[読みたい論文] 試されるイオン液体

Viewed: 03:53:20 in December 11, 2019

Posted: June 3, 2019

Synthesis of Imidazolidinone, Imidazolone, and Benzimidazolone Derivatives through Oxidation Using Copper and Air (Li, Dazhi; Ollevier, Thierry)
Org. Lett. 2019, 21 (10), 3572−3575.

Keywords: Cu

銅触媒下でのイミダゾリウム塩などのヘテロ環イオン性化合物の酸化反応に関して報告しているようです。合成反応の有用性と反応機構の解析にウェイトが置かれている模様です。例えば下の枠内の反応が典型例ですが、RがCH3だと生成物がDMIになります。高極性溶媒として用いられる化合物ですね。大昔の教科書的な合成法は右側のルートの通りですが、有毒なホスゲンを使わないといけないとか供生成物ができるとかあるわけです。ホスゲンの代わりに炭酸ジメチルを使うとか色々改善はされているのでしょうけどね。


とまあ合成上の有用性も示されていると勝手に想像しているわけですが、困ったことも示唆しているんじゃないかなと思われる反応例が、Supporting Informationに記載されているのです。下の反応なのですが、イミダゾリウム塩の酸化反応が室温でも進行するのですよね。Rの種類にもよるのでしょうが、イミダゾリウム塩はイオン液体としても注目されているわけで、こいつが化学的に安定でない(安定すぎても困るわけですが)となるとどうなるのかねぇということになるわけです。


論文中にどんなコメントが書かれているのか知りたいので、読みたい論文に追加です。
この記事を書いた人
「牧岡ふうふ堂」オーナー。博士(工学)。
酒都圏在住。
某地方の国立系工業大学でアシスタントをしていました。 専門は有機反応・金属錯体(主に希土類)・π共役系。
twitterアカウントは@makiokafufudo(お仕事用)、@ymakioka(個人用)です。

 

1991年はこんな年

人名反応など
Kobayashiヒドロキシメチル化反応 [Doi 1]
Larockインドール合成 [Doi 1]
ノーベル化学賞
高分解能NMRの開発への貢献
(Richard Robert Ernst)
できごと
大学院重点化
さきがけスタート(JST)
大阪大学でモノシランガスに絡む事故
銀行の放送メディアによるCMが解禁
失われた20年が始まる
小田和正「ラブ・ストーリーは突然に」
「東京ラブストーリー」放送(フジテレビ)
キリンビバレッジ株式会社が発足
広島新交通システム橋桁落下事故
槇原敬之「どんなときも。」
長崎県の雲仙普賢岳で火砕流発生
東北新幹線上野駅-東京駅間開業
「101回目のプロポーズ」放送(フジテレビ)
コミケ幕張メッセ追放事件
大事MANブラザーズバンド「それが大事」
小林コーセーがコーセーに社名変更
SMAPがデビュー
KAN「愛は勝つ」
「Good-bye My Loneliness」でZARDがデビュー
「たけし・逸見の平成教育委員会」放送開始(フジテレビ)
「カルトQ」放送開始(フジテレビ)

 

きょうのどうぶつ

ここの画像を使用しています。

上目遣いのクロ2号。

 

計算終わりました

 

あわせてどうぞ

SOHOのすすめ記事一覧 2019年
お仕事関係の記事のリストです(2019年)。

読みたい論文シリーズ − 2019年2Q
読みたいけと読んでいない論文を、構造式を描きながら紹介します(2019年4〜6月)。

 

[読みたい論文] インドールからBN-ナフタレンを作る
炭素−窒素結合を還元的に切断します。
Org. Lett. 2019, 21 (10), 3855−3860.

[読みたい論文] 借りてきたアシルアルミニウム
炭素−アルミニウム結合への一酸化炭素挿入反応につて。
Chem. Commun. 2019, 55 (44), 6181−6184.

[読みたい論文] ヨウ素触媒でC−Hアミノ化
ただのハロゲン化反応のような気もしますが何かあるのかも。
Angew. Chem. Int. Ed. 2019, 58 (22), 7485−7489.

[読みたい論文] ぼろはいでアルコキシシランからヒドロシランを合成します
水素化ホウ素ナトリウムね。
Chem. Commun. 2019, 55 (41), 5859−5862.

[読みたい論文] Rh(I)触媒によるアミドとシクロプロペノンの[3+2]環化反応
炭素−炭素結合切断を伴います。
Chem. Commun. 2019, 55 (41), 5740−5742.

[読みたい論文] ホスホニウム塩触媒によるグリシドールとイソシアネートの環形成
立体選択的に進行するのはわかった。で、その酸素原子はどっちの?
Chem. Commun. 2019, 55 (41), 5761−5764.

[読みたい論文] 「生きている」ラジカル重合
原子移動なやつ。
Angew. Chem. Int. Ed. 2019, 58 (21), 7113−7116.

[読みたい論文] マグネシウム触媒でアルキンのヒドロボリル化
金属単体でではないです。
Angew. Chem. Int. Ed. 2019, 58 (21), 7025−7029.

[読みたい論文] 名前を出すのに気を使ってしまう酢酸エステルのα-メチル化
メタノールがメチル源です。
Org. Lett. 2019, 21 (9), 3299−3303.

[読みたい論文] 交換反応でボロン酸エステルをフリーのボロン酸にします
ボロン酸を以ってボロン酸エステルを制す。
Org. Lett. 2019, 21 (9), 3048−3052.

 

注目のWebコンテンツ

ムーンショット型研究開発制度にかかわるビジョナリー会議:議事要旨 感想文
(有機化学論文研究所)
https://moro-chemistry.org/arc...

5G向けミリ波フェーズドアレイ無線機を開発 安価な集積回路を用いて高精度指向性制御を実現
(東京工業大学)
https://www.titech.ac.jp/news/...

窒素分子(N2)をつなぐ
(高純度化学研究所)
https://www.kojundo.blog/news/...

サンゴ共生藻と刺胞動物との共生崩壊に関わる遺伝子発現の変化を解明 共生が崩壊する「白化現象」を遺伝子レベルで解析
(東北大学)
https://www.tohoku.ac.jp/japan...

戦略的創造研究推進事業(社会技術研究開発)「SDGsの達成に向けた共創的研究開発プログラム」の提案の募集について
(科学技術振興機)
https://www.jst.go.jp/pr/info/...

 

注目の論文

ルテニウム  
[Dalton Trans. 2019053107445, 2019, 21−7432]
Dinuclear ruthenium acetylide complexes with diethynylated anthrahydroquinone and anthraquinone frameworks: a multi-stimuli-responsive organometallic switch
(Oyama, Yousuke; Kawano, Reo; Tanaka, Yuya; Akita, Munetaka)
Tag: Ru, EC, ANQ, AQN, AQ, AHQ

有機電界効果トランジスタ  
[Dalton Trans. 2019053107454, 2019, 21−7367]
New Ï?-extended catecholato complexes of Pt(ii) and Pd(ii) containing a benzothienobenzothiophene (BTBT) moiety: synthesis, electrochemical behavior and charge transfer properties
(Tahara, Keishiro; Ashihara, Yuya; Higashino, Toshiki; Ozawa, Yoshiki; Kadoya, Tomofumi; Sugimoto, Kunihisa; Ueda, Akira; Mori, Hatsumi; Abe, Masaaki)
Tag: cat, LLCT, CV, CV, EC, R, CT, O, tBu, t-Bu, Bu, HFP, ABS, FET, OFET, e-, CTT, ICT, DFT

[Dalton Trans. 20190531074616, 2019, 21−7302]
Intrinsic hydrogen evolution capability and a theoretically supported reaction mechanism of a paddlewheel-type dirhodium complex
(Kataoka, Yusuke; Yano, Natsumi; Handa, Makoto; Kawamoto, Tatsuya)
Tag: PS, OMS, Ir, H, TEtA, TriEA, TEA, e-, Rh, C, HEC, TON, Cat

ポリオキソ金属酸  
[Dalton Trans. 20190531074623, 2019, 21−7281]
Hexavacant Î-Dawson-type phosphotungstates supporting an edge-sharing bis(square-pyramidal) {O2M(Î3-O)2(Î-OAc)MO2} core (M = Mn2+, Co2+, Ni2+, Cu2+, or Zn2+)
(Suzuki, Kosuke; Minato, Takuo; Tominaga, Naoto; Okumo, Ichiro; Yonesato, Kentaro; Mizuno, Noritaka; Yamaguchi, Kazuya)
Tag: ACN, AN, ANT, MeCN, OAc, A, POM, MO, M

[Dalton Trans. 20190531074641, 2019, 21−7267]
Stereospecific polymerization of conjugated dienes using neodymium alkylborohydride complexes
(Tanaka, Ryo; Shinto, Yuto; Matsuzaki, Ryusei; Nakayama, Yuushou; Shiono, Takeshi)
Tag: PI, PIP, B, In, Nd, e-, Alk

配位高分子  
[Dalton Trans. 20190531074746, 2019, 21−7198]
Consecutive oxidative additions of iodine on undulating 2D coordination polymers: formation of I–Pt–I chains and inhomogeneous layers
(Ohtani, Ryo; Yamamoto, Riho; Ohtsu, Hiroyoshi; Kawano, Masaki; Pirillo, Jenny; Hijikata, Yuh; Sadakiyo, Masaaki; Lindoy, Leonard F.; Hayami, Shinya)
Tag: XRPD, VT, I, ABS, OA, CP

[Dalton Trans. 2019053107489, 2019, 21−7144]
Ln–Pt electron polarization effects on the magnetic relaxation of heterometallic Ho? and Er–Pt complexes
(Yoshida, Takefumi; Izuogu, David C.; Zhang, Hai-Tao; Cosquer, Goulven; Abe, Hitoshi; Wernsdorfer, Wolfgang; Breedlove, Brian K.; Yamashita, Masahiro)
Tag: ABS, NBO, e-, LOL

カーボンナノチューブ ナノ粒子  
[Dalton Trans. 20190531074814, 2019, 21−7130]
Enhanced oxygen reduction reaction performance of size-controlled Pt nanoparticles on polypyrrole-functionalized carbon nanotubes
(Ichihashi, Kentaro; Muratsugu, Satoshi; Miyamoto, Shota; Sakamoto, Kana; Ishiguro, Nozomu; Tada, Mizuki)
Tag: NT, C, FC, O, Mat, f-CNT, PP, PPY, CNT, NP, PY, C, ORR, M

[Dalton Trans. 20190531074813, 2019, 21−7138]
Evaluation of the chemo- and shape-selective association of a bowl-type dodecavanadate cage with an electron-rich group
(Kikukawa, Yuji; Kitajima, Hiromasa; Hayashi, Yoshihito)
Tag: ACN, AN, ANT, MeCN, GM, 624-73-7, DCE, EDC, NM, 75-52-5, BzH, PhCHO, DCM, DMF, e-, 1191-95-3, CH2Cl2

[Dalton Trans. 20190531074847, 2019, 21−7105]
Luminescent mechanochromism of gold N-heterocyclic carbene complexes with hypso- and bathochromic spectral shifts
(Seki, Tomohiro; Kashiyama, Kentaro; Ito, Hajime)
Tag: Au, Het, em, NHC, M

配位高分子  
[Dalton Trans. 2019053107494, 2019, 21−7090]
One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to Ï?-conjugation and magnetic properties
(Kimura, Shun; Uchida, Hikaru; Kusamoto, Tetsuro; Nishihara, Hiroshi)
Tag: R, CP

カーボンナノチューブ ナノ粒子  
[Dalton Trans. 20190531074933, 2019, 21−7074]
Facile preparation of hybrid thin films composed of spin-crossover nanoparticles and carbon nanotubes for electrical memory devices
(Tanaka, Daisuke; Aketa, Naoki; Tanaka, Hirofumi; Horike, Satoshi; Fukumori, Minoru; Tamaki, Takashi; Inose, Tomoko; Akai, Tomoki; Toyama, Hirotaka; Sakata, Osami; Tajiri, Hiroo; Ogawa, Takuji)
Tag: SCO, NT, SWCNT, SC, VT, EC, C, Htrz, Htz, tzH, trz, TAZ, CNT, NP, ECM, TF

[Analyst 20190531075029, 2019, 11−3659]
A highly sensitive endotoxin sensor based on redox cycling in a nanocavity
(Ito, Kentaro; Inoue, Kumi Y.; Ino, Kosuke; Matsue, Tomokazu; Shiku, Hitoshi)
Tag: LAL, EC, AP, pAP

[Analyst 20190531075250, 2019, 11−3483]
Determination of cellular vitamin C dynamics by HPLC-DAD
(Miyazawa, Taiki; Matsumoto, Akira; Miyahara, Yuji)
Tag: Glu, HT, DHA, Glc, VC, AA, GLUT, Glu, Glu

[Lab Chip 2019053107541, 2019, 11−1971]
Portable biohybrid odorant sensors using cell-laden collagen micropillars
(Hirata, Yusuke; Morimoto, Yuya; Nam, Eunryel; Takeuchi, Shoji)
Tag: Ca, OR, POCT, POC, FL, COL

カーボンナノチューブ  
[J. Mater. Chem. A 20190531080021, 2019, 21−12987]
Semiconducting carbon nanotubes as crystal growth templates and grain bridges in perovskite solar cells
(Seo, Seungju; Jeon, Il; Xiang, Rong; Lee, Changsoo; Zhang, Hao; Tanaka, Takeshi; Lee, Jin-Wook; Suh, Donguk; Ogamoto, Tatsuro; Nishikubo, Ryosuke; Saeki, Akinori; Chiashi, Shohei; Shiomi, Junichiro; Kataura, Hiromichi; Lee, Hyuck Mo; Yang, Yang; Matsuo, Yutaka; Maruyama, Shigeo)
Tag: NT, SWCNT, NaDOC, GB, s-SWNT, PSC, C, Na, NaDC, PCE, CNT, P

[Chem. Commun. 20190531080641, 2019, 44−6189]
Unexplored reactivity of (Sn)2? oligomers with transition metals in low-temperature solid-state reactions
(Sasaki, Shunsuke; Lesault, MÃlanie; Grange, Elodie; Janod, Etienne; Corraze, BenoÃt; Cadars, Sylvian; Caldes, Maria Teresa; Guillot-Deudon, Catherine; Jobic, StÃphane; Cario, Laurent)
Tag: SS, S, SSR, TM, e-

[Chem. Commun. 20190531080710, 2019, 44−6165]
Photo-oxygenation inhibits tau amyloid formation
(Suzuki, Takanobu; Hori, Yukiko; Sawazaki, Taka; Shimizu, Yusuke; Nemoto, Yu; Taniguchi, Atsuhiko; Ozawa, Shuta; Sohma, Youhei; Kanai, Motomu; Tomita, Taisuke)
Tag: Cat

イオン液体 自己集合 ナノファイバー  
[Polym. Chem. 20190531080738, 2019, 21−2734]
Photoluminescent poly(4-vinylpyridine)-based ionic liquids coded with l- and d-histidine: a supramolecular self-assembly leading to the formation of red-shifted photoluminescent helical aggregates
(Puneet, Puhup; Horechyy, Andriy; Srivastava, Rajiiv K.; Nandan, Bhanu; Fujiki, Michiya)
Tag: P4VP, PL, His, H, VP, IL, NF, SA, SSA

液晶 自己集合  
[Polym. Chem. 20190531080833, 2019, 21−2686]
Polymer-brush-decorated colloidal platelets: precision synthesis and self-assembly
(Ohno, Kohji; Masuda, Shota; Ogawa, Hiroki)
Tag: SI, LLC, SCA, R, In, Mat, MMA, ATRP, RP, LC, ATR, SA, MMD, Me, TF

パラジウム  
[Polym. Chem. 20190531080917, 2019, 21−2647]
Ladderization of polystyrene derivatives by palladium-catalyzed polymer direct arylation
(Takagi, Koji; Tanaka, Hidetoshi; Mikami, Koichiro)
Tag: Pd, PSt, PS, PivOH

[Polym. Chem. 20190531080927, 2019, 21−2636]
Introducing static cross-linking points into dynamic covalent polymer gels that display freezing-induced mechanofluorescence: enhanced force transmission efficiency and stability
(Kato, Sota; Aoki, Daisuke; Otsuka, Hideyuki)
Tag: R

パラジウム  
[New J. Chem. 20190531081442, 2019, 21−8015]
Synthesis of macrocyclic polyphenol resin by methylene crosslinked calix[4]arene (MC-[4]H) for the adsorption of palladium and platinum ions
(Priastomo, Yoga; Morisada, Shintaro; Kawakita, Hidetaka; Ohto, Keisuke; Jumina)
Tag: Pd, Pt, O, CL, PhOH

ポルフィリン  
[Chem. Eur. J. 20190531081658, 2019, 30−7322]
Perfluorophenyl-Directed Giant Porphyrin J-Aggregates
(Morisue, Mitsuhiko; Ueno, Ikuya; Muraoka, Kunihiko; Omagari, Shun; Nakanishi, Takayuki; Hasegawa, Yasuchika; Hikima, Takaaki; Sasaki, Sono)
Tag: PFP, SC, WAXD, XR, MCH, WAXRD, Por, Ph, XRD, DFT

[Chem. Eur. J. 2019053108179, 2019, 30−7315]
Enzymatic Cell-Surface Decoration with Proteins using Amphiphilic Lipid-Fused Peptide Substrates
(Takahara, Mari; Wakabayashi, Rie; Fujimoto, Naoki; Minamihata, Kosuke; Goto, Masahiro; Kamiya, Noriho)
Tag: Lys, K, FA, Gln, Q, Chol, MTG

[Chem. Eur. J. 20190531081716, 2019, 30−7308]
A Series of Dibenzofuran-Based n-Type Exciplex Host Partners Realizing High-Efficiency and Stable Deep-Red Phosphorescent OLEDs
(Ito, Takashi; Sasabe, Hisahiro; Nagai, Yuji; Watanabe, Yuichiro; Onuma, Natsuki; Kido, Junji)
Tag: EQE, 132-64-9, QE, Ir, em, SOTA, NIR, IR

自己集合  
[Chem. Eur. J. 20190531081716, 2019, 30−7303]
Seeded Polymerization of an Amide-Functionalized Diketopyrrolopyrrole Dye in Aqueous Media
(Ogi, Soichiro; Fukaya, Natsumi; Arifin; Skjelstad, Bastian Bjerkem; Hijikata, Yuh; Yamaguchi, Shigehiro)
Tag: TD, DPP, H, ABS, CH3OH, SA, M, HB

クロスカップリング  
[Chem. Eur. J. 20190531081921, 2019, 29−7201]
Triplet Diradical-Cation Salts Consisting of the Phenothiazine Radical Cation and a Nitronyl Nitroxide
(Tahara, Takuma; Suzuki, Shuichi; Kozaki, Masatoshi; Shiomi, Daisuke; Sugisaki, Kenji; Sato, Kazunobu; Takui, Takeji; Miyake, Yota; Hosokoshi, Yuko; Nojiri, Hiroyuki; Okada, Keiji)
Tag: PTZ, EC, R, Fm, ABS, CC

ポルフィリン  
[Eur. J. Org. Chem. 20190531082134, 2019, 20−3224]
Synthesis, Structural and Optical Properties of Tetrabenzoporphyrin Complexes Bearing Four or Eight Peripheral Phenyl Groups
(Furuyama, Taniyuki; Okujima, Tetsuo; Muramatsu, Kota; Takahashi, Yuichi; Mikami, Akihiro; Fukumura, Tomoteru; Mori, Shigeki; Nakae, Takahiro; Takase, Masayoshi; Uno, Hidemitsu; Kobayashi, Nagao)
Tag: MCD, SS, QC, ABS, TBP, Por, Ph, CD, e-, P

環化付加反応  
[Eur. J. Org. Chem. 20190531082349, 2019, 20−3117]
Synthesis of Thiazinoimidazoles by Lewis Acid–Catalyzed [3+3] Cycloaddition Reactions of Propargyl Alcohols with 2-Mercaptoimidazoles
(Mishima, Naoya; Ogawa, Takahiro; Tanabe, Genzoh; Muraoka, Osamu; Wasada, Hiroaki; Hatae, Noriyuki; Yoshimatsu, Mitsuhiro)
Tag: Yb, Se, S, C3H4, CA

[Eur. J. Org. Chem. 20190531082414, 2019, 20−3086]
Solid-State Emissive Diaminomaleimide Dimers and a Polymer ? Syntheses, Structures and Optical Properties
(Imoto, Hiroaki; Fujii, Ryosuke; Naka, Kensuke)
Tag: PL, em, SS, MI

鉄  
[Tetrahedron Lett. 20190531082634, 2019, 24−1562]
Efficient and practical synthesis of N-acetyl enamides from ketoximes by unique iron catalytic system
(Kunishige, Takahiro; Sawada, Daisuke)
Tag: Fe, Ac, Cat

[Tetrahedron Lett. 20190531082634, 2019, 24−1566]
1-Methyl-1H-tetrazol-5-yl (MT) sulfones in the Julia-Kocienski olefination: Comparison with the PT and the TBT sulfones
(Ando, Kaori; Kawano, Daiki; Takama, Daiki; Semii, Yutaka)
Tag: Et, Am, Pen, Me, Alk

[Tetrahedron Lett. 20190531082714, 2019, 24−1604]
Total synthesis and determination of the absolute configuration of paralemnolin C and biological studies of eremophilane derivatives
(Abe, Hideki; Fujimaki, Mitsuru; Goto, Ena; Yokosuka, Akihito; Mimaki, Yoshihiro; Kobayashi, Toyoharu; Ito, Hisanaka)
Tag: as, AC

[Tetrahedron Lett. 20190531082824, 2019, 24−1611]
Novel coupling reaction between sulfonyl azide and N,N,N',N'-tetramethylthiourea
(Aswad, Muhammad; Chiba, Junya; Hatanaka, Yasumaru; Tomohiro, Takenori)
Tag: tmtu

[Tetrahedron 20190531082824, 2019, 24−3145]
Total synthesis, reactivity, and structural clarification of lindenatriene
(Eagan, James M.; Kanyiva, Kyalo Stephen; Hori, Masahiro; Snyder, Scott A.)

[Tetrahedron 20190531082928, 2019, 24−3366]
A convenient C–H functionalization platform for pyrroloiminoquinone alkaloid synthesis
(Smith, Myles W.; Falk, Isaac D.; Ikemoto, Hideya; Burns, Noah Z.)
Tag: as, Cat

[Tetrahedron 20190531083037, 2019, 24−3178]
Total synthesis of 4-epi-atpenin A5 as a potent nematode complex II inhibitor
(Lee, Daiki; Kondo, Hiroki; Kuwayama, Yui; Takahashi, Kento; Arima, Shiho; Omura, Satoshi; Ohtawa, Masaki; Nagamitsu, Tohru)

[Polymer 20190531083154, 2019, −178]
Synthesis and properties of polyurethane networks composed of comb-shaped polymers grafted with L-lactide and É?-caprolactone oligomers
(Ussama, Warunya; Matsuda, Shohei; Shibata, Mitsuhiro)
Tag: HDI, MM, PU, R, EM, Bu, CL, CL, LA, BuMA, BMA, HE, ROP, e-, SEM, SEM

[Polymer 2019053108334, 2019, −234]
Polymerization of diazoacetates: New synthetic strategy for C-C main chain polymers
(Ihara, Eiji; Shimomoto, Hiroaki)
Tag: HMW, C, LMW, C2H4, M

[Polymer 20190531083415, 2019, −150]
Function extension of dual-mechanochromism of acylated hydroxypropyl cellulose/synthetic polymer composites achieved by “moderate? compatibility as well as hydrogen bonding
(Miyagi, Kazuma; Teramoto, Yoshikuni)
Tag: HP, HPC, LC, H, CD, HB, CLC

[Polymer 20190531083440, 2019, −130]
Evaluation and modeling of mechanical behaviors of thermosetting polymer under monotonic and cyclic tensile tests
(Uchida, Makoto; Wakuda, Ryohei; Kaneko, Yoshihisa)

[Angew. Chem. Int. Ed. 20190531083734, 2019, 23−7792]
Gold(I)-Catalyzed Cascade Cyclization Reactions of Allenynes for the Synthesis of Fused Cyclopropanes and Acenaphthenes
(Ikeuchi, Takaya; Inuki, Shinsuke; Oishi, Shinya; Ohno, Hiroaki)
Tag: Au, C3H4, Nu, C3H6

[Angew. Chem. Int. Ed. 20190531083734, 2019, 23−7788]
Design of Photostable, Activatable Near-Infrared Photoacoustic Probes Using Tautomeric Benziphthalocyanine as a Platform
(Toriumi, Naoyuki; Asano, Norihito; Ikeno, Takayuki; Muranaka, Atsuya; Hanaoka, Kenjiro; Urano, Yasuteru; Uchiyama, Masanobu)
Tag: FL, PA, ABS, PAI, NIR, IR

[Angew. Chem. Int. Ed. 20190531083841, 2019, 23−7749]
A Monomeric Stannabenzene: Synthesis, Structure, and Electronic Properties
(Kaiya, Canon; Suzuki, Katsunori; Yamashita, Makoto)
Tag: Sn, PhH, BZ, CS, NICS, HLG, e-, M

超分子キラリティー  
[Angew. Chem. Int. Ed. 2019053108397, 2019, 23−7733]
Reversing the Handedness of Self-Assembled Porous Molecular Networks through the Number of Identical Chiral Centres
(Tahara, Kazukuni; Noguchi, Aya; Nakayama, Ruri; Ghijsens, Elke; De?Feyter, Steven; Tobe, Yoshito)
Tag: AC, SC, SAM

[Angew. Chem. Int. Ed. 20190531084122, 2019, 23−7626]
Direct Observation and Analysis of the Dynamics of the Photoresponsive Transcription Factor GAL4
(Raghavan, Guruprasad; Hidaka, Kumi; Sugiyama, Hiroshi; Endo, Masayuki)
Tag: AF, TF, SM, ds, SMI, AFM

ポリ乳酸  
[Macromolecules 20190531084550, 2019, 10−3730]
Structure–Property Relationships of Poly(glycolic acid) and Poly(2-hydroxybutyrate)
(Sasanuma, Yuji; Yamamoto, Hiromi; Choi, Somin)
Tag: PBC, PGA, MO, PLA, RIS, DFT

ナノ粒子  
[Macromolecules 20190531084547, 2019, 10−3716]
Well-Defined Titanium Complex for Free-Radical and Cationic Photopolymerizations under Visible Light and Photoinduction of Ti-Based Nanoparticles
(Breloy, Louise; BrezovÃ, Vlasta; Malval, Jean-Pierre; Bourgon, Julie; Kurogi, Takashi; Mindiola, Daniel J.; Versace, Davy-Louis)
Tag: HAADF, FTIR, BF, FP, R, Ti, EPR, ESR, EM, FT, PA, Mat, PIS, ADF, STEM, VL, CTEM, NP, LFP, HAADF-STEM, FRP, 91-22-5, TEM, e-, M, IR

[Macromolecules 20190531084632, 2019, 10−3787]
Sliding Dynamics of Ring on Polymer in Rotaxane: A Coarse-Grained Molecular Dynamics Simulation Study
(Yasuda, Yusuke; Toda, Masatoshi; Mayumi, Koichi; Yokoyama, Hideaki; Morita, Hiroshi; Ito, Kohzo)
Tag: CG, MDS, MD

[Macromolecules 20190531084646, 2019, 10−3813]
Colorless Partially Alicyclic Polyimides Based on TrÃger’s Base Exhibiting Good Solubility and Dual Fluorescence/Phosphorescence Emission
(Zhuang, Yongbing; Orita, Ryoji; Fujiwara, Eisuke; Zhang, Yu; Ando, Shinji)
Tag: FL, em, St, PI

[Macromolecules 20190531084752, 2019, 10−3881]
Formation of Isolated Pseudo-Polyrotaxane Nanosheet Consisting of α-Cyclodextrin and Poly(ethylene glycol)
(Uenuma, Shuntaro; Maeda, Rina; Yokoyama, Hideaki; Ito, Kohzo)
Tag: NS, CD, PEG, PRX, PE

[Macromolecules 20190531084813, 2019, 10−3909]
Ester-Functionalized Naphthobispyrazine as an Acceptor Building Unit for Semiconducting Polymers: Synthesis, Properties, and Photovoltaic Performance
(Mikie, Tsubasa; Osaka, Itaru)
Tag: UMO, LUMO, PV, OPV, OVD, C60, MO, PCE, EL, OBG, e-

[Macromolecules 2019053108491, 2019, 10−3951]
Rheology and Entanglement Structure of Well-Entangled Polymer Melts: A Slip-Link Simulation Study
(Sato, Takeshi; Taniguchi, Takashi)

[Chem. Mater. 20190531085034, 2019, 10−3694]
Weak Anisotropic Lithium-Ion Conductivity in Single Crystals of Li10GeP2S12
(Iwasaki, Rui; Hori, Satoshi; Kanno, Ryoji; Yajima, Takeshi; Hirai, Daigorou; Kato, Yuki; Hiroi, Zenji)
Tag: IS, Li, XR, XRD, SC, Ea

固体電池 リチウムイオン二次電池  
[Chem. Mater. 20190531085117, 2019, 10−3745]
Visualization of the Interfacial Decomposition of Composite Cathodes in Argyrodite-Based All-Solid-State Batteries Using Time-of-Flight Secondary-Ion Mass Spectrometry
(Walther, Felix; Koerver, Raimund; Fuchs, Till; Ohno, Saneyuki; Sann, Joachim; Rohnke, Marcus; Zeier, Wolfgang G.; Janek, JÃrgen)
Tag: SEI, PE, SE, TOF-SIMS, TOF, EC, Li, SS, XPS, EM, PS, TM, SIMS, LIB, SSB, ASSB, e-, MS

高分子電解質  
[Chem. Mater. 20190531085141, 2019, 10−3766]
Fabrication of Tough and Stretchable Hybrid Double-Network Elastomers Using Ionic Dissociation of Polyelectrolyte in Nonaqueous Media
(Matsuda, Takahiro; Nakajima, Tasuku; Gong, Jian Ping)
Tag: DN, PA, IPN, SOTA, PEL

[J. Med. Chem. 20190531085747, 2019, 10−4915]
Discovery of Potent, Selective, and Brain-Penetrant 1H-Pyrazol-5-yl-1H-pyrrolo[2,3-b]pyridines as Anaplastic Lymphoma Kinase (ALK) Inhibitors
(Fushimi, Makoto; Fujimori, Ikuo; Wakabayashi, Takeshi; Hasui, Tomoaki; Kawakita, Youichi; Imamura, Keisuke; Kato, Tomoko; Murakami, Morio; Ishii, Tsuyoshi; Kikko, Yorifumi; Kasahara, Maki; Nakatani, Atsushi; Hiura, Yuto; Miyamoto, Maki; Saikatendu, Kumar; Zou, Hua; Lane, Scott Weston; Lawson, J. David; Imoto, Hiroshi)
Tag: PFC, CNS, RTK, TK, Y, Tyr, ALK, NH2, Me

[J. Med. Chem. 2019053108593, 2019, 10−5080]
Structure-Based Design of Selective Î-Site Amyloid Precursor Protein Cleaving Enzyme 1 (BACE1) Inhibitors: Targeting the Flap to Gain Selectivity over BACE2
(Fujimoto, Kazuki; Matsuoka, Eriko; Asada, Naoya; Tadano, Genta; Yamamoto, Takahiko; Nakahara, Kenji; Fuchino, Kouki; Ito, Hisanori; Kanegawa, Naoki; Moechars, Diederik; Kusakabe, Ken-ichi)
Tag: SBDD, APP

ナノ粒子  
[J. Chem. Inf. Model. 20190531090213, 2019, 5−1873]
Feature Engineering for Materials Chemistry—Does Size Matter?
(, Roger; Amos, D.; Kobayashi, Rika)
Tag: Ag, MAE, AgNP, RMSE, NP, ML, DFT

[J. Chem. Inf. Model. 20190531090623, 2019, 5−2264]
Determinants of Oligonucleotide Selectivity of APOBEC3B
(, Jeffrey; Wagner, R.; Demir, Ãzlem; Carpenter, Michael A.; Aihara, Hideki; Harki, Daniel A.; Harris, Reuben S.; Amaro, Rommie E.)
Tag: CTD, WT, Cy, C, MDS, MD, Rib