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phase-transfer catalyst (PTC)
 

(1) Quaternary β2,2-amino acid derivatives by asymmetric addition of isoxazolidin-5-ones to para-quinone methides (Chem. Commun. 2020, 56, 579−582; 10.1039/C9CC09239K) AA, PTC

(2) A Spiroalkylation Method for the Stereoselective Construction of α-Quaternary Carbons and Its Application to the Total Synthesis of (R)-Puraquinonic Acid (Org. Lett. 2019, 21, 9729−9733; 10.1021/acs.orglett.9b03887) C, PTC

(3) Recent Advances in Chiral Guanidine‐Catalyzed Enantioselective Reactions (Chem. Asian. J. 2019, 14, 3803−3822; 10.1002/asia.201901183) as, GUAN, PTC

(4) Phase Transfer Ceria-Supported Nanocatalyst for Nitrile Hydration Reaction (ACS Omega 2019, 4, 16037−16044; 10.1021/acsomega.9b02173) PXRD, TPD, PE, ES, Met, FESEM, em, XPS, XR, EM, FT, REM, PTC

 
 
 
phenyldithiocarbamate (PTC)
 

(1) Ligand-Enhanced Energy Transport in Nanocrystal Solids Viewed with Two-Dimensional Electronic Spectroscopy (J. Phys. Chem. Lett. 2019, 10, 5602−5608; 10.1021/acs.jpclett.9b02040) VB, PTC, 2DES, MO, WF, ET, NC, LE, HE, WFO, e-

(2) Organotin(IV) N-butyl-N-phenyldithiocarbamate complexes: Synthesis, characterization, biological evaluation and molecular docking studies (J. Mol. Struct. 2019, 1192, 15−26; https://doi.org/10.1016/j.molstruc.2019.04.097) PTC, FU, 5-FU, Efudex, FUra, Bu, DTC, SA, SC, Alk

(3) Oxidation of a Molecule by the Biexcitonic State of a CdS Quantum Dot (J. Phys. Chem. C 2019, 123, 5923−5930; 10.1021/acs.jpcc.9b00210) AR, VB, PS, PTC, TAS, PTZ, IR, TA, ABS, QD, NIR

(4) Synthesis, characterization, and cytotoxicity study of organotin(IV) complexes involving different dithiocarbamate groups (J. Mol. Struct. 2019, 1179, 366−375; https://doi.org/10.1016/j.molstruc.2018.11.022) PTC, FU, 5-FU, Efudex, FUra, Et, EA, Sn, S, Nme, DTC, Me

(5) Influence of an exciton-delocalizing ligand on the structural, electronic, and spectral features of the Cd33S33 quantum dot: insights from computational studies (J. Mater. Chem. C 2018, 6, 8751−8761; 10.1039/C8TC03342K) TD, PTC, bza, PTZ, CT, GS, ABS, EBG, DFT, TDDFT, QD, HE, EDD, e-

 
 
 
premature termination codon (PTC)
 

(1) New Negamycin-Based Potent Readthrough Derivative Effective against TGA-Type Nonsense Mutations (ACS Med. Chem. Lett. 2019, 10, 1450−1456; 10.1021/acsmedchemlett.9b00273) AA, DMD, PTC

(2) 2-Aminothiazole-4-carboxamides Enhance Readthrough of Premature Termination Codons by Aminoglycosides (ACS Med. Chem. Lett. 2019, 10, 726−731; 10.1021/acsmedchemlett.8b00610) AA, N, AG, Ind, Ar, PTC

 
 
 
phase transfer catalysis (PTC)
 

(1) Enantioselective catalytic synthesis of α-aryl-α-SCF3-β2,2-amino acids (Org. Biomol. Chem. 2020, 18, 405−408; 10.1039/C9OB02666E) Et, AA, TFM, Me, PTC

(2) Enantioselective Synthesis of Multifunctionalized 4H-Pyrans via Formal [4 + 2] Annulation Process by Bifunctional Phosphonium Salt Catalysis (Org. Lett. 2020, 22, 395−399; 10.1021/acs.orglett.9b04079) g, as, Sn, ph, C3H4, PTC

(3) Synthesis, characterization and DFT studies of 6-bis(2-(thiazol-4-yl)-benzimidazol-1-yl)hexane hemihydrate crystal: Experimental and theoretical investigation (J. Mol. Struct. 2020, 1202, 127253−; https://doi.org/10.1016/j.molstruc.2019.127253) lb, FMO, 629-03-8, CT, IMD, imH, Him, imid, Hx, MO, SG, Im, 57-13-6, CS, bim, expt., PTC

(4) Asymmetric Three-Component Cyclizations toward Structurally Spiro Pyrrolidines via Bifunctional Phosphonium Salt Catalysis (Org. Lett. 2019, 21, 8667−8672; 10.1021/acs.orglett.9b03282) lb, as, ph, MCR, 3CR, PTC

(5) Synthesis, anticancer evaluation in vitro, DFT, Hirshfeld surface analysis of some new 4-(1,3-benzothiazol-2-yl)-3-methyl-1-phenyl-4,5-dihydro-1H-pyrazol-5-one derivatives (J. Mol. Struct. 2019, 1198, 126910−; https://doi.org/10.1016/j.molstruc.2019.126910) BT, BTZ, 95-16-9, HPz, pzH, pz, Me, Ph, PTC, GS

 
 
 
phase-transfer conditions (PTC)
 

(1) Enantioselective cyclopropanation of conjugated cyanosulfones using carbohydrate-based crown ether catalysts (Tetrahedron 2020, 76, 130965−; https://doi.org/10.1016/j.tet.2020.130965) Glu, Et, as, Pyr, CN, Sn, Naph, Nap, Np, PTC

(2) A General Method for High-Pressure-Promoted Postfunctionalization of Unclosed Cryptands: Potential Phase-Transfer Catalysts (J. Org. Chem. 2020, 85, 1308−1314; 10.1021/acs.joc.9b02985) PTC

(3) Asymmetric Synthesis of α-Trifluoromethylthio-β-Amino Acids under Phase Transfer Catalysis (Org. Lett. 2020, 22, 219−223; 10.1021/acs.orglett.9b04195) er, Et, AA, C, as, Sn, am, PTC

(4) Multiphase Methods in Organic Electrosynthesis (Acc. Chem. Res. 2019, 52, 3325−3338; 10.1021/acs.accounts.9b00480) aq., fac, Fe, Pd, H, Sn, US, PTC

(5) Nucleophilic Aromatic Substitutions of 2-Halo-5-(sulfamoyl)benzoic Acids and N,O-Bis-alkylation via Phase Transfer Catalysis: Synthesis of RoRÎ Inverse Agonist GSK2981278A (Org. Process Res. Dev. 2019, 23, 1396−1406; 10.1021/acs.oprd.9b00147) RA, K, PTC, Nu, ñè, 119-36-8, Me, PTC, NAS, SNAr, Ar

 
 
 
peptidyl transferase center (PTC)
 

(1) Introducing the Mechanical Forces in Biochemistry Special IssueMechanochemistry in Translation (Biochemistry 2019, 58, 4657−4666; 10.1021/acs.biochem.9b00999DO - 10.1021/acs.biochem.9b00260) PTC

(2) Defects in the Assembly of Ribosomes Selected for β-Amino Acid Incorporation (Biochemistry 2019, 58, 4494−4504; 10.1021/acs.biochem.9b00746) PTC

(3) Discovery of small-molecule inhibitors targeting the ribosomal peptidyl transferase center (PTC) of M. tuberculosis (Chem. Sci. 2019, 10, 8764−8767; 10.1039/C9SC02520K) PTC, TB, SMI

(4) Antibacterial properties and clinical potential of pleuromutilins (Nat. Prod. Rep. 2019, 36, 220−247; 10.1039/C8NP00042E) PTC

(5) d-Amino Acid-Mediated Translation Arrest Is Modulated by the Identity of the Incoming Aminoacyl-tRNA (Biochemistry 2018, 57, 4241−4246; 10.1021/acs.biochem.8b00595) PTC, AA, SC

 
 
 
positive train control (PTC)
 
 
 
 
perylene-3,4,9,10-tetracarboxylate (ptc)
 

(1) Potassium perylene-tetracarboxylate with two-electron redox behaviors as a highly stable organic anode for K-ion batteries (Chem. Commun. 2019, 55, 1801−1804; 10.1039/C8CC09596E) ptc, K, PY, Per, e-

(2) CVD growth of molybdenum diselenide surface structures with tailored morphology (CrystEngComm 2018, 20, 4867−4874; 10.1039/C8CE00917A) TMD, Mo, ptc, TMDC, Si, AP, TM, PY, Per

(3) Specific Uniaxial Self-assembly of Columnar Perylene Liquid Crystals in Au Nanofin Arrays (Chem. Lett. 2018, 47, 354−357; 10.1246/cl.171228) IP, ptc, Au, LC, HEX, Hx, LC, PY, Per, SA

(4) Controllable Monobromination of Perylene Ring System: Synthesis of Bay-Functionalized Perylene Dyes (J. Org. Chem. 2018, 83, 624−631; 10.1021/acs.joc.7b02540) ptc, PY, Per

(5) Perylene-Based All-Organic Redox Battery with Excellent Cycling Stability (ACS Appl. Mater. Interfaces 2016, 8, 22762−22767; 10.1021/acsami.6b07591) ptc, Li, Hex, nHex, LIB, PY, Per

 
 
 
pertussis toxin (PTC)
 

(1) A Dissolvable Microneedle Formulation of Bordetella pertussis Subunit Vaccine: Translational Development and Immunological Evaluation in Mice (ACS Appl. Bio Mater. 2019, 2, 5053−5061; 10.1021/acsabm.9b00730) esp., PTC

(2) 5-HT1B Receptor-Mediated Activation of ERK1/2 Requires Both Gαi/o and Î-Arrestin Proteins (ACS Chem. Neurosci. 2019, 10, 3143−3153; 10.1021/acschemneuro.8b00596) PTC, KO, Ala, A, CYC, Ser, S

(3) Lack of beta-arrestin signaling in the absence of active G proteins (Nature Communications 2018, 9, 341−; 10.1038/s41467-017-02661-3) PTC, PCR, GPCR, GPGR

(4) An ELISA method to estimate the mono ADP-ribosyltransferase activities: e.g in pertussis toxin and vaccines (Anal. Biochem. 2018, 540–541, 15−19; https://doi.org/10.1016/j.ab.2017.10.025) PTC, RBP, EC, Rib

(5) ROCK regulates the intermittent mode of interstitial T cell migration in inflamed lungs (Nature Communications 2017, 8, 1010−; 10.1038/s41467-017-01032-2) PTC, TP, PKG, TPI, ALI

 
 
 
planar tetracoordinate carbon (ptC)
 

(1) Theoretical Studies of SiC4H2 Isomers Delineate Three Low-Lying Silylidenes Are Missing in the Laboratory (J. Phys. Chem. A 2020, 124, 987−1002; 10.1021/acs.jpca.9b11742) esp., CC, MIS, ISM, Et, C, TS, Si, Sn, Mat, ptC

(2) Cluster-Inspired Design of High-Capacity Anode for Li-Ion Batteries (ACS Energy Lett. 2016, 1, 202−208; 10.1021/acsenergylett.6b00120) NT, LBL, C, Si, ptC

(3) CLiAl2E and CLi2AlE (E = P, As, Sb, Bi): Planar Tetracoordinate Carbon Clusters with 16 and 14 Valence Electrons (ACS Omega 2019, 4, 21311−21318; 10.1021/acsomega.9b02869) esp., PES, lp, C, Sn, DB, ptC

(4) Carbon rings decorated with group 14 elements: new aromatic clusters containing planar tetracoordinate carbon (New J. Chem. 2019, 43, 6781−6785; 10.1039/C9NJ01022J) PES, C, Cp, HC, PhH, BZ, ptC, arene, e-

(5) B-Heterocyclic Carbene Arising from Charge Shift: A Computational Verification (Chem. Eur. J. 2018, 24, 10216−10223; 10.1002/chem.201801620) WBI, B, C, Het, LB, LA, ptC, e-, BHC

 
 
 
papillary thyroid carcinoma (PTC)
 

(1) Glyco-CPLL: An Integrated Method for In-Depth and Comprehensive N-Glycoproteome Profiling of Human Plasma (J. Proteome Res. 2020, 19, 655−666; 10.1021/acs.jproteome.9b00557) IC, GP, Sn, HILIC, PTC

(2) N-glycan profiling of papillary thyroid carcinoma tissues by MALDI-TOF-MS (Anal. Biochem. 2019, 584, 113389−; https://doi.org/10.1016/j.ab.2019.113389) PTM, PTC, FFPE, MS

(3) Identification and Application of an Aptamer Targeting Papillary Thyroid Carcinoma Using Tissue-SELEX (Anal. Chem. 2019, 91, 8289−8297; 10.1021/acs.analchem.9b01000) SALEX, FL, PTC, SELEX

(4) Knockdown of circPVT1 inhibits progression of papillary thyroid carcinoma by sponging miR-126 (RSC Adv. 2019, 9, 13316−13324; 10.1039/C9RA01820D) IF, FCM, PCR, PTC, Luc, PVT1

(5) Induction of Apoptosis in Human Papillary-Thyroid-Carcinoma BCPAP Cells by Diallyl Trisulfide through Activation of the MAPK Signaling Pathway (J. Agric. Food Chem. 2018, 66, 5871−5878; 10.1021/acs.jafc.8b02243) PTC

 
 
 
positive temperature coefficient (PTC)
 

(1) Solid-State Carbon-Doped GaN Schottky Diodes by Controlling Dissociation of the Graphene Interlayer with a Sputtered AlN Capping Layer (ACS Appl. Mater. Interfaces 2019, 11, 48086−48094; 10.1021/acsami.9b18976) esp., Fe, C, SS, Sn, SIMS, PTC

(2) Optimizing composition in MnBi permanent magnet alloys (Acta Mater. 2019, 181, 595−602; https://doi.org/10.1016/j.actamat.2019.10.003) lb, Sn, O, 57-13-6, PTC

(3) High-Temperature Polarization-Free III-Nitride Solar Cells with Self-Cooling Effects (ACS Photonics 2019, 6, 2096−2103; 10.1021/acsphotonics.9b00655) EQE, TRPL, MQ, QE, TR, PV, PL, PTC, MQW, QW

(4) Ba8CoNb6–xTaxO24 Eight-Layer Shifted Hexagonal Perovskite Ceramics with Spontaneous Ta5+ Ordering and Near-Zero Ïf (Inorg. Chem. 2019, 58, 10974−10982; 10.1021/acs.inorgchem.9b01417) XEDS, O, HEX, Hx, NPD, ADF, EDS, PTC, e-, P

(5) Ba8CoNb6–xTaxO24 Eight-Layer Shifted Hexagonal Perovskite Ceramics with Spontaneous Ta5+ Ordering and Near-Zero Ïf (Inorg. Chem. 2019, 58, 10974−10982; 10.1021/acs.inorgchem.9b01417) XEDS, O, HEX, Hx, NPD, ADF, EDS, PTC, e-, P

 
 
 
protein trans cleavage (PTC)
 

(1) Cell-Based Biosensors Based on Intein-Mediated Protein Engineering for Detection of Biologically Active Signaling Molecules (Anal. Chem. 2018, 90, 9779−9786; 10.1021/acs.analchem.8b01481) GC, GR, IF, RE, FL, ET, DEX, 51-45-6, RET, PTS, FRET, PTC

 
 
 
pseudo transient continuation (PTC)
 

(1) Simultaneous Optimization of Heat-Integrated Extractive Distillation with a Recycle Feed Using Pseudo Transient Continuation Models (Ind. Eng. Chem. Res. 2018, 57, 15423−15436; 10.1021/acs.iecr.8b02728) EC, ALGM, DMK, PhMe, CH3OH, TolH, ACE, CED, EDC, SRC, PTC

 
 
February 19, 2020
DBUで落とすのかと思ってました。
Chem. Lett. 2020, 49 (3), 252−253.
February 18, 2020
「呉カレーふりかけ」なるものを試した。
February 18, 2020
不斉反応です。
Org. Lett. 2020, 22 (3), 1135−1138.
February 17, 2020
ステーキハウス但馬でステーキランチをいただきました。
February 17, 2020
デヒドロヒドロアリール化?。
Org. Lett. 2020, 22 (3), 1124−1129.
February 14, 2020
大根を食い尽くす。
February 14, 2020
タイトルそのまんまです。
Angew. Chem. Int. Ed. 2020, 59 (8), 3147−3150.
February 13, 2020
所用で「都心」へ。
よく読まれている記事をアーカイブ化しました。
読みたいけと読んでいない論文を、構造式を描きながら紹介します(2019年10〜12月)。
December 12, 2019
PhCMe(CN)2
J. Am. Chem. Soc. 2019, 141 (49), 19257−19262.
March 4, 2019
還元剤はこれ。
J. Am. Chem. Soc. 2019, 141 (8), 3664−3669.
May 24, 2019
炭素−炭素結合切断を伴います。
Chem. Commun. 2019, 55 (41), 5740−5742.
June 7, 2016
放電すると残量が増えていく!
November 19, 2014
頻繁にフリーズとかハングアップとか、そんなやつが頻繁に起こるようになったのです。
January 27, 2016
最近は少し「ふつう」になりました。
May 28, 2019
水素化ホウ素ナトリウムね。
Chem. Commun. 2019, 55 (41), 5859−5862.
February 11, 2018
うん、やっぱりこうなるよね。
October 30, 2019
今日の晩御飯はニラ餃子の予定です。
April 19, 2018
広島でちょっと有名なあれです。
November 6, 2019
アルミニウム触媒と塩基の使い方が絶妙。
Org. Lett. 2019, 21 (21), 8509−8513.
May 28, 2016
無理くりになりましたので、結果は予想通りに。
January 1, 2020
2018年と比較すると興味深い傾向が
December 11, 2019
ご参考になれば
March 11, 2016
分子ではないですよ。
June 7, 2016
バッテリーを交換しても充電できないままだが何かが変だった話。
October 5, 2017
にゃー→まぉー→あぅー
September 30, 2019
WordPress最後の記事。
November 22, 2016
何を習ったかを思い出せ。
December 29, 2015
JavascriptとPerlを組み合わせ、アクセスランキングなどをWebに表示させたいときなどに使います。
December 26, 2019
部分日食見えず。
December 20, 2019
ブールバール攻略。
(c) Nanoniele, 2003-