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acetyl (Ac)
 

(1) The Importance of How the Pieces Fit Together: The Microwave Spectrum and Molecular Structure of 2-Chloro-1,1-Difluoroethylene–Acetylene (J. Phys. Chem. A 2020, 124, 1382−1389; 10.1021/acs.jpca.9b11861) det., Mic, MW, Et, H, Ac

(2) Microwave Spectrum and Internal Rotations of Heptan-2-one: A Pheromone in the Gas Phase (J. Phys. Chem. A 2020, 124, 1353−1361; 10.1021/acs.jpca.9b11577) STD, SD, Et, Ac

(3) Mechanical and Electronic Properties of Diacetylene and Polydiacetylene Self-Assembled Monolayers on Au(111) (J. Phys. Chem. C 2020, 124, 4081−4089; 10.1021/acs.jpcc.9b09600) CB, PDA, PSA, Ac

(4) Synthetic Approaches for Piperidone-Based Templates as Scaffolds to Access Chirally Enriched Donepezil Analogues (ACS Omega 2020, 5, 2378−2396; 10.1021/acsomega.9b03808) ACh, Ac

(5) Coral-Like TeO2 Microwires for Rechargeable Aluminum Batteries (ACS Sustainable Chem. Eng. 2020, 8, 2416−2422; 10.1021/acssuschemeng.9b06193) c.d., Ac

 
 
 
allyl chloride (AC)
 
 

(1) Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides (Organometallics 2019, 38, 3991−3995; 10.1021/acs.organomet.9b00197) Al, as, AC

(2) Allyl Palladium Complexes of Cycloheptatrienyl-Cyclopentadienyl Phosphane Ligands in Buchwald-Hartwig Amination Reactions (Eur. J. Inorg. Chem. 2019, 2019, 2569−2576; 10.1002/ejic.201900225) cHex, Cy, Buchwald-Hartwig, cHx, CyHx, 100-61-8, Pd, Al, Cp, tBu, t-Bu, Bu, AC, MORP, C, Ar, Cat

(3) Room-Temperature Cavity Ring-Down Spectroscopy of Methylallyl Peroxy Radicals (J. Phys. Chem. A 2019, 123, 3510−3517; 10.1021/acs.jpca.9b01233) R, Al, O, AC, CRDS, Me, e-, CRD

(4) Design of Epichlorohydrin-Oriented Quaternary System Separation via Hybrid Extraction–Distillation Process (Ind. Eng. Chem. Res. 2019, 58, 4534−4545; 10.1021/acs.iecr.8b06039) EC, ECH, Al, AC, CH3OH, HE, TAC

(5) A Convenient Palladium-Catalyzed Carbonylative Synthesis of (E)-3-Benzylidenechroman-4-ones (Chem. Eur. J. 2019, 25, 3521−3524; 10.1002/chem.201900015) 533-58-4, Pd, Al, AC

 
 
 
Analytical Chemistry (AC)
 
 
 
 
activated carbon (AC)
 

(1) Multi-Scale Model for Describing the Effect of Pore Structure on Carbon-Based Electric Double Layer (J. Phys. Chem. C 2020, 124, 3952−3961; 10.1021/acs.jpcc.9b10587) PSD, aq., EDLC, NL-DFT, EDL, C, Sn, EM, AC

(2) Effect of Thermal Extraction on Coal-Based Activated Carbon for Methane Decomposition to Hydrogen (ACS Omega 2020, 5, 2465−2472; 10.1021/acsomega.9b04044) PD, C, H, em, Sn, O, AC

(3) Hydrothermal synthesis of flower-like MgCo2O4 porous microstructures as high-performance electrode material for asymmetric supercapacitors (J. Alloys Compd. 2020, 824, 153939−; https://doi.org/10.1016/j.jallcom.2020.153939) aq., av., NS, c.d., Pv, Met, SSA, ASC, C, EC, as, ret, AC

(4) Pd/SiO2 Aerogel Composite Adsorbents with High Desulfurization Performance (J. Chem. Eng. Data 2020, 65, 923−934; 10.1021/acs.jced.9b01122) Ne, lb, TP, C, TPH, AC

(5) Adsorption of Light Alkanes and Alkenes on Activated Carbon and Zeolite 13X at Low Temperatures (J. Chem. Eng. Data 2020, 65, 706−716; 10.1021/acs.jced.9b00948) esp., Ne, pt, Et, C, Pr, Al, HC, AC

 
 
 
acetonate (ac)
 

(1) Tris(tropolonato) ruthenium as a hub for connecting π-conjugated systems (Dalton Trans. 2020, 49, 2102−2111; 10.1039/C9DT04860J) acac, trop, Ac, ac

(2) Phosphorescent heteroleptic iridium(III) cyclometallates: Improved syntheses of acetylacetonate complexes and quantum chemical studies of their excited state properties (Polyhedron 2020, 176, 114256−; https://doi.org/10.1016/j.poly.2019.114256) acac, lb, QE, DME, Ir, Et, ES, O, Ac, PL, QY, em, XR, SCXRD, ac

(3) UV/VIS spectroelectrochemistry with 3D printed electrodes (J. Electroanal. Chem. 2020, 857, 113760−; https://doi.org/10.1016/j.jelechem.2019.113760) NT, acac, electrochem., CV, CV, Ru, ET, C, EC, Ac, Sn, ac

(4) Hydrogen selective palladium-alumina composite membranes prepared by Atomic Layer Deposition (J. Membr. Sci. 2020, 596, 117701−; https://doi.org/10.1016/j.memsci.2019.117701) at., acac, SF, ALD, NC, Pd, H, Ac, ac

(5) Development of an acetylacetonate-modified silica-zirconia composite membrane applicable to gas separation (J. Membr. Sci. 2020, 599, 117844−; https://doi.org/10.1016/j.memsci.2020.117844) acac, Zr, Ac, Sn, ac

 
 
 
alternating current (a.c.)
 
 
 
 
adenylate cyclase (AC)
 

(1) Single Molecule Force Spectroscopy Reveals the Mechanical Design Governing the Efficient Translocation of the Bacterial Toxin Protein RTX (J. Am. Chem. Soc. 2019, 141, 20498−20506; 10.1021/jacs.9b11281) HL, OT, Fe, CYC, SM, Sn, AC

(2) Pep‐Lipid Cubosomes and Vesicles Compartmentalized by Micelles from Self‐Assembly of Multiple Neuroprotective Building Blocks Including a Large Peptide Hormone PACAP‐DHA (ChemNanoMat 2019, 5, 1381−1389; 10.1002/cnma.201900468) NS, Fe, CYC, Sn, AC

(3) Engineering Adenylate Cyclase Activated by Near-Infrared Window Light for Mammalian Optogenetic Applications (ACS Synth. Biol. 2019, 8, 1314−1324; 10.1021/acssynbio.8b00528) CYC, m, AC, AC, NIR, IR

(4) Guiding Biomolecular Interactions in Cells Using de Novo Protein–Protein Interfaces (ACS Synth. Biol. 2019, 8, 1284−1293; 10.1021/acssynbio.8b00501) CYC, AC, AC

(5) Piperine-mediated suppression of voltage-dependent Ca2+ influx and glutamate release in rat hippocampal nerve terminals involves 5HT1A receptors and G protein ÎÎ activation (Food Funct. 2019, 10, 2720−2728; 10.1039/C8FO02189A) AP, APY, PKG, CYC, AC, AC, PKA, 504-24-5, 5-HT

 
 
 
Angewandte Chemie (AC)
 
 
 
 
adenylate cyclase (AC)
 

(1) Single Molecule Force Spectroscopy Reveals the Mechanical Design Governing the Efficient Translocation of the Bacterial Toxin Protein RTX (J. Am. Chem. Soc. 2019, 141, 20498−20506; 10.1021/jacs.9b11281) HL, OT, Fe, CYC, SM, Sn, AC, AC

(2) Pep‐Lipid Cubosomes and Vesicles Compartmentalized by Micelles from Self‐Assembly of Multiple Neuroprotective Building Blocks Including a Large Peptide Hormone PACAP‐DHA (ChemNanoMat 2019, 5, 1381−1389; 10.1002/cnma.201900468) NS, Fe, CYC, Sn, AC, AC

(3) Engineering Adenylate Cyclase Activated by Near-Infrared Window Light for Mammalian Optogenetic Applications (ACS Synth. Biol. 2019, 8, 1314−1324; 10.1021/acssynbio.8b00528) CYC, m, AC, AC, NIR, IR

(4) Guiding Biomolecular Interactions in Cells Using de Novo Protein–Protein Interfaces (ACS Synth. Biol. 2019, 8, 1284−1293; 10.1021/acssynbio.8b00501) CYC, AC, AC

(5) Piperine-mediated suppression of voltage-dependent Ca2+ influx and glutamate release in rat hippocampal nerve terminals involves 5HT1A receptors and G protein ÎÎ activation (Food Funct. 2019, 10, 2720−2728; 10.1039/C8FO02189A) AP, APY, PKG, CYC, AC, AC, PKA, 504-24-5, 5-HT

 
 
 
alternating current (AC)
 

(1) Detecting Exosomes Specifically: A Multiplexed Device Based on Alternating Current Electrohydrodynamic Induced Nanoshearing (Anal. Chem. 2014, 86, 11125−11132; 10.1021/ac502082b) hEGF, EGFR, AC, EGF, PSA

(2) Control of Subgrain Formation in Protein Crystals by the Application of an External Electric Field (Crystal Growth & Design 2014, 14, 5662−5667; 10.1021/cg500946b) EEF, HEW, XRD, AC, XR, EF, Lysd, Lyso, LSZ, FWHM

(3) Novel 3D Alkali–Lanthanide Heterometal–Organic Frameworks with Pyrazine-2,3,5,6-tetracarboxylic Acid: Synthesis, Structure, and Magnetism (Crystal Growth & Design 2014, 14, 2014−2021; 10.1021/cg5001254) HMOF, AC, L, pyz

(4) Effective AC needleless and collectorless electrospinning for yarn production (Phys. Chem. Chem. Phys. 2014, 16, 26816−26822; 10.1039/C4CP04346D) AC, DC, CE, EF

(5) Electrospun composite poly(lactic acid)/polyaniline nanofibers from low concentrations in CHCl3: Making a biocompatible polyester electro-active (Polymer 2014, 55, 5727−5733; 10.1016/j.polymer.2014.09.015) b4, diams, AC, PANI, em, PLA

 
 
 
actinium (Ac)
 

(1) Multifunctional GdVO4:Eu core–shell nanoparticles containing 225Ac for targeted alpha therapy and molecular imaging (J. Mater. Chem. B 2018, 6, 7985−7997; 10.1039/C8TB02173B) Eu, Fr, em, Bi, Gd, ret, Ac, PSD, MI, NP, TAT

(2) Quantum Simulation Verifies the Stability of an 18-Coordinated Actinium–Helium Complex (Chem. Eur. J. 2018, 24, 12716−12721; 10.1002/chem.201802554) FSS, He, R, PIMD, Ac, MDS, MD, CN, NQE

(3) Separation of Protactinium Employing Sulfur-Based Extraction Chromatographic Resins (Anal. Chem. 2018, 90, 7012−7017; 10.1021/acs.analchem.8b01380) Th, U, Ge, Ra, FP, Nb, S, Pa, Ac, HCl, EXC, TAT

(4) Theoretical investigation of M@Pb122- and M@Sn122- Zintl clusters (M = Lrn+, Lun+, La3+, Ac3+ and n = 0, 1, 2, 3) (Phys. Chem. Chem. Phys. 2018, 20, 15253−15272; 10.1039/C8CP01056K) BE, BCP, SO, Lr, DOS, MO, Ac, La, BDE, GS, Lu, CP, SOC, DFT, ELF

(5) Bond Covalency and Oxidation State of Actinide Ions Complexed with Therapeutic Chelating Agent 3,4,3-LI(1,2-HOPO) (Inorg. Chem. 2018, 57, 5352−5363; 10.1021/acs.inorgchem.8b00345) Am, An, Cm, Es, EXAFS, Ac, Cf, pyr, ABS, HOPO, Py

 
 
 
absolute configuration (AC)
 

(1) Total Synthesis of Amphidinol 3: A General Strategy for Synthesizing Amphidinol Analogues and Structure–Activity Relationship Study (J. Am. Chem. Soc. 2020, 142, 3472−3478; 10.1021/jacs.9b11789) abs., det., C, MOA, AC

(2) Microsclerodermins N and O, cytotoxic cyclic peptides containing a p-ethoxyphenyl moiety from a deep-sea marine sponge Pachastrella sp. (Tetrahedron 2020, 76, 130997−; https://doi.org/10.1016/j.tet.2020.130997) PEP, abs., PMP, AA, AC

(3) First enantioselective synthesis of gingesulfonic acids and unequivocal determination of their absolute stereochemistry (Org. Biomol. Chem. 2020, 18, 1091−1094; 10.1039/C9OB02662B) abs., AC

(4) Synthesis and stereochemistry of helical polyurethanes based on 2,2′-dihydroxy-1,1′-binaphthyl and diisocyanatobenzenes (Polym. Chem. 2020, 11, 1134−1144; 10.1039/C9PY01348B) abs., PU, PhH, BZ, AC

(5) Morindolestatin, Naturally Occurring Dehydromorpholinocarbazole Alkaloid from Soil-Derived Bacterium of the Genus Streptomyces (Org. Lett. 2020, 22, 1113−1116; 10.1021/acs.orglett.9b04609) abs., det., lb, 110-83-8, Sn, IND, AC

 
 
 
amorphous carbon (AC)
 

(1) Locally Controllable Surface Foaming of Polymers Induced by Graphene via Near-Infrared Pulsed Laser (ACS Sustainable Chem. Eng. 2020, 8, 2498−2511; 10.1021/acssuschemeng.9b07046) FTIR, ATR, PE, ES, Fe, Ra, MLG, C, Pr, XPS, EM, FT, Mat, ipso, oxidn., PS, AC

(2) Filamentary High-Resolution Electrical Probes for Nanoengineering (Nano Lett. 2020, 20, 1067−1073; 10.1021/acs.nanolett.9b04302) at., AF, Pr, Ge, EF, Te, C, Pt, Sn, Sb, DEP, AC

(3) Understanding the Carbon–Bio Interface: Influence of Surface Chemistry and Buffer Composition on the Adsorption of Phospholipid Liposomes at Carbon Surfaces (ACS Appl. Bio Mater. 2020, 3, 997−1007; 10.1021/acsabm.9b01011) PS, det., biol., PC, PPL, FL, C, ML, Sn, PS, Cho, Ser, S, AC

(4) Polyvinyl alcohol-assisted synthesis of porous MoO2/C microrods as anodes for lithium-ion batteries (J. Electroanal. Chem. 2020, 857, 113751−; https://doi.org/10.1016/j.jelechem.2019.113751) Mo, C, EC, Sn, ret, PVOH, PVA, MR, AC

(5) Ru supported on N-doped reduced graphene oxide aerogels with different N-type for alcohol selective oxidation (Mol. Catal. 2020, 484, 110737−; https://doi.org/10.1016/j.mcat.2019.110737) rGOx, NS, C, N, Sn, Bn, PDA, DA, oxidn., GNS, NH2, AC

 
 
February 25, 2020
三井アウトレットパーク倉敷に行ってきました。
February 25, 2020
マグネシウム触媒を使います。
Org. Lett. 2020, 22 (4), 1594−1598.
February 21, 2020
ケイデンスを上げる。
February 21, 2020
青色光照射下での反応です。
J. Am. Chem. Soc. 2020, 142 (7), 3366−3370.
February 20, 2020
株主総会の日。
February 20, 2020
エノラートの幾何異性制御。
Org. Lett. 2020, 2 (3), 791−794.
February 19, 2020
氷点下5度割れ。
February 19, 2020
DBUで落とすのかと思ってました。
Chem. Lett. 2020, 49 (3), 252−253.
January 21, 2020
PLICTでソルバトクロミズム
Chem. Lett. 2020, 49 (1), 10−13.
よく読まれている記事をアーカイブ化しました。
January 21, 2020
ファンタ背負って激坂登り。
September 29, 2016
賭けてたらお縄ですって。
H4OやH14などの分子構造をむりくり計算しました。信じるも信じないもあなた次第。
July 16, 2019
アルケンの炭素を1つ捨てます。
Org. Lett. 2019, 21 (13), 4966−4970.
October 23, 2019
「カルベン」をどうやって確認したんだろう。
J. Am. Chem. Soc. 2019, 141 (41), 16227−16231.
April 12, 2019
ジアゾ化合物不要なのが売りのようです。
Org. Lett. 2019, 21 (7), 2265−2268.
December 26, 2015
Sbsk先生だったかSsi先生だったか、どなたかがおっしゃっていました。
September 10, 2018
25年以上前から闘い(?)は続いています。
January 27, 2020
開環メタセシス重合。
J. Am. Chem. Soc. 2020, 142 (3), 1186−1189.
September 22, 2019
一瞬の不注意でこんなことに。
October 18, 2019
アルミニウム(I)とアレーンからの酸化的付加反応。
Angew. Chem. Int. Ed. 2019, 58 (43), 15496−15503.
May 29, 2017
ポリシランを狙っていたのでしょうか。
May 20, 2019
メタノールがメチル源です。
Org. Lett. 2019, 21 (9), 3299−3303.
January 1, 2020
2018年と比較すると興味深い傾向が
December 11, 2019
ご参考になれば
March 11, 2016
分子ではないですよ。
June 7, 2016
バッテリーを交換しても充電できないままだが何かが変だった話。
May 28, 2016
無理くりになりましたので、結果は予想通りに。
October 5, 2017
にゃー→まぉー→あぅー
読みたいけと読んでいない論文を、構造式を描きながら紹介します(2019年10〜12月)。
February 11, 2018
うん、やっぱりこうなるよね。
September 30, 2019
WordPress最後の記事。
November 22, 2016
何を習ったかを思い出せ。
June 7, 2016
放電すると残量が増えていく!
December 29, 2015
JavascriptとPerlを組み合わせ、アクセスランキングなどをWebに表示させたいときなどに使います。
December 26, 2019
部分日食見えず。
December 29, 2015
忘れないように書き留めておきました。
December 20, 2019
ブールバール攻略。
(c) Nanoniele, 2003-