTEM, TEM, e-, DFT

[J. Phys. Chem. C 20190507073340, 2019, 17−11197]
Incorporation of Melittin Enhances Interfacial Fluidity of Bicontinuous Microemulsions
(Sharma, V. K.; Hayes, D. G.; Gupta, S.; Urban, V. S.; O’Neill, H. M.; Pingali, S. V.; Ohl, M.; Mamontov, E.)
Tag: DLS, LS, LDS, E, TM, C12H25, AMP, ML, Na, DS, DSL, NSE, DLA, SANS, 20449-79-0, SDS

[J. Phys. Chem. C 2019050707342, 2019, 17−11224]
Excited-State Intramolecular Proton-Transfer Process of Crystalline 6-Cyano-2-(2′-hydroxyphenyl)imidazo[1,2a]pyridine, as Revealed by Femtosecond Pump–Probe Microspectroscopy
(Ishibashi, Yukihide; Murakami, Mako; Araki, Koji; Mutai, Toshiki; Asahi, Tsuyoshi)
Tag: ps, TAS, PT, FL, H, CN, TA, GS, FSTA, ABS, IPT, ESIPT, THF

[J. Phys. Chem. C 2019050707342, 2019, 17−11233]
Theory and Kinetic Monte Carlo Simulation of Guest Molecule Transport in sI Clathrate Hydrates Based on Cage Hopping
(Chu, Lee-Shin; Wu, David T.; Lin, Shiang-Tai)
Tag: GM, KMC, MC, TPS, CH4

ナノ粒子  
[J. Phys. Chem. C 20190507073414, 2019, 17−11257]
Simulation of Colloidal Silver Nanoparticle Formation from a Precursor Complex
(Yoneya, Makoto; Sugisawa, Shin-ya)
Tag: Ag, ShS, OAm, NH2, AgNP, NP

[J. Phys. Chem. C 20190507073438, 2019, 17−11284]
Significant Increase in Electrical Transport of Conducting Polymers Confined in Alumina Nanopores
(Das, Sukanya; Narayan, Kavassery Sureswaran)
Tag: CP, EC, e-

ナノ粒子  
[J. Phys. Chem. C 20190507073447, 2019, 17−11310]
Connecting Theory with Experiment to Understand the Sintering Processes of Ag Nanoparticles
(da Silva, Edison Z.; Faccin, Giovani M.; Machado, Thales R.; Macedo, Nadia G.; de Assis, Marcelo; Maya-Johnson, Santiago; Sczancoski, JÃlio C.; AndrÃs, Juan; Longo, Elson; San-Miguel, Miguel A.)
Tag: DOT, SF, OA, SPR, EM, SP, EB, MDS, MD, NP, OTS, ED, TEM, e-

[J. Phys. Chem. B 20190507073546, 2019, 17−3598]
Detection of Drug Binding to a Target Protein Using EVV 2DIR Spectroscopy
(Sowley, Hugh; Liu, ZhiQiang; Davies, Julia; Peach, Robert; Guo, Rui; Sim, Sophie; Long, FengQin; Holdgate, Geoffrey; Willison, Keith; Zhuang, Wei; Klug, David R.)
Tag: QM, e-, IR, DFT

[J. Phys. Chem. B 20190507073554, 2019, 17−3607]
Crowding-Induced Elongated Conformation of Urea-Unfolded Apoazurin: Investigating the Role of Crowder Shape in Silico
(Zegarra, Fabio; Homouz, Dirar; Gasic, Andrei G.; Babel, Lucas; Kovermann, Michael; Wittung-Stafshede, Pernilla; Cheung, Margaret S.)
Tag: CG, DEX, MR, 57-13-6, MDS, MD, NMR

[J. Phys. Chem. B 20190507073617, 2019, 17−3658]
How Fast Is Too Fast in Force-Probe Molecular Dynamics Simulations?
(Sheridan, Steven; GrÃter, Frauke; Daday, Csaba)
Tag: AF, G, MDS, Gly, MD, AFM

[J. Phys. Chem. B 20190507073650, 2019, 17−3699]
Simulations of Cellulose Synthesis Initiation and Termination in Bacteria
(Yang, Hui; McManus, John; Oehme, Daniel; Singh, Abhishek; Yingling, Yaroslava G.; Tien, Ming; Kubicki, James D.)
Tag: DP, MM, TM, BC, MDS, MD, QM, DOP

[J. Phys. Chem. B 20190507073650, 2019, 17−3688]
Spectral and Kinetic Study of 3-Styrylquinoxalin-2(1H)-ones Photoreduced by N-Phenylglycine and Amines
(DÃaz-HernÃndez, Dafne; Cañete, Ãlvaro; Pavez, Lynda; PÃrez-Sanhueza, Alberto; GÃnther, GermÃn; Szreder, Tomasz; De la Fuente, Julio R.)
Tag: SET, FP, RIP, ET, R, CT, PrOH, TEtA, TriEA, NH2, TEA, Phg, e-

[J. Phys. Chem. B 20190507073719, 2019, 17−3706]
Mobility of Histidine Side Chains Analyzed with 15N NMR Relaxation and Cross-Correlation Data: Insight into Zinc-Finger–DNA Interactions
(Kemme, Catherine; Luu, Ross H.; Chen, Chuanying; Pletka, Channing C.; Pettitt, B. Montgomery; Iwahara, Junji)
Tag: CSA, IF, Zn, Lys, K, IMD, imH, Him, imid, His, H, R, Arg, CS, SC

自己集合  
[J. Phys. Chem. B 20190507073731, 2019, 17−3711]
Single-Chain Î-d-Glycopyranosylamides of Unsaturated Fatty Acids: Self-Assembly Properties and Applications to Artificial Cell Development
(Bhattacharya, Ahanjit; Brea, Roberto J.; Song, Jing-Jin; Bhattacharya, Rupak; Sinha, Sunil K.; Devaraj, Neal K.)
Tag: Lam, NT, FL, FA, XR, EM, OM, UFA, DSC, SA, XRD, TEM, e-, BB

自己集合  
[J. Phys. Chem. B 20190507073731, 2019, 17−3721]
Optimization of Amino Acid Sequence of Fmoc-Dipeptides for Interaction with Lipid Membranes
(Argudo, Pablo; Contreras-Montoya, Rafael; Ãlvarez de Cienfuegos, Luis; MartÃn-Romero, MarÃa T.; Camacho, Luis; Giner-Casares, Juan J.)
Tag: LM, BAM, RfS, AA, PPL, ML, AWI, SA, BB

[J. Phys. Chem. B 20190507073815, 2019, 17−3763]
Enthalpies of Solution of C-Alkylresorcin[4]arenes in Water and Acetonitrile: Hydrophilic and Hydrophobic Effects
(Riveros, Diana; Hefter, Glenn; Vargas, Edgar F.)
Tag: ACN, AN, ANT, MeCN, C, D-A, Hex, EEC, Me, Alk

[J. Phys. Chem. B 20190507073816, 2019, 17−3769]
Charge-Transfer-to-Solvent Reaction in a Hydrophobic Tetrabutylammonium Iodide Molecular Layer in Aqueous Solution
(Karashima, Shutaro; Suzuki, Toshinori)
Tag: BE, TBAI, PE, CT, TBA, BDE, CTTS, PS, e-, EBE

[J. Phys. Chem. B 20190507073818, 2019, 17−3776]
pH-dependent X-ray Photoelectron Chemical Shifts and Surface Distribution of Cysteine in Aqueous Solution
(Carravetta, Vincenzo; de Abreu Gomes, Anderson Herbert; Monti, Susanna; Mocellin, Alexandra; Marinho, Ricardo R. T.; BjÃrneholm, Olle; Ã?gren, Hans; Naves de Brito, Arnaldo)
Tag: PE, Cys, AA, C, MDS, MD, CS, ReaxFF, FF, DFT

[J. Phys. Chem. B 20190507073830, 2019, 17−3786]
Exact Solutions for Distributions of First-Passage, Direct-Transit, and Looping Times in Symmetric Cusp Potential Barriers and Wells
(Berezhkovskii, Alexander; Dagdug, Leonardo; Bezrukov, Sergey M.)
Tag: FPT

イオン液体  
[J. Phys. Chem. B 20190507073835, 2019, 17−3797]
Modeling Carbon Dioxide Vibrational Frequencies in Ionic Liquids: IV. Temperature Dependence
(Daly, Clyde; Allison, Cecelia; Corcelli, Steven A.)
Tag: C, as, CO2, Bu, BDMIM, BMImPF6, HFP, BMIM, ABS, IL, VS, IR

[J. Phys. Chem. B 20190507073838, 2019, 17−3804]
Photoinduced Proton Transfer of GFP-Inspired Fluorescent Superphotoacids: Principles and Design
(Chen, Cheng; Zhu, Liangdong; Baranov, Mikhail S.; Tang, Longteng; Baleeva, Nadezhda S.; Smirnov, Alexander Yu.; Yampolsky, Ilia V.; Solntsev, Kyril M.; Fang, Chong)
Tag: FSRS, PT, CIP, Ra, FL, TA, GS, ESPT, FSTA, ABS, EWG, CH3OH, PhOH, e-

自己集合  
[J. Phys. Chem. B 2019050707394, 2019, 17−3841]
Asymmetrical, Symmetrical, Divalent, and Y-Shaped (Bola)amphiphiles: The Relationship between the Molecular Structure and Self-Assembly in Amino Derivatives of Sophorolipid Biosurfactants
(Baccile, Niki; Delbeke, Elisabeth I. P.; Brennich, Martha; Seyrig, ChloÃ; Everaert, Jonas; Roelants, Sophie L. K. W.; Soetaert, Wim; Van Bogaert, Inge N. A.; Van Geem, Kevin M.; Stevens, Christian V.)
Tag: RM, N, as, NH2, SA

触媒的芳香族求核置換 芳香族求核置換  
[J. Phys. Chem. B 20190507073925, 2019, 17−3866]
Oxidation Pathways Involving a Sulfide-Endcapped Donor–Acceptor–Donor Ï?-Conjugated Molecule and Antimony(V) Chloride
(Chaudhry, Saadia; Ryno, Sean M.; Zeller, Matthias; McMillin, David R.; Risko, Chad; Mei, Jianguo)
Tag: OEC, EC, EC, EPR, ESR, O, E, Nu, El, DCM, NAS, e-, CH2Cl2, SNAr, DFT

[J. Phys. Chem. B 20190507073925, 2019, 17−3875]
Improved Temperature Behavior of PNIPAM in Water with a Modified OPLS Model
(Dalgicdir, Cahit; van der Vegt, Nico F. A.)
Tag: RE, REMD, MDS, LCST, MD, CH3OH, FF, CST

ナノ粒子  
[RSC Adv. 20190507074037, 2019, 23−13297]
Clouding observed for surface active, mPEG-grafted silica nanoparticles
(BjÃrkegren, Sanna; Nordstierna, Lars; Sundblom, Andreas; Palmqvist, Anders)
Tag: CP, PEG, Tcp, NP, SNP, Me, PE

多環芳香族炭化水素 (PAH)  
[RSC Adv. 20190507074038, 2019, 23−13283]
Tar yield and composition from poultry litter gasification in a fluidised bed reactor: effects of equivalence ratio, temperature and limestone addition
(Horvat, Alen; Pandey, Daya Shankar; Kwapinska, Marzena; Mello, Barbara B.; GÃmez-Barea, Alberto; Fryda, Lydia E.; Rabou, Luc P. L. M.; Kwapinski, Witold; Leahy, James J.)
Tag: GC, ER, St, N, Het, AP, HC, PhH, BZ, BN, PhMe, 2-Mepy, 2-MP, pyr, SPA, arene, PAH, PY, Me, Py, TolH, Cat

ナノ結晶  
[RSC Adv. 20190507074119, 2019, 23−13263]
Facile anion-exchange reaction in mixed-cation lead bromide perovskite nanocrystals
(Pisanu, Ambra; Quadrelli, Paolo; Malavasi, Lorenzo)
Tag: em, NC, P

[RSC Adv. 2019050707448, 2019, 23−13088]
Microwave absorption enhancement by adjusting reactant ratios and filler contents based on 1D K–MnO2@PDA and poly(vinylidene fluoride) matrix
(Lv, Shu-Qing; Xu, Wei; Huang, Wujisiguleng; Lv, Guo-Cheng; Wang, Guang-Sheng)
Tag: Mat, PBF2, DA, ABS, RL, EAB

リチウムイオン二次電池  
[RSC Adv. 20190507074418, 2019, 23−13077]
Highly efficient & stable Bi & Sb anodes using lithium borohydride as solid electrolyte in Li-ion batteries
(Kumari, Pooja; Sharma, Khushbu; Pal, Pratibha; Kumar, Manoj; Ichikawa, Takayuki; Jain, Ankur)
Tag: SE, Li, SS, C2H2, HEBM, CE, LIB, AB, HE, SSE

[RSC Adv. 20190507074451, 2019, 23−13033]
Strain vs. charge mediated magnetoelectric coupling across the magnetic oxide/ferroelectric interfaces
(Paudel, Binod; Vasiliev, Igor; Hammouri, Mahmoud; Karpov, Dmitry; Chen, Aiping; Lauter, Valeria; Fohtung, Edwin)
Tag: OP, NR, EF, Fm, ODS, MEC, EEF, PNR, DFT

[RSC Adv. 2019050707451, 2019, 23−13016]
Synthesis and characterization of photocrosslinkable hydrogels from bovine skin gelatin
(Suvarnapathaki, Sanika; Nguyen, Michelle A.; Wu, Xinchen; Nukavarapu, Syam P.; Camci-Unal, Gulden)
Tag: TE, CL, 760-93-0, GEL

[RSC Adv. 2019050707463, 2019, 23−12921]
A synchrotron X-ray spectroscopy study of titanium co-ordination in explosive melt glass derived from the trinity nuclear test
(Bailey, D. J.; Stennett, M. C.; Ravel, B.; Crean, D. E.; Hyatt, N. C.)
Tag: Ti, ABS, XAS

[RSC Adv. 20190507074720, 2019, 23−12823]
Reducing leakage current and dielectric losses of electroactive polymers through electro-annealing for high-voltage actuation
(Pedroli, Francesco; Marrani, Alessio; Le, Minh-Quyen; Sanseau, Olivier; Cottinet, Pierre-Jean; Capsal, Jean-Fabien)
Tag: EF, EAP, Mat

[RSC Adv. 20190507074741, 2019, 23−12801]
One-pot synthesis of 2-amino-4H-chromene derivatives by MNPs@Cu as an effective and reusable magnetic nanocatalyst
(MA, Wanzheng; Ebadi, Abdol Ghaffar; sabil, Mostafa shahbazi; Javahershenas, Ramin; Jimenez, Giorgos)
Tag: FTIR, EDS, EDX, SFC, XR, EM, FT, VSM, MN, TG, TGA, 3CR, XRD, e-, C, SEM, IR, Cat

[Chem. Commun. 20190507074819, 2019, 37−5391]
Enantioselective conjugate addition of an α,α-dithioacetonitrile with nitroalkenes using chiral bis(imidazoline)–Pd complexes
(Nakamura, Shuichi; Tokunaga, Akari; Saito, Hikari; Kondo, Masaru)
Tag: CA, ECA

[Chem. Commun. 20190507074952, 2019, 37−5335]
Electrochemical fabrication of fibrin gels via cascade reaction for cell culture
(Taira, Noriko; Ino, Kosuke; Kumagai, Tatsuki; Nashimoto, Yuji; Shiku, Hitoshi)
Tag: FBN, EC

[Chem. Commun. 20190507074953, 2019, 37−5331]
Persian waxing of graphite: towards green large-scale production of graphene
(Aliprandi, Alessandro; Eredia, Matilde; Anichini, Cosimo; Baaziz, Walid; Ersen, Ovidiu; Ciesielski, Artur; SamorÃ, Paolo)

[Chem. Commun. 20190507074955, 2019, 37−5327]
Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis
(Uchiyama, Mineto; Satoh, Kotaro; Kamigaito, Masami)
Tag: TTC, OAc, A, R, PSt, PVAc, PS, C, Cat

[Chem. Commun. 20190507075015, 2019, 37−5323]
Redox-responsive phosphonite gold complexes in hydroamination catalysis
(Deck, Eva; Wagner, Hanna E.; Paradies, Jan; Breher, Frank)
Tag: Au, e-, C